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1.发明授权Catalysts for producing acetic acid from ethane oxidation, processes of making the same and methods of using same 有权用于从乙烷氧化生产乙酸的催化剂，其制备方法和使用方法公开(公告)号：US06383977B1
公开(公告)日：2002-05-07
申请号：US09461085
申请日：1999-12-14
申请人： Khalid Karim , Edouard Mamedov , Mohammed H. Al-Hazmi , Anis H. Fakeeha , Mustaf A. Soliman , Yousef S. Al-Zeghayer , Ahmed S. Al-Fatish , Abdulsalm A. Al-Arify
发明人： Khalid Karim , Edouard Mamedov , Mohammed H. Al-Hazmi , Anis H. Fakeeha , Mustaf A. Soliman , Yousef S. Al-Zeghayer , Ahmed S. Al-Fatish , Abdulsalm A. Al-Arify
IPC分类号： B01J2328
CPC分类号： C07C51/215 , B01J23/002 , B01J23/6525 , B01J37/0236 , B01J2523/00 , Y02P20/582 , C07C53/08 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/824
摘要： An oxide catalyst comprising the elements Mo, V, Nb and Pd. The novel catalytic system provides both higher selectivity and yield of acetic acid in the low temperature one step vapor phase direct oxidation of ethane with molecular oxygen containing gas without production of side products such as ethylene and CO.
摘要翻译： 包含元素Mo，V，Nb和Pd的氧化物催化剂。 新型催化体系在低温一步气相直接氧化乙烷与含分子氧的气体中同时提供乙酸的较高选择性和产率，而不生产乙烯和CO等副产物。
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2.发明授权Catalysts methods for producing acetic acid from ethane oxidation using MO, V, PD and NB based catalysts, processes of making same and methods of using same 有权使用MO，V，PD和NB催化剂从乙烷氧化生产乙酸的催化剂方法，制备方法及其使用方法公开(公告)号：US06310241B1
公开(公告)日：2001-10-30
申请号：US09461086
申请日：1999-12-14
申请人： Khalid Karim , Edouard Mamedov , Mohammed H. Al-Hazmi , Anis H. Fakeeha , Mustaf A. Soliman , Yousef S. Al-Zeghayer , Ahmed S. Al-Fatish , Abdulsalm A. Al-Arify
发明人： Khalid Karim , Edouard Mamedov , Mohammed H. Al-Hazmi , Anis H. Fakeeha , Mustaf A. Soliman , Yousef S. Al-Zeghayer , Ahmed S. Al-Fatish , Abdulsalm A. Al-Arify
IPC分类号： C07C51215
CPC分类号： C07C51/215 , B01J23/002 , B01J23/6525 , B01J37/0236 , B01J2523/00 , Y02P20/582 , C07C53/08 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/824
摘要： An oxide catalyst comprising the elements Mo, V, Nb and Pd. The novel catalytic system provides both higher selectivity and yield of acetic acid in the low temperature one step vapor phase direct oxidation of ethane with molecular oxygen containing gas without production of side products such as ethylene and CO. The feed gas is contacted with a catalyst containing Mo, V, Nb, Pd and O in the ratio a:b:c:d:x where a is 1 to 5; b is 0 to 0.5; c is 0.01 to 0.5; d is 0 0.2 and x is a number determined by the valence of the other elements in the catalyst.
摘要翻译： 包含元素Mo，V，Nb和Pd的氧化物催化剂。 新型催化体系在低温一步气相直接氧化乙烷与含分子氧的气体中提供乙酸的较高选择性和产率，而不生产乙烯和CO等副产物，进料气体与含有 Mo，V，Nb，Pd和O，其比例a:b:c:d:x其中a为1至5; b为0〜0.5; c为0.01〜0.5; d为0 0.2，x为由催化剂中其它元素的化合价决定的数。
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3.发明授权Catalysts for the oxidation of ethane to acetic acid processes of making same and, processes of using same 失效用于将乙烷氧化成乙酸的催化剂制备方法及其使用方法
公开(公告)号：US6013597A
公开(公告)日：2000-01-11
申请号：US932075
申请日：1997-09-17
IPC分类号： B01J23/00 , B01J23/20 , B01J23/28 , B01J27/057 , B01J27/199 , C07C51/215 , C07C53/08 , B01J27/198 , B01J27/19
CPC分类号： B01J23/002 , B01J23/28 , B01J27/199 , C07C51/215 , B01J23/20 , B01J2523/00 , Y02P20/582
摘要： An oxide catalyst comprising the elements Mo, V and Nb with small amounts of phosphorus, boron, hafnium, Te and/or As. The modified catalyst provides both higher selectivity and yield of acetic acid in the low temperature oxidation of ethane with molecular oxygen-containing gas. A process for the higher selective production of acetic acid by the catalytic oxidation of ethane with oxygen, in the presence of the improved catalyst.
