摘要:
A multi-layer, positive-working lithographic printing plate precursor can be imaged with infrared radiation and processed in a single step using a single processing solution that has a pH greater than 6 and up to about 11. This single processing solution both develops the imaged precursor and provides a protective coating that need not be rinsed off before lithographic printing.
摘要:
An imaged and developed element, such as a lithographic printing plate, is provided by infrared radiation imaging of a negative-working imagable element having an outermost imagable layer that includes a free radically polymerizable component, a free radical initiator composition comprising a diaryliodonium borate, and an infrared radiation absorbing compound. The imagable layer also includes a polymeric binder that is represented by the following Structure (I): -(A)w-(A′)w′- (I) wherein A represents recurring units comprising a pendant reactive vinyl group, A′ represents recurring units other than those represented by A, w is from about 1 to about 70 mol %, and w′ is from about 30 to about 99 mol %. The imagewise exposed element is developed with a gum to remove only the non-exposed regions. The gum has a pH greater than 7 and up to about 11 and at least 1 weight % of an anionic surfactant.
摘要:
A negative-working lithographic printing plate precursor can be imaged with infrared radiation and processed in a single step using a single processing solution that has a pH of from about 2 to about 11 and contains an anionic surfactant. This single processing solution both develops the imaged precursor and provides a protective coating that need not be rinsed off before lithographic printing. The lithographic printing plate precursor contains a particulate polymeric binder.
摘要:
An imaged and developed element, such as a lithographic printing plate, is provided by infrared radiation imaging of a negative-working imageable element having an outermost imageable layer that includes an acid generating compound that generates acid upon exposure to imaging infrared radiation, an infrared radiation absorbing compound, an acid activatable crosslinking agent that has acid activatable reactive groups, and a polymeric binder that is capable of undergoing an acid-catalyzed condensation reaction with the crosslinking agent. The imaged element is heated at from about 120 to about 150° C. for up to two minutes, and then developed with a single processing solution to remove only the non-exposed regions and to provide a protective layer prior to lithographic printing.
摘要:
A method for providing lithographic printing plates is achieved by imaging a lithographic printing plate precursor and processing it with fresh (not reused) samples of a processing solution that both develops and protects the resulting lithographic image. The lithographic printing plate precursors can be either negative-working or positive-working.
摘要:
An imaged and developed element, such as a lithographic printing plate, is provided by violet radiation imaging of a negative-working imageable element having an outermost imageable layer that includes a free radically polymerizable component, an initiator composition that provides free radicals upon violet irradiation, a sensitizer, and a polymeric binder having pendant reactive vinyl groups. The element also includes an additive that is represented by the following Structure (II): wherein R1, R2, R3, and R4 are independently hydrogen, or alkyl, alkenyl, cycloalkyl, or aryl groups. The imaged element can be developed using a gum having a pH greater than 6 and up to about 11 and comprising at least 1 weight % of one or more anionic surfactants.
摘要:
A negative-working imageable element has an imageable layer that includes an initiator composition including an iodonium cation and a boron-containing anion at a molar ratio of at least 1.2:1, an infrared radiation absorbing compound, a primary polymeric binder, and a spirolactone or spirolactam colorant precursor. The imaged element exhibits improved print-out.
摘要:
Negative-working imageable elements that can be imaged using infrared radiation comprise an imageable layer and a protective overcoat on a hydrophilic substrate. The imageable layer includes an IR-sensitive cyanine dye. The protective overcoat predominantly comprises one or more poly(vinyl alcohol) resins, each of which has a hydrolysis level of 85% or less. The use of this particular overcoat composition used in combination with the IR-sensitive cyanine dye provides improved tolerance to fogging by white light while maintaining desired imaging speed.
摘要:
Positive-working imageable elements comprise a radiation absorbing compound and inner and outer layers on a substrate having a hydrophilic surface. The inner layer comprises a polymeric material that is removable using an alkaline developer and comprises a backbone and attached groups represented by the following Structure Q: wherein L1, L2, and L3 independently represent linking groups, T1, T2, and T3 independently represent terminal groups, and a, b, and c are independently 0 or 1. The imageable elements have improved resistance to development and printing chemicals and solvents.
摘要翻译:正性可成像元件包括辐射吸收化合物和在具有亲水表面的基底上的内层和外层。 内层包含可使用碱性显影剂除去的聚合物材料,其包含由以下结构Q表示的骨架和连接基团:其中L 1,L 2,和 L 3独立地表示连接基团,T 1,T 2和T 3独立地表示连接基团,和 a,b和c独立地为0或1.可成像元件具有改善的耐显影和印刷化学品和溶剂的能力。
摘要:
Single-layer and multilayer imageable elements have a substrate and at least one imageable layer and can be used to prepare positive-working lithographic printing plates. The imageable elements also include a radiation absorbing compound and a solvent-resistant polymer binder comprising an —N(R)—C(═X)—N(R′)—S(═O)2— moiety that is attached to the polymer backbone, wherein X is O or S, R and R′ are independently hydrogen, halo, or an alkyl group having 1 to 6 carbon atoms. This solvent-resistant polymer binder is located in the imageable layer closest to the substrate and provides improved chemical resistance.