公开(公告)号：US09780375B2

公开(公告)日：2017-10-03

申请号：US12993729

申请日：2009-05-19

申请人： Takaki Mori ,  Toshiyuki Goshima ,  Maw Soe Win

发明人： Takaki Mori ,  Toshiyuki Goshima ,  Maw Soe Win

IPC分类号： H01M4/583 ,  H01B1/24 ,  B82Y30/00 ,  H01M4/62 ,  H01M4/13 ,  H01M10/052 ,  H01M4/04 ,  H01M4/133 ,  H01M4/1393

CPC分类号： H01M4/625 ,  H01M4/0404 ,  H01M4/13 ,  H01M4/133 ,  H01M4/1393 ,  H01M4/622 ,  H01M10/052

摘要： Disclosed is a highly reliable secondary battery, as well as an electrode and a conductive agent used therefor, which battery has a long cycle life and is also less likely to be damaged or rupture even when the battery temperature becomes abnormally high. The conductive agent of the battery electrode contains, as the main component, a reaction product between a π-conjugated carbon material and a soluble polyimide, preferably a soluble block copolymerized polyimide. The battery electrode is formed by coating a composition containing this conductive agent and an electrode active substance onto a current collector. The battery comprises this electrode.

公开(公告)号：US08779085B2

公开(公告)日：2014-07-15

申请号：US13266925

申请日：2010-04-30

申请人： Toshiyuki Goshima ,  Maw Soe Win ,  Eika Kyo

发明人： Toshiyuki Goshima ,  Maw Soe Win ,  Eika Kyo

IPC分类号： C08G69/36

CPC分类号： C08G69/36 ,  C08G18/10 ,  C08G18/44 ,  C08G73/1035 ,  C08G73/1042 ,  C08G73/1078 ,  C08J5/18 ,  C08J2379/08 ,  C08L79/08 ,  C09D179/08 ,  H05K3/285 ,  H05K2201/0154 ,  C08G18/346

摘要： The present invention discloses a method of producing a modified polyimide comprising a polycarbonate, which modified polyimide has excellent electric properties and adhesion as well as excellent heat resistance, flexibility, bending property, low warping, chemical resistance and storage stability; and the modified polyimide. Also disclosed are a composition comprising the modified polyimide and used thereof. According to the method in which an isocyanate-terminated oligomer comprising a polycarbonate component having excellent flexibility is allowed to react with a tetracarboxylic dianhydride to synthesize a tetracarboxylic dianhydride oligomer comprising the polycarbonate component and the thus obtained oligomer is then further allowed to react with an aromatic diamine and aromatic tetracarboxylic dianhydride to produce a polyimide block copolymer, by selecting the aromatic diamine from a wide range of selectable aromatic diamines, an excellent modified polyimide satisfying all of the above-described various characteristics can be produced.

摘要翻译： 本发明公开了一种改性聚酰亚胺的制造方法，该改性聚酰亚胺具有优异的电性能和粘合性，耐热性，柔软性，弯曲性，低翘曲性，耐化学性和储存稳定性优异。 和改性聚酰亚胺。 还公开了包含改性聚酰亚胺并使用的组合物。 根据其中含有具有优异柔性的聚碳酸酯组分的异氰酸酯封端的低聚物与四羧酸二酐反应以合成包含聚碳酸酯组分的四羧酸二酐低聚物和由此得到的低聚物进一步与芳族化合物反应的方法 二胺和芳香族四羧酸二酐以制备聚酰亚胺嵌段共聚物，通过从宽范围的可选择的芳族二胺中选择芳族二胺，可以制备出满足所有上述各种特性的优异的改性聚酰亚胺。

