公开(公告)号：US07956145B2

公开(公告)日：2011-06-07

申请号：US11958905

申请日：2007-12-18

Applicant: Kohtaro Osakada ,  Daisuke Takeuchi ,  Sehoon Park ,  Makoto Uemura ,  Masayuki Fujita

Inventor： Kohtaro Osakada ,  Daisuke Takeuchi ,  Sehoon Park ,  Makoto Uemura ,  Masayuki Fujita

IPC: C08F236/02 ,  C08F32/02

CPC classification number: C08F136/20 ,  C08F4/7006 ,  C08F4/7042

Abstract: A polymer containing units represented by the defined formula (1); and a process for producing the polymer, which comprises the step of polymerizing a compound represented by the defined formula (3), the units represented by the formula (1) being polymerized units of the compound represented by the formula (3) such as 9,9-diallylfluorene.

Abstract translation: 含有由式（1）表示的单元的聚合物; 和聚合物的制造方法，其特征在于，包括使由式（3）表示的化合物聚合的方法，由式（1）表示的单元是由式（3）表示的化合物的聚合单元，例如9 ，9-二烯丙基芴。

公开(公告)号：US20090221774A1

公开(公告)日：2009-09-03

申请号：US12372815

申请日：2009-02-18

Applicant: Kohtaro Osakada ,  Daisuke Takeuchi ,  Yusuke Fukuda ,  Osamu Ihata ,  Hiroshi Kuribayashi

Inventor： Kohtaro Osakada ,  Daisuke Takeuchi ,  Yusuke Fukuda ,  Osamu Ihata ,  Hiroshi Kuribayashi

IPC: C08F2/00 ,  C08F14/14

CPC classification number: C08F36/20 ,  C08F4/7098

Abstract: A polymer comprising a unit represented by the following formula (1); and a process for producing the polymer comprising the step of polymerizing a diene compound such as 9,9-diallylfluorene in the presence of a polymerization catalyst formed by contacting a nickel compound with an organoaluminum compound and/or a boron compound:

Abstract translation: 包含由下式（1）表示的单元的聚合物; 以及一种制备聚合物的方法，包括在通过使镍化合物与有机铝化合物和/或硼化合物接触而形成的聚合催化剂的存在下聚合二烯化合物如9,9-二烯丙基芴的步骤：

公开(公告)号：US08247510B2

公开(公告)日：2012-08-21

申请号：US13184020

申请日：2011-07-15

Applicant: Kohtaro Osakada ,  Daisuke Takeuchi ,  Sehoon Park ,  Masayuki Fujita ,  Wataru Hirahata

Inventor： Kohtaro Osakada ,  Daisuke Takeuchi ,  Sehoon Park ,  Masayuki Fujita ,  Wataru Hirahata

IPC: C08F18/14

CPC classification number: C08F210/02 ,  C08F10/00 ,  C08G61/02 ,  C08G61/123 ,  C08F220/00 ,  C08F2500/03 ,  C08F4/7006

Abstract: A homopolymer having a monomer unit such as an isopropylidene diallylmalonate unit; a process for producing said homopolymer comprising the step of homopolymerising a monomer such as isopropylidene diallylmalonate; a copolymer containing said monomer unit and an ethylene unit and/or α-olefin unit; and a process for producing said copolymer comprising the step of copolymerizing a monomer such as isopropylidene diallylmalonate with at least ethylene and/or an α-olefin.

Abstract translation: 具有单体单元的均聚物，如异丙叉二烯丙基丙二酸单元; 一种制备所述均聚物的方法，包括均聚单体如异丙基二烯丙基丙二酸酯的步骤; 含有所述单体单元和乙烯单元和/或α-烯烃单元的共聚物; 以及一种制备所述共聚物的方法，包括使单体如异丙叉二烯丙基丙二酸酯与至少乙烯和/或α-烯烃共聚的步骤。

公开(公告)号：US20110245441A1

公开(公告)日：2011-10-06

申请号：US13072033

申请日：2011-03-25

Applicant: Kohtaro OSAKADA ,  Daisuke TAKEUCHI ,  Osamu IHATA ,  Hirofumi JOHOJI

Inventor： Kohtaro OSAKADA ,  Daisuke TAKEUCHI ,  Osamu IHATA ,  Hirofumi JOHOJI

IPC: C08F10/14 ,  C08F4/70

CPC classification number: C08F110/14 ,  C08G61/04 ,  C08G2261/3323 ,  C08F4/7006 ,  C08F2500/03 ,  C08F2500/17

Abstract: A polymer and a method for producing same are provided, which includes a repeating unit represented by the following formula (1): wherein: each of A1, A2, A3, and A4 independently represents a hydrogen atom, a halogen atom, an alkyl group, an aralkyl group, an aryl group, a silyl group, a siloxy group, an alkoxy group, an aralkyloxy group, an aryloxy group, an amino group, an amide group, an imide group, or a hydrocarbon thio group; each of A1, A2, A3, and A4 is independently any of these groups at different carbons to which the each of A1, A2, A3, and A4 is bonded, and A1, A2, A3, and A4 may be bonded to each other; and each of m, n, and k is independently an integer in a range of 2 to 20.

