公开(公告)号：US08652247B2

公开(公告)日：2014-02-18

申请号：US13071888

申请日：2011-03-25

申请人： Szilard Csihony ,  Ivette Garcia Castro ,  Heike Pfistner ,  Eva Wagner ,  Pia Baum ,  Christian Hubert Weidl

发明人： Szilard Csihony ,  Ivette Garcia Castro ,  Heike Pfistner ,  Eva Wagner ,  Pia Baum ,  Christian Hubert Weidl

IPC分类号： C09D191/06

CPC分类号： C09D123/08 ,  C09D191/06

摘要： An aqueous paint formulation having an aqueous basecoat and an aqueous dispersion having an at least partially neutralized ethylene copolymer wax, wherein the ethylene copolymer wax contains as comonomers in copolymerized form (A) 12-40 wt % of an ethylenically unsaturated carboxylic acid of formula (I), (B) 60-88 wt % of ethylene, and (C) 0-10 wt % of a further comonomer; or the ethylene copolymer was contains as comonomers in copolymerized form (A′) 5-50 wt % of a comonomer of formula (II), (B′) 50-95 wt % of ethylene, and (C′) 0-20 wt % of a further comonomer; wherein the ethylene copolymer wax comprising the comonomers (A), (B), and optionally (C) has a molecular weight Mw of 10000 to 150000 g/mol, and the ethylene copolymer wax comprising the comonomers (A′), (B′), and optionally (C′) has a molecular weight Mw of 5000 to 40000 g/mol.

摘要翻译： 一种具有底漆水溶液和含有至少部分中和的乙烯共聚物蜡的水性分散体的水性涂料配方，其中乙烯共聚物蜡含有共聚形式的共聚单体（A）12-40重量％的式（I）的烯属不饱和羧酸 I），（B）60-88重量％的乙烯和（C）0-10重量％的另外的共聚单体; 或乙烯共聚物作为共聚单体（A'）含有5-50重量％的式（II）共聚单体，（B'）50-95重量％乙烯和（C'）0-20重量％的共聚单体 ％的另外的共聚单体; 其中包含共聚单体（A），（B）和任选的（C）的乙烯共聚物蜡的分子量Mw为10000至150000g / mol，并且包含共聚单体（A'），（B' ），任选地（C'）的分子量Mw为5000〜40000g / mol。

公开(公告)号：US07645345B2

公开(公告)日：2010-01-12

申请号：US12181900

申请日：2008-07-29

申请人： Pia Baum ,  Kathrin Michl ,  Franz Weingart ,  Stephan Nied ,  Gregor Brodt

发明人： Pia Baum ,  Kathrin Michl ,  Franz Weingart ,  Stephan Nied ,  Gregor Brodt

IPC分类号： B08B3/04 ,  C11D3/37

CPC分类号： C11D3/378

摘要： Use of copolymers containing sulfonic acid groups which comprise (a) 30 to 95 mol % of at least one monoethylenically unsaturated carboxylic acid, one monoethylenically unsaturated carboxylic ester or one water-soluble salt of a monoethylenically unsaturated carboxylic acid, (b) 3 to 35 mol % of at least one monomer containing sulfonic acid groups of the formula I in which the variables have the following meanings: R is hydrogen or methyl; X is a chemical bond or —COO—R1—; R1 is unbranched or branched C1-C4-alkylene; M is hydrogen, alkali metal or ammonium, and (c) 2 to 35 mol % of at least one nonionic monomer of the formula II in which the variables have the following meanings: R2 is hydrogen or methyl; R3 is a chemical bond or unbranched or branched C1-C6-alkylene; R4 are identical or different unbranched or branched C2-C4-alkylene radicals; R5 is unbranched or branched C1-C6-alkyl, C5-C8-cycloalkyl or aryl; n is 3 to 50, in random or block copolymerized form, as additive for detergents and cleaners.

