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公开(公告)号：US20110017907A1
公开(公告)日：2011-01-27
申请号：US12809867
申请日：2008-12-22
Applicant: Alexander A. Makarov , Dmitry E. Grinfield , Mikhail A. Monastyrskiy
Inventor： Alexander A. Makarov , Dmitry E. Grinfield , Mikhail A. Monastyrskiy
IPC: H01J49/40
CPC classification number: H01J49/406 , H01J49/061 , H01J49/405
Abstract: The present invention provides a method of reflecting ions in a multireflection time of flight mass spectrometer comprising providing an ion mirror having a plurality of electrodes, the ion mirror having a cross section with a first, minor axis (Y) and a second, major axis (X) each perpendicular to a longitudinal axis (Z) of the ion mirror which lies generally in the direction of time of flight separation of the ions in the mirror; guiding ions towards the ion mirror; applying a voltage to the electrodes so as to create an electric field which: (a) causes the mean trajectory of the ions to intersect a plane of symmetry of the ion mirror which contains the longitudinal (Z) and major axes (X) of the mirror; (b) causes the ions to reflect in the ion mirror; and (c) causes the ions to exit the ion mirror in a direction such that the mean trajectory of ions passing through the ion mirror has a component of movement in a direction (Y) perpendicular to and diverging from the said plane of symmetry thereof.
Abstract translation: 本发明提供一种在多反射飞行时间质谱仪中反射离子的方法，包括提供具有多个电极的离子反射镜，所述离子反射镜具有具有第一短轴（Y）和第二长轴（Y）的横截面 （X），每个垂直于离子镜的纵向轴线（Z），其通常位于反射镜中的离子的飞行时间分离方向上; 引导离子到离子镜; 向电极施加电压以产生电场：（a）使离子的平均轨迹与包含纵向（Z）和长轴（X）的离子镜的对称平面相交， 镜子; （b）使离子在离子反射镜中反射; 和（c）使得离子离开离子反射镜的方向，使得通过离子镜的离子的平均轨迹具有与所述对称平面垂直的方向（Y）和与其对称的发散方向的运动分量。
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公开(公告)号：US20130313424A1
公开(公告)日：2013-11-28
申请号：US13957776
申请日：2013-08-02
Applicant: Alexander A. MAKAROV , Dmitry E. GRINFELD , Mikhail A. MONASTYRSKIY
Inventor： Alexander A. MAKAROV , Dmitry E. GRINFELD , Mikhail A. MONASTYRSKIY
IPC: H01J49/40
CPC classification number: H01J49/406 , H01J49/061 , H01J49/405
Abstract: A method of reflecting ions in a multireflection time of flight mass spectrometer is disclosed. The method includes guiding ions toward an ion mirror having multiple electrodes, and applying a voltage to the ion mirror electrodes to create an electric field that causes the mean trajectory of the ions to intersect a plane of symmetry of the ion mirror and to exit the ion mirror, wherein the ion are spatially focussed by the mirror to a first location and temporally focused to a second location different from the first location. Apparatus for carrying out the method is also disclosed.
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公开(公告)号：US20150294849A1
公开(公告)日：2015-10-15
申请号：US14748582
申请日：2015-06-24
Applicant: Alexander A. MAKAROV , Dmitry E. GRINFELD , Mikhail A. MONASTYRSKIY
Inventor： Alexander A. MAKAROV , Dmitry E. GRINFELD , Mikhail A. MONASTYRSKIY
CPC classification number: H01J49/406 , H01J49/061 , H01J49/405
Abstract: A method of reflecting ions in a multireflection time of flight mass spectrometer is disclosed. The method includes guiding ions toward an ion mirror having multiple electrodes, and applying a voltage to the ion mirror electrodes to create an electric field that causes the mean trajectory of the ions to intersect a plane of symmetry of the ion mirror and to exit the ion mirror, wherein the ion are spatially focussed by the mirror to a first location and temporally focused to a second location different from the first location. Apparatus for carrying out the method is also disclosed.
Abstract translation: 公开了一种在多反射飞行时间质谱仪中反射离子的方法。 该方法包括将离子导向具有多个电极的离子反射镜，并向离子镜电极施加电压以产生电场，使得离子的平均轨迹与离子反射镜的对称平面相交并离开离子 反射镜，其中离子由反射镜在空间上聚焦到第一位置并且在时间上聚焦到与第一位置不同的第二位置。 还公开了用于执行该方法的装置。
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公开(公告)号：US08546754B2
公开(公告)日：2013-10-01
申请号：US13204043
申请日：2011-08-05
Applicant: Alexander A. Makarov , Mikhail A. Monastyrskiy , Dmitry E. Grinfeld
Inventor： Alexander A. Makarov , Mikhail A. Monastyrskiy , Dmitry E. Grinfeld
CPC classification number: H01J49/423 , H01J49/427
Abstract: An ion trap comprises substantially elongate electrodes 10, 20 some of which are curved along their axis of elongation and which define a trapping volume between them. The sectional area of this trapping volume towards the extremities of the trap in the direction of elongation is different to the sectional area away from its extremities (eg towards the middle of the trap). In a preferred embodiment, the trap has a plurality of elongate electrodes, wherein opposed electrodes have different radii of curvature so that the trap splays towards its extremities. Thereby, a wider mass range of ions can be trapped and ejected, a higher space charge capacity (for a given trap length) is provided, and sharper ion beam focussing on ejection is possible.