公开(公告)号：US20110189540A1

公开(公告)日：2011-08-04

申请号：US12993729

申请日：2009-05-19

申请人： Takaki Mori ,  Toshiyuki Goshima ,  Maw Soe Win

发明人： Takaki Mori ,  Toshiyuki Goshima ,  Maw Soe Win

IPC分类号： H01M4/583 ,  H01B1/24 ,  B82Y30/00

CPC分类号： H01M4/625 ,  H01M4/0404 ,  H01M4/13 ,  H01M4/133 ,  H01M4/1393 ,  H01M4/622 ,  H01M10/052

摘要： Disclosed is a highly reliable secondary battery, as well as an electrode and a conductive agent used therefor, which battery has a long cycle life and is also less likely to be damaged or rupture even when the battery temperature becomes abnormally high. The conductive agent of the battery electrode contains, as the main component, a reaction product between a π-conjugated carbon material and a soluble polyimide, preferably a soluble block copolymerized polyimide. The battery electrode is formed by coating a composition containing this conductive agent and an electrode active substance onto a current collector. The battery comprises this electrode.

摘要翻译： 公开了一种高度可靠的二次电池，以及用于其的电极和导电剂，该电池具有长的循环寿命，并且即使当电池温度异常高时也不太可能损坏或破裂。 电池电极的导电剂含有共轭碳材料和可溶性聚酰亚胺（优选可溶性嵌段共聚聚酰亚胺）之间的反应产物作为主要成分。 电池电极通过将含有该导电剂的组合物和电极活性物质涂布在集电体上而形成。 电池包括该电极。

公开(公告)号：US20110127077A1

公开(公告)日：2011-06-02

申请号：US13025581

申请日：2011-02-11

申请人： Maw Soe WIN ,  Toshiyuki Goshima ,  Eika Kyo ,  Shintaro Nakajima ,  Noriki Hayashi ,  Tohru Kashiwagi ,  Kenji Miyazaki ,  Katsuya Yamada ,  Naoyuki Yamabayashi ,  Shoji Nakagama ,  Hiroshi Okuyama ,  Fumio Kasabo ,  Ippei Tanaka

发明人： Maw Soe WIN ,  Toshiyuki Goshima ,  Eika Kyo ,  Shintaro Nakajima ,  Noriki Hayashi ,  Tohru Kashiwagi ,  Kenji Miyazaki ,  Katsuya Yamada ,  Naoyuki Yamabayashi ,  Shoji Nakagama ,  Hiroshi Okuyama ,  Fumio Kasabo ,  Ippei Tanaka

IPC分类号： H05K1/00 ,  C08K5/101 ,  C08K5/3492 ,  C08K5/5399 ,  C08K5/3475 ,  C08L79/08 ,  B05D5/00

CPC分类号： C09D11/102 ,  H05K3/28 ,  H05K2201/0154 ,  H05K2203/0783

摘要： The object is to provide a polyimide ink composition having good printing properties and good continuous priming properties, which composition can be dried at a low temperature of not higher than 220° C., and which composition gives a coating film, after being dried, having excellent dimensional stability, heat resistance, low modulus of elasticity, flexibility, resistance to warping, chemical resistance, adhesiveness with substrates, and plating resistance. This object is accomplished by a polyimide ink composition for printing, comprising a mixed solvent containing an benzoic acid ester solvent and a glyme solvent, and a polyimide soluble in the mixed solvent; wherein the polyimide is obtained by polycondensing a polyimide oligomer with a tetracarboxylic dianhydride component(s) and/or a diamine component(s) having no siloxane bond in molecular skeleton thereof, the polyimide oligomer being prepared by polycondensing a tetracarboxylic dianhydride component(s) and a diamine component(s) having siloxane bonds in molecular skeleton thereof in the presence of a base catalyst(s), or a mixed catalyst including a lactone(s) and/or an acidic compound(s) and a base(s); the content of the diamine component(s) having siloxane bonds based on the total diamine components being 15 to 85% by weight.