摘要翻译： 使用包含（a）30-95摩尔％至少一种单烯属不饱和羧酸，一种单烯属不饱和羧酸酯或一种单烯属不饱和羧酸的一种水溶性盐的磺酸基团的共聚物，（b）3-35 mol％的至少一种含有式I磺酸基的单体，其中变量具有以下含义：R是氢或甲基; X是化学键或-COO-R 1; R1是无支链或支链C1-C4-亚烷基; M是氢，碱金属或铵，和（c）2-35mol％的至少一种式II的非离子单体，其中变量具有以下含义：R 2是氢或甲基; R3是化学键或无支链或支链C1-C6-亚烷基; R4是相同或不同的非支链或支链C 2 -C 4 - 亚烷基; R5是无支链或支链C 1 -C 6 - 烷基，C 5 -C 8 - 环烷基或芳基; n为3至50，以无规或嵌段共聚形式，作为洗涤剂和清洁剂的添加剂。

公开(公告)号：US20080281053A1

公开(公告)日：2008-11-13

申请号：US12181900

申请日：2008-07-29

申请人： Pia Baum ,  Kathrin Michl ,  Franz Weingart ,  Stephan Nied ,  Gregor Brodt

发明人： Pia Baum ,  Kathrin Michl ,  Franz Weingart ,  Stephan Nied ,  Gregor Brodt

IPC分类号： C08F228/02 ,  C08F230/04

CPC分类号： C11D3/378

摘要： Use of copolymers containing sulfonic acid groups which comprise (a) 30 to 95 mol % of at least one monoethylenically unsaturated carboxylic acid, one monoethylenically unsaturated carboxylic ester or one water-soluble salt of a monoethylenically unsaturated carboxylic acid, (b) 3 to 35 mol % of at least one monomer containing sulfonic acid groups of the formula I in which the variables have the following meanings: R is hydrogen or methyl; X is a chemical bond or —COO—R1—; R1 is unbranched or branched C1-C4-alkylene; M is hydrogen, alkali metal or ammonium, and (c) 2 to 35 mol % of at least one nonionic monomer of the formula II in which the variables have the following meanings: R2 is hydrogen or methyl; R3 is a chemical bond or unbranched or branched C1-C6-alkylene; R4 are identical or different unbranched or branched C2-C4-alkylene radicals; R5 is unbranched or branched C1-C6-alkyl, C5-C8-cycloalkyl or aryl; n is 3 to 50, in random or block copolymerized form, as additive for detergents and cleaners.

摘要翻译： 使用包含（a）30-95摩尔％至少一种单烯属不饱和羧酸，一种单烯属不饱和羧酸酯或一种单烯属不饱和羧酸的一种水溶性盐的磺酸基团的共聚物，（b）3-35 mol％的至少一种含有式I磺酸基的单体，其中变量具有以下含义：R是氢或甲基; X是化学键或-COO-R 1 - R 1是非支链或支链C 1 -C 4 - 亚烷基; M是氢，碱金属或铵，和（c）2-35mol％的至少一种式II的非离子单体，其中变量具有以下含义：R 2是氢或甲基 ; R 3是化学键或无支链或支链C 1 -C 6 - 亚烷基; R 4是相同或不同的未支链或支链C 2 -C 4 - 亚烷基; R 5是非支链或支链C 1 -C 6 - 烷基，C 5 -C 8 环烷基或芳基; n为3至50，以无规或嵌段共聚形式，作为洗涤剂和清洁剂的添加剂。

公开(公告)号：US20060116311A1

公开(公告)日：2006-06-01

申请号：US10537268

申请日：2003-11-28

申请人： Pia Baum ,  Nicola Kulzer ,  Frank Funke ,  Andreas Bastian ,  Markus Ringelsbacher ,  Heinz Heissler ,  Gerhard Reuther ,  Rouven Konrad ,  James Carnahan ,  Karl Siemensmeyer ,  Birgit Potthoff-Karl ,  Tarja Schneider ,  Johann Muller

发明人： Pia Baum ,  Nicola Kulzer ,  Frank Funke ,  Andreas Bastian ,  Markus Ringelsbacher ,  Heinz Heissler ,  Gerhard Reuther ,  Rouven Konrad ,  James Carnahan ,  Karl Siemensmeyer ,  Birgit Potthoff-Karl ,  Tarja Schneider ,  Johann Muller

IPC分类号： C11D3/37

CPC分类号： D06P5/137 ,  D06P1/52 ,  D06P1/5242 ,  D06P1/60 ,  D06P5/08

摘要： The use of copolymers containing units derived from at least 2 monoethylenically unsaturated monomers B1 and B2 which each contain at least one nitrogenous heterocycle, as auxiliaries for textile dyeing and textile printing.