Abstract translation: 离子阱包括基本上细长的电极10,20，其中一些电极10,10沿着其伸长轴线弯曲并且在它们之间限定捕获体积。 该捕集体向伸长方向截面的横截面面积与远离其末端的截面积（例如朝向捕集阱的中部）不同。 在优选实施例中，陷阱具有多个细长电极，其中相对电极具有不同的曲率半径，使得陷阱向其四肢展开。 因此，可以捕获并喷射更宽质量范围的离子，提供更高的空间电荷容量（对于给定的陷阱长度），并且能够在喷射时聚焦更清晰的离子束。
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公开(公告)号：US20130187043A1
公开(公告)日：2013-07-25
申请号：US13790760
申请日：2013-03-08
Applicant: Alexander A. MAKAROV , Dmitry E. GRINFIELD , Mikhail A. MONASTYRSKIY
Inventor： Alexander A. MAKAROV , Dmitry E. GRINFIELD , Mikhail A. MONASTYRSKIY
CPC classification number: H01J49/406 , H01J49/061 , H01J49/405
Abstract: A method of reflecting ions in a multireflection time of flight mass spectrometer is disclosed. The method includes guiding ions toward an ion mirror having multiple electrodes, and applying a voltage to the ion mirror electrodes to create an electric field that causes the mean trajectory of the ions to intersect a plane of symmetry of the ion mirror and to exit the ion mirror, wherein the ion are spatially focussed by the mirror to a first location and temporally focused to a second location different from the first location. Apparatus for carrying out the method is also disclosed.
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Patent Agency Ranking
公开(公告)号：US08674293B2
公开(公告)日：2014-03-18
申请号：US13790760
申请日：2013-03-08
Applicant: Alexander A. Makarov , Dmitry E. Grinfeld , Mikhail A. Monastyrskiy
Inventor： Alexander A. Makarov , Dmitry E. Grinfeld , Mikhail A. Monastyrskiy
CPC classification number: H01J49/406 , H01J49/061 , H01J49/405
Abstract: A method of reflecting ions in a multireflection time of flight mass spectrometer is disclosed. The method includes guiding ions toward an ion mirror having multiple electrodes, and applying a voltage to the ion mirror electrodes to create an electric field that causes the mean trajectory of the ions to intersect a plane of symmetry of the ion mirror and to exit the ion mirror, wherein the ion are spatially focussed by the mirror to a first location and temporally focused to a second location different from the first location. Apparatus for carrying out the method is also disclosed.
Abstract translation: 公开了一种在多反射飞行时间质谱仪中反射离子的方法。 该方法包括将离子导向具有多个电极的离子反射镜，并向离子镜电极施加电压以产生电场，使得离子的平均轨迹与离子反射镜的对称平面相交并离开离子 反射镜，其中离子由反射镜在空间上聚焦到第一位置并且在时间上聚焦到与第一位置不同的第二位置。 还公开了用于执行该方法的装置。
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公开(公告)号：US08017909B2
公开(公告)日：2011-09-13
申请号：US12521706
申请日：2007-12-27
Applicant: Alexander Makarov , Mikhail A Monastyrskiy , Dmitry E. Grinfeld
Inventor： Alexander Makarov , Mikhail A Monastyrskiy , Dmitry E. Grinfeld
CPC classification number: H01J49/423 , H01J49/427
Abstract: An ion trap comprises substantially elongate electrodes 10, 20 some of which are curved along their axis of elongation and which define a trapping volume between them. The sectional area of this trapping volume towards the extremities of the trap in the direction of elongation is different to the sectional area away from its extremities (eg towards the middle of the trap). In a preferred embodiment, the trap has a plurality of elongate electrodes, wherein opposed electrodes have different radii of curvature so that the trap splays towards its extremities. Thereby, a wider mass range of ions can be trapped and ejected, a higher space charge capacity (for a given trap length) is provided, and sharper ion beam focussing on ejection is possible.