Abstract translation: 提供聚合物及其制造方法，其包括由下式（1）表示的重复单元：其中：A1，A2，A3和A4各自独立地表示氢原子，卤素原子，烷基 芳烷基，芳基，甲硅烷基，甲硅烷氧基，烷氧基，芳烷氧基，芳氧基，氨基，酰胺基，酰亚胺基或烃硫基; A1，A2，A3和A4中的每一个独立地是与A1，A2，A3和A4各自键合的不同碳上的这些基团中的任一个，并且可以将A1，A2，A3和A4彼此键合 ; m，n和k分别为2〜20的整数。

公开(公告)号：US20110245440A1

公开(公告)日：2011-10-06

申请号：US13071754

申请日：2011-03-25

Applicant: Kohtaro OSAKADA ,  Daisuke TAKEUCHI ,  Osamu IHATA ,  Hirofumi JOHOJI ,  Kenji SOGO

Inventor： Kohtaro OSAKADA ,  Daisuke TAKEUCHI ,  Osamu IHATA ,  Hirofumi JOHOJI ,  Kenji SOGO

IPC: C08F210/14 ,  C08F4/70 ,  C08F210/06 ,  C08F210/02

CPC classification number: C08F232/04 ,  C08F210/06 ,  C08F210/08 ,  C08F210/14 ,  C08F210/16 ,  C08F2500/03 ,  C08F2500/17

Abstract: A copolymer and method for providing it are provided, which includes a monomer unit represented by the following formula (1) and an olefin unit: wherein: each of A1, A2, A3, and A4 independently represents a hydrogen atom, a halogen atom, an alkyl group, an aralkyl group, an aryl group, a silyl group, a siloxy group, an alkoxy group, an aralkyloxy group, an aryloxy group, an amino group, an amide group, an imide group, or a hydrocarbon thio group; which group may have a substituent; and each of m, n, and k is independently an integer in a range of 2 to 20.

Abstract translation: 提供了一种提供它的共聚物和方法，其包括由下式（1）表示的单体单元和烯烃单元：其中：A1，A2，A3和A4各自独立地表示氢原子，卤素原子， 烷基，芳烷基，芳基，甲硅烷基，甲硅烷氧基，烷氧基，芳烷氧基，芳氧基，氨基，酰胺基，酰亚胺基或烃硫基; 该基团可以具有取代基; m，n和k分别为2〜20的整数。

公开(公告)号：US20090240085A1

公开(公告)日：2009-09-24

申请号：US12441780

申请日：2007-09-28

Applicant: Hideo Hosono ,  Haritha Buchammagari ,  Yoshitake Toda ,  Masahiro Hirano ,  Kohtaro Osakada ,  Daisuke Takeuchi

Inventor： Hideo Hosono ,  Haritha Buchammagari ,  Yoshitake Toda ,  Masahiro Hirano ,  Kohtaro Osakada ,  Daisuke Takeuchi

IPC: C07C45/00 ,  C07C31/18 ,  C07C29/16

CPC classification number: C07C45/72 ,  C07B41/02 ,  C07C29/143 ,  C07C29/38 ,  C07C41/26 ,  C07C41/30 ,  C07C45/73 ,  C07C46/00 ,  C07C253/30 ,  C07C31/22 ,  C07C31/42 ,  C07C31/20 ,  C07C49/83 ,  C07C49/835 ,  C07C50/20 ,  C07C255/53 ,  C07C43/23

Abstract: The invention is a process of using, as a reducing agent, a 12CaO.7Al2O3 electride containing electrons in a number of 1019 or more and 2.3×1021 cm−3 or less in its cages to subject a carbonyl compound to reductive coupling in a solvent, thereby synthesizing a diol or polydiol. The invention is also a process of reducing a ketone compound in a solvent, thereby synthesizing a secondary alcohol or diketone compound. According to the process of the invention, it is possible to synthesize a diol or polydiol, or a secondary alcohol or diketone compound through simple operations in a short period without using an expensive and harmful metal hydride or metal salt nor limiting the atmosphere for the synthesis to an inert gas atmosphere as in conventional processes.

Abstract translation: 本发明是在其笼中使用含有1019以上且2.3×10 21 cm -3以下的电子的12CaO·7Al 2 O 3电极作为还原剂的方法，以使羰基化合物在溶剂中进行还原偶联， 从而合成二醇或聚二醇。 本发明也是在溶剂中还原酮化合物的方法，从而合成仲醇或二酮化合物。 根据本发明的方法，可以在短时间内通过简单的操作合成二醇或多元醇或仲醇或二酮化合物，而不使用昂贵且有害的金属氢化物或金属盐，也不限制合成气氛 到惰性气体气氛中，如常规方法。

公开(公告)号：US20090171054A1

公开(公告)日：2009-07-02

申请号：US12064399

申请日：2006-06-28

Applicant: Kohtaro Osakada ,  Daisuke Takeuchi ,  Sehoon Park ,  Masayuki Fujita ,  Wataru Hirahata