摘要翻译： 本发明的目的是提供具有良好的印刷性能和良好的连续起始性能的聚酰亚胺油墨组合物，该组合物可以在不高于220℃的低温下干燥，并且该组合物在干燥后得到涂膜，具有 优异的尺寸稳定性，耐热性，低弹性模量，柔软性，抗翘曲性，耐化学性，与基材的粘合性和耐电镀性。 该目的通过用于印刷的聚酰亚胺油墨组合物实现，其包含含有苯甲酸酯溶剂和甘醇二甲醚溶剂的混合溶剂和可溶于混合溶剂的聚酰亚胺; 其中所述聚酰亚胺是通过将聚酰亚胺低聚物与其分子骨架中不含硅氧烷键的四羧酸二酐组分和/或二胺组分缩聚得到的，所述聚酰亚胺低聚物是通过使四羧酸二酐组分缩聚而制备的， 和在其基础催化剂存在下的分子骨架中具有硅氧烷键的二胺组分或包含内酯和/或酸性化合物和碱的混合催化剂， ; 基于总二胺成分的具有硅氧烷键的二胺成分的含量为15〜85重量％。

公开(公告)号：US08987376B2

公开(公告)日：2015-03-24

申请号：US13035536

申请日：2011-02-25

申请人： Toshiyuki Goshima ,  Sigemasa Segawa ,  Maw Soe Win ,  Junichi Yamashita ,  Ken Takanashi

发明人： Toshiyuki Goshima ,  Sigemasa Segawa ,  Maw Soe Win ,  Junichi Yamashita ,  Ken Takanashi

IPC分类号： C08G69/26 ,  C08G73/10 ,  C08L79/08 ,  C09D179/08 ,  H01L23/31

CPC分类号： C08G73/1042 ,  C08G73/106 ,  C08L79/08 ,  C09D179/08 ,  H01L23/3157 ,  H01L2924/0002 ,  H01L2924/09701 ,  H01L2924/19041 ,  H01L2924/00

摘要： Disclosed is a polyimide composition for semiconductor devices, which has a rheological characteristics suited for screen printing and dispense coating, which has an improved wetting property with various coating bases, by which continuous printing of 500 times or more can be attained, with which blisters, cissing and pinholes are not generated after printing and drying or during drying or curing, which can coat a desired area. A method of forming a film in a semiconductor and semiconductors having the film formed by this method as an insulation film, protective film or the like are also disclosed. The composition for semiconductor devices contains a mixed solvent of a first organic solvent (A) and a second organic solvent (B); and a polyimide resin having at least one group selected from the group consisting of alkyl groups and perfluoroalkyl groups in recurring units, and having thixotropic property, the polyimide resin being dissolved in the mixed solvent.

摘要翻译： 公开了一种半导体器件的聚酰亚胺组合物，其具有适用于丝网印刷和分配涂料的流变特性，其具有改善的各种涂层基底的润湿性能，通过该组合物可获得500次以上的连续印刷， 在印刷和干燥之后或在干燥或固化期间不产生可以涂覆所需区域的发丝和针孔。 还公开了一种在半导体中形成膜的方法以及通过该方法形成的膜作为绝缘膜，保护膜等的半导体。 半导体器件用组合物含有第一有机溶剂（A）和第二有机溶剂（B）的混合溶剂。 和具有至少一个选自重复单元中的烷基和全氟烷基的基团并且具有触变性的聚酰亚胺树脂，聚酰亚胺树脂溶解在混合溶剂中。

公开(公告)号：US08349537B2

公开(公告)日：2013-01-08

申请号：US13007373

申请日：2011-01-14

申请人： Maw Soe Win ,  Toshiyuki Goshima ,  Sigemasa Segawa ,  Shintaro Nakajima ,  Eika Kyo ,  Yoshikazu Nishikawa ,  Shuzo Waki

发明人： Maw Soe Win ,  Toshiyuki Goshima ,  Sigemasa Segawa ,  Shintaro Nakajima ,  Eika Kyo ,  Yoshikazu Nishikawa ,  Shuzo Waki

