摘要:
Highly dispersed lithium titanate crystal structures having a thickness of few atomic layers level and the two-dimensional surface in a plate form are supported on carbon nanofiber (CNF). The lithium titanate crystal structure precursors and CNF that supports these are prepared by a mechanochemical reaction that applies sheer stress and centrifugal force to a reactant in a rotating reactor. The mass ratio between the lithium titanate crystal structure and carbon nanofiber is preferably between 75:25 and 85:15. The carbon nanofiber preferably has an external diameter of 10-30 nm and an external specific surface area of 150-350 cm2/g. This composite is mixed with a binder and then molded to obtain an electrode, and this electrode is employed for an electrochemical element.
摘要:
An electrolyte having a high conductivity, an excellent high-temperature life characteristic and leading to improvement of the shelf characteristic of an aluminum electrolytic capacitor. At least one phosphate ion producing compound and a chelating agent are added using a solvent largely composed of water. Therefor, an aluminum electrolytic capacitor comprising such an electrolyte has a low impedance, an excellent high-temperature life characteristic, and an improved shelf characteristic.
摘要:
A composite powder in which highly dispersed metal oxide nanoparticle precursors are supported on carbon is rapidly heated under nitrogen atmosphere, crystallization of metal oxide is allowed to progress, and highly dispersed metal oxide nanoparticles are supported by carbon. The metal oxide nanoparticle precursors and carbon nanoparticles supporting said precursors are prepared by a mechanochemical reaction that applies sheer stress and centrifugal force to a reactant in a rotating reactor. The rapid heating treatment in said nitrogen atmosphere is desirably heating to 400° C.-1000° C. By further crushing the heated composite, its aggregation is eliminated and the dispersity of metal oxide nanoparticles is made more uniform. Examples of a metal oxide that can be used are manganese oxide, lithium iron phosphate, and lithium titanate. Carbons that can be used are carbon nanofiber and Ketjen Black.
摘要:
The electrode material includes metal oxide nanoparticles formed by applying shear force and centrifugal force to reactants containing a reaction inhibitor in a rotating reaction vessel during a chemical reaction; and carbon nanotubes with a specific area of 600 to 2600 m2/g to which shear force and centrifugal force are applied for dispersion in the rotating reaction vessel during the chemical reaction. The metal oxide particles are highly dispersed and carried on the carbon nanotubes. Preferably, the metal oxide is lithium titanate.
摘要:
Highly dispersed lithium titanate crystal structures having a thickness of few atomic layers level and the two-dimensional surface in a plate form are supported on carbon nanofiber (CNF). The lithium titanate crystal structure precursors and CNF that supports these are prepared by a mechanochemical reaction that applies sheer stress and centrifugal force to a reactant in a rotating reactor. The mass ratio between the lithium titanate crystal structure and carbon nanofiber is preferably between 75:25 and 85:15. The carbon nanofiber preferably has an external diameter of 10-30 nm and an external specific surface area of 150-350 cm2/g. This composite is mixed with a binder and then molded to obtain an electrode, and this electrode is employed for an electrochemical element.
摘要:
An electrical double-layer capacitor electrode with excellent capacitance characteristics is obtained together with a manufacturing method therefor.Paper-molded sheet 2 of carbon nanotubes is integrated with etched foil 1 constituting a collector, by means of bumps and indentations 1a formed on the surface of etched foil 1 to prepare an electrical double-layer capacitor electrode. Alternatively, carbon nanotubes 4 grown around core catalyst particles on substrate 3 are integrated with etched foil 1 by means of bumps and indentations 1a formed on the surface of etched foil 1 to prepare an electrical double-layer capacitor electrode. To manufacture these electrodes, this carbon nanotube sheet 2 or substrate 3 with carbon nanotubes grown thereon is laid over bumps and indentations la on the surface of etched foil 1, and the sheet or substrate and the foil are pressed under 0.01 to 100 t/cm2 of pressure to integrate the carbon nanotubes with the etched foil.