Inventor： Kohtaro Osakada ,  Daisuke Takeuchi ,  Sehoon Park ,  Masayuki Fujita ,  Wataru Hirahata

IPC: C08F4/42 ,  C08G63/12

CPC classification number: C08F210/02 ,  C08F10/00 ,  C08G61/02 ,  C08G61/123 ,  C08F220/00 ,  C08F2500/03 ,  C08F4/7006

Abstract: A homopolymer having a monomer unit such as an isopropylidene diallylmalonate unit; a process for producing said homopolymer comprising the step of homopolymerising a monomer such as isopropylidene diallylmalonate; a copolymer containing said monomer unit and an ethylene unit and/or α-olefin unit; and a process for producing said copolymer comprising the step of copolymerizing a monomer such as isopropylidene diallylmalonate with at least ethylene and/or an α-olefin.

Abstract translation: 具有单体单元的均聚物，如异丙叉二烯丙基丙二酸单元; 一种制备所述均聚物的方法，包括均聚单体如异丙基二烯丙基丙二酸酯的步骤; 含有所述单体单元和乙烯单元和/或α-烯烃单元的共聚物; 以及一种制备所述共聚物的方法，包括使单体如异丙烯二烯丙基丙二酸酯与至少乙烯和/或α-烯烃共聚的步骤。

公开(公告)号：US20080221287A1

公开(公告)日：2008-09-11

申请号：US11957859

申请日：2007-12-17

Applicant: Kohtaro OSAKADA ,  Daisuke TAKEUCHI ,  Sehoon PARK ,  Makoto UEMURA ,  Masayuki FUJITA

Inventor： Kohtaro OSAKADA ,  Daisuke TAKEUCHI ,  Sehoon PARK ,  Makoto UEMURA ,  Masayuki FUJITA

IPC: C08F2/60 ,  C08F2/00 ,  C08F4/12

CPC classification number: C08F36/20 ,  C08F4/7006

Abstract: A polymer containing units represented by the defined formula (1); and a process for producing the polymer, which comprises the step of polymerizing a compound represented by the defined formula (3), the units represented by the formula (1) being polymerized units of the compound represented by the formula (3) such as 2,2-dially-1,3-cyclopentanedione.

Abstract translation: 含有由式（1）表示的单元的聚合物; 和聚合物的制造方法，其特征在于，包括使由式（3）表示的化合物进行聚合的方法，由式（1）表示的单元是由式（3）表示的化合物的聚合单元，例如2 ，2-二烯-1,3-环戊二酮。

公开(公告)号：US20080221286A1

公开(公告)日：2008-09-11

申请号：US11946939

申请日：2007-11-29

Applicant: Kohtaro OSAKADA ,  Daisuke TAKEUCHI ,  Sehoon PARK ,  Ryuichi MATSUURA ,  Makoto UEMURA ,  Masayuki FUJITA

Inventor： Kohtaro OSAKADA ,  Daisuke TAKEUCHI ,  Sehoon PARK ,  Ryuichi MATSUURA ,  Makoto UEMURA ,  Masayuki FUJITA

IPC: C08F4/12 ,  C08F230/08

CPC classification number: C08F36/20 ,  C08F4/7042

Abstract: A polymer containing units represented by the defined formula (1); and a process for producing the polymer, which comprises the step of polymerizing a compound represented by the defined formula (3), the units represented by the formula (1) being polymerized units of the compound represented by the formula (3) such as 1,6-heptadiene.

Abstract translation: 含有由式（1）表示的单元的聚合物; 和聚合物的制造方法，其特征在于，包括使由式（3）表示的化合物进行聚合的方法，式（1）所示的单元为式（3）表示的化合物的聚合单元，例如1 ，6-庚二烯。

公开(公告)号：US20080214755A1

公开(公告)日：2008-09-04

申请号：US12036231

申请日：2008-02-23

Applicant: Kohtaro Osakada ,  Daisuke Takeuchi ,  Sehoon Park ,  Makoto Uemura

Inventor： Kohtaro Osakada ,  Daisuke Takeuchi ,  Sehoon Park ,  Makoto Uemura

IPC: C08F4/606

CPC classification number: C08F36/20 ,  C08F210/02 ,  C08F4/7006 ,  C08F232/00 ,  C08F2500/25 ,  C08F2500/03

Abstract: A copolymer containing units represented by the defined formula (1) and olefin units; and a process for producing the copolymer, which comprises the step of copolymerizing a compound represented by the defined formula (3) with an olefin, the units represented by the formula (1) being polymerized units of the compound represented by the formula (3) such as 5,5-diallyl-2,2-dimethyl-1,3-dioxane.

Abstract translation: 含有由式（1）表示的单元和烯烃单元的共聚物; （3）表示的化合物与烯烃共聚的方法，式（1）表示的单元为式（3）表示的化合物的聚合单元， 例如5,5-二烯丙基-2,2-二甲基-1,3-二恶烷。