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    Surfactants
    3.
    发明授权
    Surfactants 有权
    表面活性剂

    公开(公告)号：US06841655B1

    公开(公告)日：2005-01-11

    申请号：US10451149

    申请日：2001-12-25

    申请人： Tetsuya Gota ,  Kazushi Kobayashi ,  Kaoru Komiya ,  Masahide Tsuzuki ,  Takeaki Mizutari

    发明人： Tetsuya Gota ,  Kazushi Kobayashi ,  Kaoru Komiya ,  Masahide Tsuzuki ,  Takeaki Mizutari

    IPC分类号： B01F17/00 ,  B01F17/18 ,  B01F17/42 ,  C08F2/24 ,  C08F2/26 ,  C08F2/28 ,  C08F220/28 ,  C08G65/34

    CPC分类号： C08F2/24 ,  B01F17/0021 ,  B01F17/0028 ,  B01F17/0035 ,  B01F17/0042 ,  B01F17/005 ,  B01F17/0057 ,  B01F17/0064 ,  C08F220/28

    摘要： Disclosed are surfactants represented by the following formula (1): wherein R1 represents a branched aliphatic hydrocarbon group, a secondary aliphatic hydrocarbon group or a branched aliphatic acyl group, AO and AO′ each independently represents an oxyalkylene group having 2 to 4 carbon atoms, L represents a group represented by formula (2) to be described below, z stands for a number of from 1 to 10, X represents a hydrogen atom or an ionic hydrophilic group, m stands for a number of from 0 to 1,000, and n stands for a number of from 0 to 1,000. wherein R2 and R3 each independently represents a hydrogen atom or a methyl group, x stands for a number of from 0 to 12, and y stands for a number of 0 or 1. These surfactants do not contain any phenyl ether group considered to have significant effects on the environment, such as a nonylphenyl group, and have performance comparable with reactive surfactants containing one or more phenyl ether groups. Emulsifiers for emulsion polymerization, dispersants for dispersion polymerization and resin modifiers, all of which contain the surfactants, are also disclosed.

    摘要翻译： 公开了由下式（1）表示的表面活性剂：其中R 1表示支链脂族烃基，脂肪族脂族烃基或支链脂肪族酰基，AO和AO'各自独立地表示具有2〜4个碳原子的氧化烯基 碳原子，L表示由下述式（2）表示的基团，z表示1至10的数，X表示氢原子或离子性亲水基团，m表示0至1,000的数 ，n表示0〜1,000的数。R 2和R 3各自独立地表示氢原子或甲基，x表示0〜12的数，y表示 这些表面活性剂不包含被认为对环境具有显着影响的任何苯基醚基团，例如壬基苯基，并具有与含有一个或多个苯基醚基团的反应性表面活性剂相当的性能。 还公开了用于乳液聚合的乳化剂，用于分散聚合的分散剂和树脂改性剂，所有这些都包含表面活性剂。

    Solution polymerization with reactive modifier
    4.
    发明授权
    Solution polymerization with reactive modifier 失效
    溶液聚合反应性改性剂

    公开(公告)号：US5371159A

    公开(公告)日：1994-12-06

    申请号：US12529

    申请日：1993-02-02

    申请人： Masahide Tsuzuki ,  Kaoru Komiya

    发明人： Masahide Tsuzuki ,  Kaoru Komiya

    IPC分类号： C08F16/26 ,  C08F16/30 ,  C08F30/02 ,  C08F290/06 ,  C08G65/28 ,  C08F216/20 ,  C08F228/00 ,  C08F230/02

    CPC分类号： C08F16/26 ,  C08F16/30 ,  C08F290/062 ,  C08F30/02

    摘要： An improved solution polymerization process is provided wherein vinyl monomers are polymerized in the presence of at least one reactive modifier which is a substituted alpha-olefin that incorporates at least three ether groups, is hydrophilic, and has a molecular weight of at least about 200. The modified vinyl polymers so produced are characterized by various improved physical properties including, in particular, electrical characteristics such as antistatic capacity.

    摘要翻译： 提供了一种改进的溶液聚合方法，其中乙烯基单体在至少一种反应性改性剂存在下聚合，所述反应性改性剂是引入至少三个醚基团的取代的α-烯烃，是亲水的，并且具有至少约200的分子量。 如此制备的改性乙烯基聚合物的特征在于各种改进的物理性质，特别包括诸如抗静电能力的电特性。

    Surfactant, emulsifier for emulsion polymerization, dispersant for suspension polymerization and modifier for resin modification
    5.
    发明授权
    Surfactant, emulsifier for emulsion polymerization, dispersant for suspension polymerization and modifier for resin modification 失效
    表面活性剂，乳液聚合乳化剂，悬浮聚合用分散剂和树脂改性改性剂

    公开(公告)号：US5990342A

    公开(公告)日：1999-11-23

    申请号：US683776

    申请日：1996-07-16

    申请人： Masahide Tsuzuki ,  Kaoru Komiya

    发明人： Masahide Tsuzuki ,  Kaoru Komiya

    IPC分类号： B01F17/42 ,  B01F17/52 ,  C08F2/18 ,  C08F2/20 ,  C08F2/24 ,  C08F2/26 ,  C07C69/73 ,  C07C69/52

    CPC分类号： C08F2/26

    摘要： A surfactant, an emusifier for emulsion polymerization, a dispersant for suspension polymerization and a modifier for modification of resin properties are disclosed, each of these agents being comprised of a novel compound having a dibasic carboxyl group. The compound is represented by Formula (1)[X--O--(R.sup.1 O).sub.m --OC--R.sup.2 --COO].sub.y M (1)where M is a hydrogen atom, a metal atom or a quaternary nitrogen-containing group, y is equal to the valence of M, R.sup.1 is at least one hydrocarbon group, R.sup.2 is a moiety of a dibasic acid or a moiety of its anhydride, m is 0 or an integer of 1 to 1,000, and X is a hydrocarbon group having at least one polymerizable double bond of carbon--ncarbon which may contain an oxygen atom and a fluorine atom.

    摘要翻译： 公开了一种表面活性剂，用于乳液聚合的乳化剂，用于悬浮聚合的分散剂和用于改性树脂性质的改性剂，这些试剂均由具有二元羧基的新化合物组成。 该化合物由式（1）[XO-（R1O）m-OC-R2-COO] yM（1）表示，其中M是氢原子，金属原子或含季氮的基团，y等于 M的价数，R 1是至少一个烃基，R 2是二元酸的部分或其酸酐的部分，m是0或1〜1000的整数，X是具有至少一个可聚合双键的烃基 可以含有氧原子和氟原子的碳 - 碳的键。