COMPOSITION COMPRISING AS THE AQUEOUS DISPERSION PREFERABLY (METH)ACRYLATE POLYMERS CONTAINING BENZOPHENONE IN A MIXTURE WITH (METH)ACRYLATE POLYMERS DIFFERENT THEREFROM AND THE USE OF SAID COMPOSITION
    1.
    发明申请
    COMPOSITION COMPRISING AS THE AQUEOUS DISPERSION PREFERABLY (METH)ACRYLATE POLYMERS CONTAINING BENZOPHENONE IN A MIXTURE WITH (METH)ACRYLATE POLYMERS DIFFERENT THEREFROM AND THE USE OF SAID COMPOSITION 失效
    作为含有(甲基)丙烯酸酯聚合物的混合物中含有苯甲酸酯(甲基)丙烯酸酯聚合物的优选(甲基)丙烯酸酯聚合物的组合物和不同组合物的使用

    公开(公告)号:US20110319514A1

    公开(公告)日:2011-12-29

    申请号:US13201889

    申请日:2010-03-02

    IPC分类号: C09D129/12 C08J3/28

    摘要: The invention describes a composition comprising, in the form of aqueous dispersion, A) for every 100 parts by weight of a, or of a plurality of, (meth)acrylate polymer(s); B) from 1-400 parts by weight of a, or of a plurality of, (meth)acrylate polymer(s), which contain(s) a compound of the formula (I) copolymerized, where the (meth)acrylate polymer(s) B) differ from the (meth)acrylate polymers specified in A), where these are obtainable by emulsion polymerization of a mixture comprising a) from 0.1 to 99.9 percent by weight of at least one compound of the formula (I), preferably of a benzophenone (meth)acrylate, in which the definitions of the moieties are those given in the description; and b) from 99.9 to 0.1% by weight of a, or of a plurality of, ethylenically unsaturated monomer(s) which differ(s) from a) and which is/are copolymerizable with a), where components a) and b) together give 100% by weight of the polymerizable constituents of the mixture; and where the parts by weight of A) and B) are based on the solids content of the polymers A) or B) in the aqueous dispersion. Dispersions of this type are UV-curable and have excellent suitability for the production of coatings of any type, in particular for coating of mineral substrates, such as concrete. The dispersions of the invention are also advantageous for blending with known dispersions and improve their properties, in particular in respect of their curing profile.

    摘要翻译: 本发明描述了一种组合物,其包含水分散体的形式,A)每100重量份的一种或多种(甲基)丙烯酸酯聚合物; B)1-400重量份的一种或多种(甲基)丙烯酸酯聚合物,其含有(s)共聚的式(I)化合物,其中(甲基)丙烯酸酯聚合物( s)B)与A)中规定的(甲基)丙烯酸酯聚合物不同,其中这些可通过将混合物乳液聚合而获得,所述混合物包含a)0.1至99.9重量%的至少一种式(I)化合物,优选 的二苯甲酮(甲基)丙烯酸酯,其中部分的定义是在说明书中给出的那些; 和b)99.9重量%至0.1重量%的a)或多个不同于a)的烯键式不饱和单体,并且其可与a)共聚,其中组分a)和b) 一起提供100重量%的混合物的可聚合组分; 并且其中A)和B)的重量份数基于水分散体中聚合物A)或B)的固体含量。 这种类型的分散体是可UV固化的,并且对于任何类型的涂料的生产具有优异的适用性,特别是用于矿物基材例如混凝土的涂层。 本发明的分散体也有利于与已知的分散体共混并改进其性能,特别是在其固化分布方面。

    POLYFUNCTIONAL (METH)ACRYLIC POLYMER, COATING COMPOSITION, PROCESS FOR PRODUCING A COATING AND COATED ARTICLE
    5.
    发明申请
    POLYFUNCTIONAL (METH)ACRYLIC POLYMER, COATING COMPOSITION, PROCESS FOR PRODUCING A COATING AND COATED ARTICLE 审中-公开
    多官能(甲基)丙烯酸聚合物,涂料组合物,制备涂料和涂料的方法

    公开(公告)号:US20120016071A1

    公开(公告)日:2012-01-19

    申请号:US13259184

    申请日:2010-03-03

    摘要: The present invention relates to a (meth)acrylate polymer for preparing a coating composition, where the (meth)acrylate polymer comprises 0.5% to 20% by weight of units derived from (meth)acrylic monomers which in the alkyl radical have at least one double bond and 8 to 40 carbon atoms, 0.1% to 60% by weight of units derived from hydroxyl-containing monomers which have up to 9 carbon atoms, 0.1% to 95% by weight of units derived from (meth)acrylates having 1 to 12 carbon atoms in the alkyl radical, and 0.1% to 60% by weight of units derived from styrene monomers, based in each case on the weight of the (meth)acrylate polymer, and the (meth)acrylate polymer has a weight-average molecular weight in the range from 2000 to 60 000 g/mol. The present invention further relates to a coating composition and to a method of producing a coating. The present invention describes, furthermore, a coated article comprising a coating obtainable by the method.