摘要翻译： 使用含有至少2个单烯属不饱和单体B1和B2的单元的共聚物，每个含有至少一个含氮杂环的单烯属不饱和单体作为织物染色和织物印刷的助剂。

公开(公告)号：US20050004322A1

公开(公告)日：2005-01-06

申请号：US10494512

申请日：2002-11-11

申请人： Pia Baum ,  Christine Muller ,  Anke Oswald ,  Birgit Potthoff-Karl

发明人： Pia Baum ,  Christine Muller ,  Anke Oswald ,  Birgit Potthoff-Karl

IPC分类号： C08F261/06 ,  C08F283/06 ,  C11D3/37

CPC分类号： C11D3/3788 ,  C08F283/06 ,  C11D3/0021 ,  C08F226/06 ,  C08F226/10

摘要： Graft polymers containing (A) a polymeric grafting base devoid of monoethylenically unsaturated units, and (B) polymeric side chains formed by polymerization of a cyclic N-vinylamide of the general formula I where R is C1-C5-alkyl and R1 is hydrogen or C1-C4-alkyl, wherein said side chains (B) account for ≧60% by weight of the total polymer.

摘要翻译： 含有（A）不含单烯键式不饱和单元的聚合接枝基的接枝聚合物，和（B）聚合侧链，通过通式Ⅰ的环状N-乙烯基酰胺的聚合形成，其中R是C 1 -C 5烷基和R 1， 是氢或C 1 -C 4 - 烷基，其中所述侧链（B）占总聚合物重量的≥60％。

公开(公告)号：US08475538B2

公开(公告)日：2013-07-02

申请号：US13058112

申请日：2009-07-30

申请人： Pia Baum ,  Klaus Scheuermann ,  Dieter Boeckh

发明人： Pia Baum ,  Klaus Scheuermann ,  Dieter Boeckh

IPC分类号： C11D3/00

CPC分类号： D06P5/02 ,  D06P1/52 ,  D06P1/60 ,  D06P3/54 ,  D06P3/79 ,  D06P3/794 ,  D06P5/08

摘要： A process for aftertreating dyed and/or printed textiles to remove excess portions of colorants comprises utilizing an aqueous formulation comprising at least one graft copolymer having a hydrophilic main chain and also surfactants.

摘要翻译： 用于后处理染色和/或印刷纺织品以除去多余部分着色剂的方法包括使用包含至少一种具有亲水主链的接枝共聚物和表面活性剂的水性制剂。

公开(公告)号：US20110253010A1

公开(公告)日：2011-10-20

申请号：US13071888

申请日：2011-03-25

申请人： Szilard CSIHONY ,  Ivette Garcia Castro ,  Heike Pfistner ,  Eva Wagner ,  Pia Baum ,  Christian Hubert Weidl

发明人： Szilard CSIHONY ,  Ivette Garcia Castro ,  Heike Pfistner ,  Eva Wagner ,  Pia Baum ,  Christian Hubert Weidl

IPC分类号： C09D191/06

CPC分类号： C09D123/08 ,  C09D191/06

摘要： An aqueous paint formulation composed of an aqueous basecoat and an aqueous dispersion of an at least partially neutralized ethylene copolymer wax which is selected from ethylene copolymer waxes comprising as comonomers in copolymerized form: (A) 12% to 40% of an ethylenically unsaturated carboxylic acid of the formula I, where R1 and R2 are hydrogen and/or C1-C10alkyl; (B) 60% to 88% of ethylene; (C) 0% to 10% of a further comonomer; or (A′) 5% to 50% of a comonomer of the formula II where R1 and R2 are hydrogen and/or C1-C10alkyl, R3 is hydrogen, C1-C10alkyl and/or C3-C12cycloalkyl, where two radicals R3 may be joined to form a ring, X is oxygen, sulfur and/or N—R4, R4 is C1-C10alkyl or hydrogen, and A1 is a divalent group; (B′) 50% to 95% by weight of ethylene, and (C′) zero to 20% by weight of a further comonomer; where the ethylene copolymer waxes (A)(B)(C) and (A′)(B′)(C′) have a molecular weight 10 000 to 100 000 and 5000 to 40 000 g/mol, respectively; and the use thereof for coating plastics.