IPC分类号： G03F7/00 ,  G03F7/004 ,  C08G77/04

CPC分类号： H05K3/287 ,  C08G73/106 ,  C08G77/455 ,  C08L79/08 ,  C08L83/10 ,  C09D11/101

摘要： Disclosed is a photosensitive ink which can form a coated film that is excellent in insulation properties, heat resistance, low warping, low elasticity and adhesion with the substrate, when used as an ink for screen printing, and with which clogging of the screen, bleeding, blur, chipping and the like are unlikely to occur even when the screen printing is repeatedly carried out, so that which has an excellent ease of handling in printing. The ink composition comprises 100 parts by weight of an organic solvent-soluble polyimide block copolymer(s), and 1 to 100 parts by weight of a photoacid generator(s). The polyimide block copolymer(s) and the photoacid generator(s) are dissolved in an organic solvent. The polyimide block copolymer(s) contain(s) in its molecular skeleton a diamine having a siloxane bond, and an aromatic diamine having a hydroxyl group(s) and/or carboxyl group(s) at ortho-position with respect to an amino group.

摘要翻译： 公开了一种感光油墨，当用作丝网印刷的油墨时，可以形成绝缘性能，耐热性，低翘曲性，低弹性和与基材的粘合性优异的涂膜，并且使丝网堵塞，渗色 ，即使重复执行丝网印刷也不可能发生模糊，碎片等，从而在印刷中具有极好的处理容易性。 油墨组合物包含100重量份的有机溶剂可溶性聚酰亚胺嵌段共聚物和1至100重量份的光酸产生剂。 将聚酰亚胺嵌段共聚物和光酸产生剂溶解在有机溶剂中。 聚酰亚胺嵌段共聚物在其分子骨架中含有具有硅氧烷键的二胺和相对于氨基的邻位羟基和/或羧基的芳族二胺 组。

公开(公告)号：US20120097435A1

公开(公告)日：2012-04-26

申请号：US13318058

申请日：2010-04-30

申请人： Toshiyuki Goshima ,  Maw Soe Win ,  Sigemasa Segawa ,  Eika Kyo

发明人： Toshiyuki Goshima ,  Maw Soe Win ,  Sigemasa Segawa ,  Eika Kyo

IPC分类号： H05K1/03 ,  G03F7/022 ,  G03F7/008 ,  G03F7/004 ,  G03F7/20

CPC分类号： C08L79/08 ,  C08G18/10 ,  C08G18/346 ,  C08G18/44 ,  C08G18/73 ,  C08G18/7678 ,  C08G73/1035 ,  C08G73/1042 ,  G03F7/0233 ,  G03F7/40 ,  H05K3/287 ,  H05K2201/0154 ,  Y10S430/107

摘要： Disclosed are: a photosensitive modified polyimide resin composition having photo-fabrication property, which is excellent in the electric properties and adhesion as well as in the heat resistance, flexibility, bending property, low warping, chemical resistance and storage stability; a resin film formed from the composition; and a printed circuit board, flexible printed circuit board (FPC) and the like which comprises the film as an insulating protective film and/or interlayer insulation film. The photosensitive modified polyimide resin composition comprises a modified polyimide of a specific structure having a flexible structure such as polycarbonate; a photosensitizer; a curing agent; and a solvent.

摘要翻译： 公开了具有光电性能和粘合性以及耐热性，柔软性，弯曲性，低翘曲性，耐化学性和储存稳定性优异的光致改性聚酰亚胺树脂组合物。 由该组合物形成的树脂膜; 以及包括作为绝缘保护膜和/或层间绝缘膜的膜的印刷电路板，柔性印刷电路板（FPC）等。 感光改性聚酰亚胺树脂组合物包含具有柔性结构的特定结构的改性聚酰亚胺，如聚碳酸酯; 光敏剂; 固化剂; 和溶剂。

公开(公告)号：US20110213075A1

公开(公告)日：2011-09-01

申请号：US13035536

申请日：2011-02-25

申请人： Toshiyuki GOSHIMA ,  Sigemasa Segawa ,  Maw Soe Win ,  Junichi Yamashita ,  Ken Takanashi