Abstract translation: 离子阱包括基本上细长的电极10,20，其中一些电极10,10沿着其伸长轴线弯曲并且在它们之间限定捕获体积。 该捕集体向伸长方向截面的横截面面积与远离其末端的截面积（例如朝向捕集阱的中部）不同。 在优选实施例中，陷阱具有多个细长电极，其中相对电极具有不同的曲率半径，使得陷阱向其四肢展开。 因此，可以捕获并喷射更宽质量范围的离子，提供更高的空间电荷容量（对于给定的陷阱长度），并且能够在喷射时聚焦更清晰的离子束。
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公开(公告)号：US08395115B2
公开(公告)日：2013-03-12
申请号：US12809867
申请日：2008-12-22
Applicant: Alexander A. Makarov , Dmitry E. Grinfield , Mikhail A. Monastyrskiy
Inventor： Alexander A. Makarov , Dmitry E. Grinfield , Mikhail A. Monastyrskiy
CPC classification number: H01J49/406 , H01J49/061 , H01J49/405
Abstract: The present invention provides a method of reflecting ions in a multireflection time of flight mass spectrometer comprising providing an ion mirror having a plurality of electrodes, the ion mirror having a cross section with a first, minor axis (Y) and a second, major axis (X) each perpendicular to a longitudinal axis (Z) of the ion mirror which lies generally in the direction of time of flight separation of the ions in the mirror; guiding ions towards the ion mirror; applying a voltage to the electrodes so as to create an electric field which: (a) causes the mean trajectory of the ions to intersect a plane of symmetry of the ion mirror which contains the longitudinal (Z) and major axes (X) of the mirror; (b) causes the ions to reflect in the ion mirror; and (c) causes the ions to exit the ion mirror in a direction such that the mean trajectory of ions passing through the ion mirror has a component of movement in a direction (Y) perpendicular to and diverging from the said plane of symmetry thereof.
Abstract translation: 本发明提供一种在多反射飞行时间质谱仪中反射离子的方法，包括提供具有多个电极的离子反射镜，所述离子反射镜具有具有第一短轴（Y）和第二长轴（Y）的横截面 （X），每个垂直于离子镜的纵向轴线（Z），其通常位于反射镜中的离子的飞行时间分离方向上; 引导离子到离子镜; 向电极施加电压以产生电场：（a）使离子的平均轨迹与包含纵向（Z）和长轴（X）的离子镜的对称平面相交， 镜子; （b）使离子在离子反射镜中反射; 和（c）使得离子离开离子反射镜的方向，使得通过离子镜的离子的平均轨迹具有与所述对称平面垂直的方向（Y）和与其对称的发散方向的运动分量。
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公开(公告)号：US20110284737A1
公开(公告)日：2011-11-24
申请号：US13204043
申请日：2011-08-05
Applicant: Alexander MAKAROV , Mikhail A. MONASTYRSKIY , Dmitry E. GRINFELD
Inventor： Alexander MAKAROV , Mikhail A. MONASTYRSKIY , Dmitry E. GRINFELD
IPC: H01J49/04
CPC classification number: H01J49/423 , H01J49/427
Abstract: An ion trap comprises substantially elongate electrodes 10, 20 some of which are curved along their axis of elongation and which define a trapping volume between them. The sectional area of this trapping volume towards the extremities of the trap in the direction of elongation is different to the sectional area away from its extremities (eg towards the middle of the trap). In a preferred embodiment, the trap has a plurality of elongate electrodes, wherein opposed electrodes have different radii of curvature so that the trap splays towards its extremities. Thereby, a wider mass range of ions can be trapped and ejected, a higher space charge capacity (for a given trap length) is provided, and sharper ion beam focussing on ejection is possible.
Abstract translation: 离子阱包括基本上细长的电极10,20，其中一些电极10,10沿着其伸长轴线弯曲并且在它们之间限定捕获体积。 该捕集体向伸长方向截面的横截面面积与远离其末端的截面积（例如朝向捕集阱的中部）不同。 在优选实施例中，陷阱具有多个细长电极，其中相对电极具有不同的曲率半径，使得陷阱向其四肢展开。 因此，可以捕获并喷射更宽质量范围的离子，提供更高的空间电荷容量（对于给定的陷阱长度），并且能够在喷射时聚焦更清晰的离子束。
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公开(公告)号：US20100320376A1
公开(公告)日：2010-12-23
申请号：US12521706
申请日：2007-12-27
Applicant: Alexander Makarov , Mikhail A. Monastyrskiy , Dmitry E. Grinfeld
Inventor： Alexander Makarov , Mikhail A. Monastyrskiy , Dmitry E. Grinfeld
CPC classification number: H01J49/423 , H01J49/427
Abstract: An ion trap comprises substantially elongate electrodes 10, 20 some of which are curved along their axis of elongation and which define a trapping volume between them. The sectional area of this trapping volume towards the extremities of the trap in the direction of elongation is different to the sectional area away from its extremities (eg towards the middle of the trap). In a preferred embodiment, the trap has a plurality of elongate electrodes, wherein opposed electrodes have different radii of curvature so that the trap splays towards its extremities. Thereby, a wider mass range of ions can be trapped and ejected, a higher space charge capacity (for a given trap length) is provided, and sharper ion beam focussing on ejection is possible.
Abstract translation: 离子阱包括基本上细长的电极10,20，其中一些电极10,10沿着其伸长轴线弯曲并且在它们之间限定捕获体积。 该捕集体向伸长方向截面的横截面面积与远离其末端的截面积（例如朝向捕集阱的中部）不同。 在优选实施例中，陷阱具有多个细长电极，其中相对电极具有不同的曲率半径，使得陷阱向其四肢展开。 因此，可以捕获并喷射更宽质量范围的离子，提供更高的空间电荷容量（对于给定的陷阱长度），并且能够在喷射时聚焦更清晰的离子束。
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