摘要翻译： 含有少量磷，硼，铪，Te和/或As的元素Mo，V和Nb的氧化物催化剂。 改性催化剂在含分子氧气体的乙烷的低温氧化中提供了较高的乙酸选择性和产率。 在改进的催化剂存在下，通过用氧催化氧化乙烷来选择性生产乙酸的方法。
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4.发明申请METHOD FOR PREPARING A CATALYST COMPOSITION FOR OLIGOMERIZATION OF ETHYLENE AND RESPECTIVE CATALYST COMPOSITION PRE-FORMATION UNIT 审中-公开制备乙烯和相应催化剂组合物预成型单元低聚物的催化剂组合物的方法公开(公告)号：US20140005034A1
公开(公告)日：2014-01-02
申请号：US13985664
申请日：2012-01-11
申请人： Anina Wöhl , Wolfgang Müller , Heinz Bölt , Andreas Meiswinkel , Uwe Rosenthal , Bernd Müller , Normen Peulecke , Christian Thaller , Marco Harff , Stephan Peitz , Fuad Mosa , Mohammed H. Al-Hazmi , Shahid Azam
发明人： Anina Wöhl , Wolfgang Müller , Heinz Bölt , Andreas Meiswinkel , Uwe Rosenthal , Bernd Müller , Normen Peulecke , Christian Thaller , Marco Harff , Stephan Peitz , Fuad Mosa , Mohammed H. Al-Hazmi , Shahid Azam
IPC分类号： C08F4/78
CPC分类号： C08F4/78 , B01J31/0279 , B01J31/0282 , B01J31/0288 , B01J31/143 , B01J31/189 , B01J2231/20 , B01J2531/62
摘要： The present invention relates to a method for preparing a catalyst composition for the oligomerization of ethylene and a respective catalyst composition pre-formation unit.
摘要翻译： 本发明涉及一种制备乙烯低聚催化剂组合物和各催化剂组合物预制单元的方法。
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5.发明授权Catalysts for producing acetic acid from ethane oxidation, processes of making same and method of using same 失效用于从乙烷氧化生产乙酸的催化剂，其制备方法及其使用方法
公开(公告)号：US6030920A
公开(公告)日：2000-02-29
申请号：US997913
申请日：1997-12-24
申请人： Khalid Karim , Edouard Mamedov , Mohammed H. Al-Hazmi , Anis H. Fakeeha , Mustaf A. Soliman , Yousef S. Al-Zeghayer , Ahmed S. Al-Fatish , Abdulsalm A. Al-Arify
发明人： Khalid Karim , Edouard Mamedov , Mohammed H. Al-Hazmi , Anis H. Fakeeha , Mustaf A. Soliman , Yousef S. Al-Zeghayer , Ahmed S. Al-Fatish , Abdulsalm A. Al-Arify
IPC分类号： B01J23/00 , B01J23/652 , B01J37/02 , C07C51/215 , B01J23/22 , B01J23/28
CPC分类号： C07C51/215 , B01J23/002 , B01J23/6525 , B01J37/0236 , B01J2523/00 , Y02P20/582
摘要： An oxide catalyst comprising the elements Mo, V, Nb and Pd. The novel catalytic system provides both higher selectivity and yield of acetic acid in the low temperature one step vapor phase direct oxidation of ethane with molecular oxygen containing gas without production of side products such as ethylene and CO.
摘要翻译： 包含元素Mo，V，Nb和Pd的氧化物催化剂。 新型催化体系在低温一步气相直接氧化乙烷与含分子氧的气体中同时提供乙酸的较高选择性和产率，而不生产乙烯和CO等副产物。
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公开(公告)号：US10882926B2
公开(公告)日：2021-01-05
申请号：US13985664
申请日：2012-01-11
申请人： Anina Wohl , Wolfgang Muller , Heinz Bolt , Andreas Meiswinkel , Uwe Rosenthal , Bernd Muller , Normen Peulecke , Christian Thaller , Marco Harff , Stephan Peitz , Fuad Mosa , Mohammed H. Al-Hazmi , Shahid Azam
发明人： Anina Wohl , Wolfgang Muller , Heinz Bolt , Andreas Meiswinkel , Uwe Rosenthal , Bernd Muller , Normen Peulecke , Christian Thaller , Marco Harff , Stephan Peitz , Fuad Mosa , Mohammed H. Al-Hazmi , Shahid Azam
摘要： The present invention relates to a method for preparing a catalyst composition for the oligomerization of ethylene and a respective catalyst composition pre-formation unit.
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7.发明授权Catalysts for the oxidation of ethane to acetic acid, processes of making same and processes of using same 失效用于将乙烷氧化成乙酸的催化剂，其制备方法和使用方法
公开(公告)号：US5907056A
公开(公告)日：1999-05-25
申请号：US085347
申请日：1998-05-27
IPC分类号： B01J23/00 , B01J23/20 , B01J23/28 , B01J27/057 , B01J27/199 , C07C51/215 , C07C53/08 , C07C51/16 , C07C51/235
CPC分类号： B01J23/002 , B01J23/28 , B01J27/199 , C07C51/215 , B01J23/20 , B01J2523/00 , Y02P20/582
摘要： An oxide catalyst comprising the elements Mo, V and Nb with small amounts of phosphorus, boron, hafnium, Te and/or As. The modified catalyst provides both higher selectivity and yield of acetic acid in the low temperature oxidation of ethane with molecular oxygen-containing gas. A process for the higher selective production of acetic acid by the catalytic oxidation of ethane with oxygen, in the presence of the improved catalyst.
摘要翻译： 含有少量磷，硼，铪，Te和/或As的元素Mo，V和Nb的氧化物催化剂。 改性催化剂在含分子氧气体的乙烷的低温氧化中提供了较高的乙酸选择性和产率。 在改进的催化剂存在下，通过用氧催化氧化乙烷来选择性生产乙酸的方法。
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