发明人： Toshiyuki GOSHIMA ,  Sigemasa Segawa ,  Maw Soe Win ,  Junichi Yamashita ,  Ken Takanashi

IPC分类号： C08L79/08 ,  C08L83/08 ,  H01L21/56

CPC分类号： C08G73/1042 ,  C08G73/106 ,  C08L79/08 ,  C09D179/08 ,  H01L23/3157 ,  H01L2924/0002 ,  H01L2924/09701 ,  H01L2924/19041 ,  H01L2924/00

摘要： Disclosed is a polyimide composition for semiconductor devices, which has a rheological characteristics suited for screen printing and dispense coating, which has an improved wetting property with various coating bases, by which continuous printing of 500 times or more can be attained, with which blisters, cissing and pinholes are not generated after printing and drying or during drying or curing, which can coat a desired area. A method of forming a film in a semiconductor and semiconductors having the film formed by this method as an insulation film, protective film or the like are also disclosed. The composition for semiconductor devices contains a mixed solvent of a first organic solvent (A) and a second organic solvent (B); and a polyimide resin having at least one group selected from the group consisting of alkyl groups and perfluoroalkyl groups in recurring units, and having thixotropic property, the polyimide resin being dissolved in the mixed solvent.

摘要翻译： 公开了一种半导体器件的聚酰亚胺组合物，其具有适用于丝网印刷和分配涂料的流变特性，其具有改善的各种涂层基底的润湿性能，通过该组合物可获得500次以上的连续印刷， 在印刷和干燥之后或在干燥或固化期间不产生可以涂覆所需区域的发丝和针孔。 还公开了一种在半导体中形成膜的方法以及通过该方法形成的膜作为绝缘膜，保护膜等的半导体。 半导体器件用组合物含有第一有机溶剂（A）和第二有机溶剂（B）的混合溶剂。 和具有至少一个选自重复单元中的烷基和全氟烷基的基团并且具有触变性的聚酰亚胺树脂，聚酰亚胺树脂溶解在混合溶剂中。

公开(公告)号：US20130233381A1

公开(公告)日：2013-09-12

申请号：US13822941

申请日：2011-09-20

申请人： Maw Soe Win ,  Toshiyuki Goshima ,  Takahiro Sato

发明人： Maw Soe Win ,  Toshiyuki Goshima ,  Takahiro Sato

IPC分类号： H01L31/0216

CPC分类号： H01L31/02167 ,  C08G73/1039 ,  C08G73/1042 ,  C08G73/1046 ,  C08G73/105 ,  C08G73/106 ,  C08G73/1064 ,  C09D179/08 ,  H01L31/022441 ,  H01L31/0682 ,  Y02E10/547

摘要： Disclosed is a polyimide resin composition for forming an insulation layer in a solar cell, which has an optimal rheological characteristics for screen printing and the like, which has an improved wetting property with various coating substrates, by which continuous printing of 500 times or more can be attained, with which blisters, cissing and pinholes are not generated after printing and drying or during drying or curing, which can coat a predetermined area. A method of forming an insulation layer in a solar cell and a solar cell having the insulation layer formed by this method are also disclosed. The polyimide resin composition for forming an insulation layer in a solar cell contains a mixed solvent of a first organic solvent (A) and a second organic solvent (B); and a heat-resistant polyimide resin having at least one group selected from the group consisting of alkyl groups and perfluoroalkyl groups in recurring units, and having thixotropic property, the polyimide resin being dissolved in the mixed solvent.