    摘要翻译: 本发明涉及一种用于制备涂料组合物的(甲基)丙烯酸酯聚合物,其中(甲基)丙烯酸酯聚合物包含0.5重量%至20重量%的衍生自(甲基)丙烯酸单体的单元,其在烷基中具有至少一个 双键和8至40个碳原子,0.1至60重量%的衍生自具有至多9个碳原子的含羟基单体的单元,0.1重量%至95重量%的衍生自(甲基)丙烯酸酯的单元,其具有1至 (甲基)丙烯酸酯聚合物的重量,基于(甲基)丙烯酸酯聚合物的重量,基于(甲基)丙烯酸酯聚合物的重量百分数为0.1〜60重量%的苯乙烯单体衍生的单元, 分子量在2000〜60000g / mol的范围内。 本发明还涉及一种涂料组合物和一种制备涂料的方法。 此外,本发明还描述了包含可通过该方法获得的涂层的涂覆制品。

    METHOD FOR PRODUCING POLYALKYLENE GLYCOLDI(METH)ACRYLATES
    7.
    发明申请
    METHOD FOR PRODUCING POLYALKYLENE GLYCOLDI(METH)ACRYLATES 有权
    聚甲基丙烯酸(甲基)丙烯酸酯的生产方法

    公开(公告)号:US20110082314A1

    公开(公告)日:2011-04-07

    申请号:US12992998

    申请日:2009-05-05

    IPC分类号: C07C67/24

    CPC分类号: C08G65/3322

    摘要: The present invention relates to a process for preparing polyalkylene glycol di(meth)acrylates by reacting polyalkylene glycol with (meth)acrylic anhydride, wherein the reaction mixture contains at most 0.5% by weight of metal compounds and/or amines, the reaction is carried out in the presence of polymerization inhibitors and the reaction temperature is at least 60° C.

    摘要翻译: 本发明涉及通过使聚亚烷基二醇与(甲基)丙烯酸酐反应制备聚亚烷基二醇二(甲基)丙烯酸酯的方法,其中反应混合物含有至多0.5重量%的金属化合物和/或胺,反应进行 在聚合抑制剂存在下,反应温度至少为60℃。

    Composition comprising as the aqueous dispersion preferably (meth)acrylate polymers containing benzophenone in a mixture with (meth)acrylate polymers different therefrom and the use of said composition
    8.
    发明授权
    Composition comprising as the aqueous dispersion preferably (meth)acrylate polymers containing benzophenone in a mixture with (meth)acrylate polymers different therefrom and the use of said composition 失效
    包含作为水分散体的组合物优选含有与(甲基)丙烯酸酯聚合物不同的混合物中的二苯甲酮的(甲基)丙烯酸酯聚合物,以及所述组合物

    公开(公告)号:US08669328B2

    公开(公告)日:2014-03-11

    申请号:US13201889

    申请日:2010-03-02

    摘要: The invention describes a composition comprising, in the form of aqueous dispersion, A) for every 100 parts by weight of a, or of a plurality of, (meth)acrylate polymer(s); B) from 1-400 parts by weight of a, or of a plurality of, (meth)acrylate polymer(s), which contain(s) a compound of the formula (I) copolymerized, where the (meth)acrylate polymer(s) B) differ from the (meth)acrylate polymers specified in A), where these are obtainable by emulsion polymerization of a mixture comprising a) from 0.1 to 99.9 percent by weight of at least one compound of the formula (I), preferably of a benzophenone (meth)acrylate, in which the definitions of the moieties are those given in the description; and b) from 99.9 to 0.1% by weight of a, or of a plurality of, ethylenically unsaturated monomer(s) which differ(s) from a) and which is/are copolymerizable with a), where components a) and b) together give 100% by weight of the polymerizable constituents of the mixture; and where the parts by weight of A) and B) are based on the solids content of the polymers A) or B) in the aqueous dispersion. Dispersions of this type are UV-curable and have excellent suitability for the production of coatings of any type, in particular for coating of mineral substrates, such as concrete. The dispersions of the invention are also advantageous for blending with known dispersions and improve their properties, in particular in respect of their curing profile.

    摘要翻译: 本发明描述了一种组合物,其包含水分散体的形式,A)每100重量份的一种或多种(甲基)丙烯酸酯聚合物; B)1-400重量份的一种或多种(甲基)丙烯酸酯聚合物,其含有(s)共聚的式(I)化合物,其中(甲基)丙烯酸酯聚合物( s)B)与A)中规定的(甲基)丙烯酸酯聚合物不同,其中这些可通过将混合物乳液聚合而获得,所述混合物包含a)0.1至99.9重量%的至少一种式(I)化合物,优选 的二苯甲酮(甲基)丙烯酸酯,其中部分的定义是在说明书中给出的那些; 和b)99.9重量%至0.1重量%的a)或多个不同于a)的烯键式不饱和单体,并且其可与a)共聚,其中组分a)和b) 一起提供100重量%的混合物的可聚合组分; 并且其中A)和B)的重量份数基于水分散体中聚合物A)或B)的固体含量。 这种类型的分散体是可UV固化的,并且对于任何类型的涂料的生产具有优异的适用性,特别是用于矿物基材例如混凝土的涂层。 本发明的分散体也有利于与已知的分散体共混并改进其性能,特别是在其固化分布方面。

    Method for producing polyalkylene glycoldi(meth)acrylates
    10.
    发明授权
    Method for producing polyalkylene glycoldi(meth)acrylates 有权
    聚亚烷基二(甲基)丙烯酸酯的制备方法

    公开(公告)号:US08716516B2

    公开(公告)日:2014-05-06

    申请号:US12992998

    申请日:2009-05-05

    IPC分类号: C08G65/00

    CPC分类号: C08G65/3322

    摘要: The present invention relates to a process for preparing polyalkylene glycol di(meth)acrylates by reacting polyalkylene glycol with (meth)acrylic anhydride, wherein the reaction mixture contains at most 0.5% by weight of metal compounds and/or amines, the reaction is carried out in the presence of polymerization inhibitors and the reaction temperature is at least 60° C.

    摘要翻译: 本发明涉及通过使聚亚烷基二醇与(甲基)丙烯酸酐反应制备聚亚烷基二醇二(甲基)丙烯酸酯的方法,其中反应混合物含有至多0.5重量%的金属化合物和/或胺,反应进行 在聚合抑制剂存在下,反应温度至少为60℃。