摘要翻译:获得具有优异的电容特性的电双层电容器电极及其制造方法。 通过形成在蚀刻箔1的表面上的凸起和凹陷1a,将碳纳米管的纸模制片2与构成收集器的蚀刻箔1集成,以制备双电层电容器电极。 或者,通过形成在蚀刻箔1的表面上的凸起和凹陷1a,与蚀刻箔1一体地在基板3上的核心催化剂颗粒周围生长的碳纳米管4,以制备双电层电容器电极。 为了制造这些电极,将碳纳米管片2或其上生长有碳纳米管的基板3放置在蚀刻箔1的表面上的凸起和凹槽1a上,并且将片或基板和箔压制在0.01至100t / cm 2 的压力以将碳纳米管与蚀刻箔整合。
摘要:
To provide an electrode material excellent in output characteristics and cycle property and an electrochemical device using the electrode material. The electrode material comprising polymer complex compound represented by the following graphical formula: and the electrochemical device using the electrode material. Even if such a large size ion is employed, enhanced output characteristics could be obtained in the present invention. Polymer complex compound is polarized due to an electron attracting substituent, or steric hindrance occurs due to a substituent having a branch structure so that interval of polymer complex compound formed on the electrode is increased and doping reaction. Therefore, even if using large size ions smooth and rapid doping and undoping reaction could take place.
摘要:
A composite powder in which highly dispersed metal oxide nanoparticle precursors are supported on carbon is rapidly heated under nitrogen atmosphere, crystallization of metal oxide is allowed to progress, and highly dispersed metal oxide nanoparticles are supported by carbon. The metal oxide nanoparticle precursors and carbon nanoparticles supporting said precursors are prepared by a mechanochemical reaction that applies sheer stress and centrifugal force to a reactant in a rotating reactor. The rapid heating treatment in said nitrogen atmosphere is desirably heating to 400° C.-1000° C. By further crushing the heated composite, its aggregation is eliminated and the dispersity of metal oxide nanoparticles is made more uniform. Examples of a metal oxide that can be used are manganese oxide, lithium iron phosphate, and lithium titanate. Carbons that can be used are carbon nanofiber and Ketjen Black.
摘要:
Disclosed are an aluminum electrolytic capacitor having low impedance properties and a long service life, and an electrolytic solution which enables to give such capacitor. The electrolytic solution contains a solvent containing water, a phosphorus oxoacid ion-generating compound which can generate a phosphorus oxoacid ion in an aqueous solution, and a chelating agent which can coordinate with aluminum to form an aqueous aluminum chelate complex. The electrolytic solution further contains a compound selected from the group consisting of azelaic acid and an azelaic acid salt, and a compound selected from the group consisting of formic acid, a formic acid salt, adipic acid, an adipic acid salt, glutaric acid and a glutaric acid salt. The content of azelaic acid and/or the azelaic acid salt is at least 0.03 moles per kg of the solvent. When the electrolytic solution is used in an electrolytic capacitor which utilizes an anode having an aluminum oxide film containing phosphorus in an amount of 30 to 150 mg per unit CV product in terms of phosphoric acid, the service life of the capacitor is remarkably prolonged.
摘要:
A method for producing an electrode for an electrochemical element absorbs monomers for polymerization on a surface having a specific surface area of 100 to 3000 m2g−1 and having an average pore diameter in the range of 0.4 to 100 nm, performing electrolysis polymerization by applying pulse voltage, and forming a conductive polymer layer on the surface of the conductive porous material, forming a thin and uniform electrode film. In a method for producing an electrochemical element, a conductive polymer layer is formed on the conductive porous material by absorbing monomers for polymerization on a surface of a conductive porous material having a specific surface area and pore diameter as above forming a electrochemical cell by using the conductive porous material, the monomers are absorbed in the pores, putting the electrochemical cell and the electrolyte solution in an outer casing, and performing electrolysis polymerization of the monomers in the electrolyte solution.