摘要翻译： 公开了一种用于在太阳能电池中形成绝缘层的聚酰亚胺树脂组合物，其具有丝网印刷等的最佳流变特性，其具有改善的各种涂布基材的润湿性能，通过其可以连续印刷500次以上 可以在印刷和干燥之后或干燥或固化期间不产生水泡，裂口和针孔，这可以涂覆预定区域。 还公开了一种在太阳能电池中形成绝缘层的方法和具有通过该方法形成的绝缘层的太阳能电池。 在太阳能电池中形成绝缘层的聚酰亚胺树脂组合物含有第一有机溶剂（A）和第二有机溶剂（B）的混合溶剂。 和具有至少一个选自重复单元中的烷基和全氟烷基的基团并具有触变性的耐热聚酰亚胺树脂，聚酰亚胺树脂溶解在混合溶剂中。

公开(公告)号：US20090229870A1

公开(公告)日：2009-09-17

申请号：US12470399

申请日：2009-05-21

申请人： Maw Soe Win ,  Toshiyuki Goshima ,  Eika Kyo ,  Shintaro Nakajima ,  Noriki Hayashi ,  Tohru Kashiwagi ,  Kenji Miyazaki ,  Katsuya Yamada ,  Naoyuki Yamabayashi ,  Shoji Nakagama ,  Hiroshi Okuyama ,  Fumio Kasabo ,  Ippei Tanaka

发明人： Maw Soe Win ,  Toshiyuki Goshima ,  Eika Kyo ,  Shintaro Nakajima ,  Noriki Hayashi ,  Tohru Kashiwagi ,  Kenji Miyazaki ,  Katsuya Yamada ,  Naoyuki Yamabayashi ,  Shoji Nakagama ,  Hiroshi Okuyama ,  Fumio Kasabo ,  Ippei Tanaka

IPC分类号： H05K1/00 ,  C09D131/06 ,  B05D5/00

CPC分类号： C09D11/102 ,  H05K3/28 ,  H05K2201/0154 ,  H05K2203/0783

摘要： The object is to provide a polyimide ink composition having good printing properties and good continuous printing properties, which composition can be dried at a low temperature of not higher than 220° C., and which composition gives a coating film, after being dried, having excellent dimensional stability, heat resistance, low modulus of elasticity, flexibility, resistance to warping, chemical resistance, adhesiveness with substrates, and plating resistance. This object is accomplished by a polyimide ink composition for printing, comprising a mixed solvent containing an benzoic acid ester solvent and a glyme solvent, and a polyimide soluble in the mixed solvent; wherein the polyimide is obtained by polycondensing a polyimide oligomer with a tetracarboxylic dianhydride component(s) and/or a diamine component(s) having no siloxane bond in molecular skeleton thereof, the polyimide oligomer being prepared by polycondensing a tetracarboxylic dianhydride component(s) and a diamine component(s) having siloxane bonds in molecular skeleton thereof in the presence of a base catalyst(s), or a mixed catalyst including a lactone(s) and/or an acidic compound(s) and a base(s); the content of the diamine component(s) having siloxane bonds based on the total diamine components being 15 to 85% by weight.

摘要翻译： 本发明的目的是提供具有良好的印刷性能和良好的连续印刷性能的聚酰亚胺油墨组合物，该组合物可以在不高于220℃的低温下干燥，并且该组合物在干燥后得到涂膜， 优异的尺寸稳定性，耐热性，低弹性模量，柔软性，抗翘曲性，耐化学性，与基材的粘合性和耐电镀性。 该目的通过用于印刷的聚酰亚胺油墨组合物实现，其包含含有苯甲酸酯溶剂和甘醇二甲醚溶剂的混合溶剂和可溶于混合溶剂的聚酰亚胺; 其中所述聚酰亚胺是通过将聚酰亚胺低聚物与其分子骨架中不含硅氧烷键的四羧酸二酐组分和/或二胺组分缩聚得到的，所述聚酰亚胺低聚物是通过使四羧酸二酐组分缩聚而制备的， 和在其基础催化剂存在下的分子骨架中具有硅氧烷键的二胺组分或包含内酯和/或酸性化合物和碱的混合催化剂， ; 基于总二胺成分的具有硅氧烷键的二胺成分的含量为15〜85重量％。