摘要翻译： 由底漆水溶液和至少部分中和的乙烯共聚物蜡的水分散体组成的水性涂料配方，其选自乙烯共聚物蜡，其包含共聚形式的共聚单体：（A）12％至40％的烯键式不饱和羧酸 其中R 1和R 2是氢和/或C 1 -C 10烷基; （B）60％〜88％的乙烯; （C）0％〜10％的另外的共聚单体; 或（A'）5％至50％的式II的共聚单体，其中R 1和R 2是氢和/或C 1 -C 10烷基，R 3是氢，C 1 -C 10烷基和/或C 3 -C 12环烷基，其中两个基团R 3可以是 连接形成环，X为氧，硫和/或N-R4，R4为C1-C10烷基或氢，A1为二价基团; （B'）50重量％至95重量％的乙烯，和（C'）0-20重量％的另外的共聚单体; 其中乙烯共聚物蜡（A）（B）（C）和（A'）（B'）（C'）的分子量分别为10 000至100 000和5000至40 000g / mol; 以及其用于涂覆塑料的用途。

公开(公告)号：US20070244023A1

公开(公告)日：2007-10-18

申请号：US11587584

申请日：2005-04-26

申请人： Gregor Brodt ,  Pia Baum ,  Tanja Seebeck ,  Marcus Guzmann

发明人： Gregor Brodt ,  Pia Baum ,  Tanja Seebeck ,  Marcus Guzmann

IPC分类号： C11D17/08 ,  C11D3/28

CPC分类号： C11D3/3776 ,  C11D3/0021

摘要： The present invention relates to the use of a copolymer comprising, in polymerized form, (a) from 80 to 99.9 mol %, based on the total amount of the monomers polymerized to prepare the copolymer, of at least one monomer A which in each case comprises a heterocycle having at least 1 nitrogen atom and composed of from 3 to 10 ring members and a C2-C6-alkenyl group bonded to a carbon or nitrogen ring atom of the heterocycle; and (b) from 0.1 to 20 mol %, based on the total amount of the monomers polymerized to prepare the copolymer, of at least one monomer B copolymerizable with monomer A, said monomer B having a monoethylenically unsaturated double bond and also a linear or branched poly-C2-C4-alkylene oxide group having on average from 4 to 500 C2-C4-alkylene oxide units, in liquid and in solid detergent formulations. In addition, the invention relates to a process for preparing such a copolymer, and also to a liquid or solid detergent formulation comprising at least one such copolymer.

摘要翻译： 本发明涉及共聚物的用途，所述共聚物以聚合形式包含（a）基于聚合制备共聚物的单体总量的80至99.9mol％的至少一种单体A，其在每种情况下 包含具有至少1个氮原子并由3至10个环成员组成的杂环和与碳或氮环原子键合的C 2 -C 6 -C 6 - 链烯基 的杂环; 至少一种可与单体A共聚的单体B，所述单体B具有单烯键式不饱和双键，并且还包括直链或者直链或不饱和的双键，并且（b）0.1至20摩尔％，基于聚合以制备共聚物的单体的总量， 支链多-C 2 -C 4 - 亚烷基氧基，其平均具有4至500个碳原子的2〜4个碳原子， 在液体和固体洗涤剂配方中，可以使用亚烷基氧化物单元。 此外，本发明涉及一种制备这种共聚物的方法，还涉及包含至少一种这样的共聚物的液体或固体洗涤剂制剂。

公开(公告)号：US20060074002A1

公开(公告)日：2006-04-06

申请号：US10541663

申请日：2003-12-24

申请人： Juergen Detering ,  Tanja Schneider ,  Matthias Kluglein ,  Pia Baum

发明人： Juergen Detering ,  Tanja Schneider ,  Matthias Kluglein ,  Pia Baum

IPC分类号： C11D17/00

CPC分类号： C11D3/3769 ,  C08F8/14 ,  C08F267/04 ,  C08F283/06 ,  C08L51/003 ,  C08L51/08 ,  C11D3/0021 ,  C11D3/37 ,  C11D3/3757 ,  C08L2666/02

