摘要:
The invention relates to a method for manufacturing an electrochemical cell comprising an anode and a cathode separated by a separator and a gel electrolyte. The method comprises the steps of assembling the electrodes and the separator, and injecting a liquid electrolyte composition between the electrodes, the liquid electrolyte composition comprising a polymer, an aprotic liquid solvent and a lithium salt, wherein the polymer in the liquid electrolyte composition has functional groups capable of polymerizing via cationic polymerization, and the cell is submitted to an electrochemical cycling comprising a charging step and a discharging step.
摘要:
A positive electrode for use in a lithium battery using water as a dispersion medium, not causing a problem of deteriorating the battery performance due to corrosion of a collector or the like and not forming unevenness on the coating surface, as well as a lithium battery using the positive electrode, the positive electrode used being formed from a positive electrode paste containing a positive electrode active material represented by the following formula (I), a binder ingredient comprising a water dispersible elastomer and a water soluble polymer as a viscosity improver, water as a dispersion medium and a dispersing agent: LixMPO4 (I) (in the general formula (I) above, M represents a metal atom containing at least one of metal atoms selected from the group consisting of Mn, Fe, Co, Ni, Cu, Mg, Zn, V, Ca, Sr, Ba, Ti, Al, Si, B and Mo, and 0≦x≦2).
摘要:
Polymeric compounds are provided the use of which expedites dissociation of an electrolytic salt. The polymeric compounds have a trivalent boron atom which is a Lewis acid. Transport rates of charge carrier ions can be controlled by trapping counter ions of charge carrier ions in the polymeric chain.
摘要:
Provided is a solid electrolyte having a reduced amount of non-crosslinked monomers, capable of being cured rapidly to have good film-forming ability, and having high electroconductivity. The solid electrolyte is prepared by crosslinking a composition that consists essentially of a polymer compound, a solvent and an electrolytic salt through exposure to active radiations and/or under heat, in which the polymer compound has four functional polymer chains of formula (I): R1 and R2 each represent a hydrogen atom or a lower alkyl group, R3 represents a hydrogen atom or a methyl group, m and n each represent 0 or an integer of 1 or more, and m+n≧35 in one polymer chain.
摘要翻译:本发明提供一种具有减少量的非交联单体的能够快速固化以具有良好的成膜能力并具有高导电性的固体电解质。 固体电解质通过将主要由高分子化合物,溶剂和电解质盐组成的组合物通过暴露于活性辐射和/或在加热下交联而制备,其中高分子化合物具有四个式(I)的功能性聚合物链: R 1和R 2各自表示氢原子或低级烷基,R 3表示氢原子或甲基,m和n各自表示0或1以上的整数,m + n> 35。
摘要:
The present invention provides a polymer gel electrolyte capable of inhibiting the cell expansion of a polymer secondary battery and improving the cycle characteristics and high-temperature storage characteristics of a polymer secondary battery. The present invention relates to a polymer gel electrolyte comprising an aprotic solvent; a supporting salt; a cyclic sulfonic acid ester which includes at least two sulfonyl groups; and a crosslinked polymer obtained by crosslinking a methacrylic acid ester polymer represented by general formula (1) below. In the general formula (1), n meets 1800
摘要:
Provided is an inexpensive and high-performance photoelectric conversion device of high practicability. The device comprises a semiconductor electrode, a counter electrode and an electrolyte layer held between the two electrodes, in which the electrolyte layer contains a compound of the following general formula (1) as an oxidation-reduction pair therein: (wherein M+represents an organic or inorganic cation; A represents an aromatic, non-aromatic, heteroaromatic or hetero-non-aromatic cyclic compound).
摘要:
An object of the present invention is to provide a polyether composition that can suppress reduction in a molecular weight of polyether having a low glass transition temperature and melting point. As a means of achieving this object, a polyether composition of the present invention contains polyether having a glass transition temperature of −50° C. or lower and a melting point of 55° C. or lower and, at the same time, contains at least one kind selected from the group consisting of compounds represented by the specified three general formulas.
摘要:
Provided is a dye-sensitized solar cell having improved stability of safety and performance by employing a non-volatile molten salt which makes it possible to facilitate the control over the composition of gel electrolyte, simplify the working step during production and give an excellent conversion efficiency. The dye-sensitized solar cell comprises a transparent substrate, a transparent electrically-conductive membrane formed on the surface of the transparent substrate and an electrically-conductive substrate disposed opposed to the transparent electrically-conductive membrane and further comprises a porous semiconductor layer having a dye adsorbed thereto and an electrolyte provided interposed between the aforesaid transparent electrically-conductive membrane and the electrically-conductive substrate, wherein the electrolyte comprises a molten salt incorporated in a network structure obtained by crosslinking at least one kind of Compound A having isocyanate group with at least one kind of Compound B having amino group to solve the aforesaid problems. Or the electrolyte comprises a molten salt incorporated in a network structure obtained by crosslinking at least one kind of Compound A having isocyanate group with at least one kind of Compound C having carboxyl group and/or hydroxyl group, at least one of Compound A and Compound C constituting the electrolyte has a polymer structure having a molecular weight of from 500 to 100,000 and a part or whole of the polymer structure comprises one or more selected from the group consisting of polyether, polyester, polycaprolactone, polysiloxane, polyvinylpyrrolidone, polycarbonate and polyphosphazene.
摘要:
The invention provides a dye-sensitized solar cell including a transparent substrate, a transparent conductive film formed on a surface thereof, and a conductive substrate provided in a position opposed to the transparent conductive film, and further having a porous semiconductor layer, in which a dye is adsorbed, and an electrolyte between the transparent conductive film and the conductive substrate, wherein the electrolyte is a gel electrolyte containing a redox material and a solvent capable of dissolving the same in a network structure formed by crosslinking at least one kind of compound A including an isocyanate group and at least one kind of compound B including an amino group. Otherwise, the electrolyte is a gel electrolyte containing a redox material and a solvent capable of dissolving the same in a network structure formed by crosslinking at least one kind of compound A including an isocyanate group and at least one kind of compound C including a carboxyl group and/or a hydroxyl group. Otherwise, the electrolyte is a polymer solid electrolyte containing redox material in a network structure formed by crosslinking at least one kind of compound A including an isocyanate group and at least one kind of compound D reactive with the isocyanate group. The configuration of the invention facilitates an electrolyte composition of the dye-sensitized solar cell, and simplifies process steps in the manufacture.
摘要:
The present invention provides a production process, in which, when an ethylene oxide copolymer is obtained, conditions for obtaining this copolymer having a desirable molecular weight with ease and good reproducibility are provided. The production process for an ethylene oxide copolymer, according to the present invention, comprises the step of carrying out polymerization of a monomer mixture under stirring in a solvent, thereby obtaining the ethylene oxide copolymer, wherein the monomer mixture includes ethylene oxide and a substituted oxirane compound of a structural formula (1) as essential raw materials; with the production process being characterized in that the stirring is carried out by a stirring power of not less than 0.6 kW/m3.
摘要翻译:本发明提供一种制备方法,其中当获得环氧乙烷共聚物时,提供了获得具有所需分子量并且具有良好重现性的共聚物的条件。 根据本发明的环氧乙烷共聚物的制备方法包括在溶剂中在搅拌下进行单体混合物聚合的步骤,从而得到环氧乙烷共聚物,其中单体混合物包括环氧乙烷和取代的环氧乙烷 结构式(1)的化合物作为必需的原料; 其制造方法的特征在于通过不低于0.6kW / m 3的搅拌功率进行搅拌。