摘要： The invention relates to copolymers which can be obtained by radical polymerisation of (A) at least one monoethylenically unsaturated C4-C8 dicarboxylic acid anhydride, (B) at least one vinylaromatic compound from the group containing styrol and substituted styrols, and (C) at least one monoethylenically unsaturated monomer which contains at least one heteroatom and is different from (A); by partial esterification of the obtained copolymers with (D) alcohol alkoxylates of formula (I) wherein the variables have the following designations: R represents C2-C6 alkylene radicals which can be the same or different for n>1, R1 represents C1-C30 alkyl, and n represents a number between 1 and 200; and as desired, by hydrolysis of the anhydride groups still contained in the copolymers in order to form carboxyl groups. The invention also relates to the use of said copolymers as additives for washing and cleaning products.

摘要翻译： 本发明涉及可通过（A）至少一种单烯键式不饱和C4-C8二羧酸酐，（B）至少一种乙烯基芳族化合物与苯乙烯和取代苯乙烯的基团自由基聚合获得的共聚物，和（C） 至少一个含有至少一个杂原子并且不同于（A）的单烯属不饱和单体; 所得共聚物与（D）式（I）的醇烷氧基化物的部分酯化反应，其中变量具有以下指定：R表示对于n> 1，R 1可以相同或不同的C 2 -C 6亚烷基 表示C 1〜C 30烷基，n表示1〜200的数; 并且根据需要通过水解仍然包含在共聚物中的酸酐基团以形成羧基。 本发明还涉及所述共聚物作为洗涤和清洁产品的添加剂的用途。

公开(公告)号：US07728063B2

公开(公告)日：2010-06-01

申请号：US11587584

申请日：2005-04-26

申请人： Gregor Brodt ,  Pia Baum ,  Tanja Seebeck ,  Marcus Guzmann

发明人： Gregor Brodt ,  Pia Baum ,  Tanja Seebeck ,  Marcus Guzmann

IPC分类号： A61K9/16 ,  C08F8/30 ,  C08F290/06 ,  C08F20/58 ,  C08F18/00 ,  C08F16/12 ,  C08F116/12

CPC分类号： C11D3/3776 ,  C11D3/0021

摘要： The present invention relates to the use of a copolymer comprising, in polymerized form, (a) from 80 to 99.9 mol %, based on the total amount of the monomers polymerized to prepare the copolymer, of at least one monomer A which in each case comprises a heterocycle having at least 1 nitrogen atom and composed of from 3 to 10 ring members and a C2-C6-alkenyl group bonded to a carbon or nitrogen ring atom of the heterocycle; and (b) from 0.1 to 20 mol %, based on the total amount of the monomers polymerized to prepare the copolymer, of at least one monomer B copolymerizable with monomer A, said monomer B having a monoethylenically unsaturated double bond and also a linear or branched poly-C2-C4-alkylene oxide group having on average from 4 to 500 C2-C4-alkylene oxide units, in liquid and in solid detergent formulations. In addition, the invention relates to a process for preparing such a copolymer, and also to a liquid or solid detergent formulation comprising at least one such copolymer.

摘要翻译： 本发明涉及共聚物的用途，所述共聚物以聚合形式包含（a）基于聚合制备共聚物的单体总量的80至99.9mol％的至少一种单体A，其在每种情况下 包括具有至少1个氮原子并由3至10个环成员组成的杂环和与该杂环的碳或氮环原子键合的C 2 -C 6 - 链烯基; 至少一种可与单体A共聚的单体B，所述单体B具有单烯键式不饱和双键，并且还包括直链或者直链或不饱和的双键，并且（b）0.1至20摩尔％，基于聚合以制备共聚物的单体的总量， 在液体和固体洗涤剂配方中平均具有4至500个C 2 -C 4 - 烯化氧单元的支链多C 2 -C 4 - 烯化氧基团。 此外，本发明涉及一种制备这种共聚物的方法，还涉及包含至少一种这样的共聚物的液体或固体洗涤剂制剂。