公开(公告)号：US6162847A

公开(公告)日：2000-12-19

申请号：US986470

申请日：1997-12-08

申请人： Kenichi Fujimoto ,  Kenji Mikuni

发明人： Kenichi Fujimoto ,  Kenji Mikuni

IPC分类号： C08K5/521 ,  C08K5/527 ,  C08L9/02 ,  C08K5/526

CPC分类号： C08K5/521 ,  C08K5/527 ,  C08L9/02

摘要： A method for preparing a rubber seal product of a type which contacts a metal surface for sealing thereof, comprising the steps of: preparing a rubber composition comprising acrylonitrile butadiene rubber (NBR), (A) a carbocyclic phosphite compound represented by the general formula ##STR1## where R is an alkyl group having 8 to 24 carbon atoms, or a phenyl group having a mono-, di- or tri-substituted alkyl group having 1 to 10 carbon atoms, and (B) an acid phosphate compound represented by the general formula ##STR2## where R' is a hydrogen atom, or an alkyl group having 1 to 13 carbon atoms, and R" is an alkyl group having 1 to 13 carbon atoms, the phosphate compound having an acid number of about 150 to 800 KOH mg/g; wherein a total of about 5 to 20 parts by weight of compound (A) and compound (B) are present in the composition based on 100 parts by weight of NBR, vulcanizing the rubber composition to obtain a vulcanized rubber composition; and compressing the vulcanized rubber composition toward a metal surface.

摘要翻译： 一种制备与金属表面接触密封的橡胶密封产品的方法，包括以下步骤：制备包含丙烯腈丁二烯橡胶（NBR），（A）由通式表示的碳环亚磷酸酯化合物的橡胶组合物，其中 R为碳原子数为8〜24的烷基或具有1〜10个碳原子的一取代，二取代或者三取代的烷基的苯基，（B）通式表示的酸式磷酸酯化合物，式中， R'为氢原子或碳原子数1〜13的烷基，R“为碳原子数1〜13的烷基，酸值为约150〜800KOHmg / g的磷酸化合物; 其中基于100重量份的NBR，在组合物中总共存在约5至20重量份的化合物（A）和化合物（B）），硫化橡胶组合物以获得硫化橡胶组合物; 并将硫化橡胶组合物压向金属表面。

公开(公告)号：US5869197A

公开(公告)日：1999-02-09

申请号：US814153

申请日：1997-03-10

申请人： Kenji Mikuni ,  Shingo Kawano

发明人： Kenji Mikuni ,  Shingo Kawano

IPC分类号： C08K5/521 ,  C08L33/04 ,  C08L33/06 ,  C09K3/10 ,  C10M105/04

CPC分类号： C09K3/10 ,  C08K5/521 ,  C09K2200/0208 ,  C09K2200/0234 ,  C09K2200/0417 ,  C09K2200/0458 ,  C09K2200/0625 ,  Y10T428/12493 ,  Y10T428/12556 ,  Y10T428/12562 ,  Y10T428/12569 ,  Y10T428/12986

摘要： An acrylic rubber composition comprising 100 parts by weight of acrylic rubber containing cross-linkable groups and 2 to 40 parts by weight of tri(2-ethylhexyl) phosphate has quite an unexpected effect on prevention of fixation of its vulcanized rubber moldings to metallic materials or resin moldings when brought into direct contact with the latter due to the presence of tri(2-ethylhexyl) phosphate in the acrylic rubber containing cross-linkable groups.

摘要翻译： 包含100重量份含有可交联基团的丙烯酸橡胶和2至40重量份磷酸三（2-乙基己基）酯的丙烯酸橡胶组合物对防止其硫化橡胶模制品对金属材料的固定或者 由于在含有可交联基团的丙烯酸橡胶中存在磷酸三（2-乙基己基）酯而与后者直接接触时产生树脂模制品。

公开(公告)号：US5807913A

公开(公告)日：1998-09-15

申请号：US760864

申请日：1996-12-05

申请人： Kenji Mikuni ,  Hisayuki Nagaoka ,  Norio Tanaka

发明人： Kenji Mikuni ,  Hisayuki Nagaoka ,  Norio Tanaka

IPC分类号： F16J15/10 ,  C08K5/36 ,  C08K5/5317 ,  C08L33/04 ,  C08L33/06 ,  C08L33/14 ,  C09K3/10 ,  C08K5/53

CPC分类号： C09K3/10 ,  C08K5/5317 ,  C09K2200/0417 ,  C09K2200/0488 ,  C09K2200/0625

摘要： An active halogen-containing acrylic rubber composition for molding oil filter-gaskets, which comprises an active halogen-containing acrylic rubber and a metal phosphonate represented by the following general formula: RR'nPO(OH)(OM) wherein R is an alkyl group having 1 to 32 carbon atoms, a polyfluorocarbon group or a perfluoropolyether group; R' is an alkylene group having 1 to 6 carbon atoms, a phenylene group, an oxyphenylene group or a sulfonamide group; M is an alkali metal; and n is 0 or 1, gives oil filter-gaskets having a distinguished durable protection against fixation without lowering of high temperature sealability, even if used in engine oil.

摘要翻译： 一种用于成型油过滤垫片的活性含卤素丙烯酸橡胶组合物，其包含由以下通式表示的含活性卤素的丙烯酸橡胶和金属膦酸盐：RR'nPO（OH）（OM）其中R是烷基 具有1至32个碳原子，多氟碳基团或全氟聚醚基团; R'是具有1至6个碳原子的亚烷基，亚苯基，氧亚苯基或磺酰胺基; M是碱金属; 并且n为0或1，即使在发动机机油中使用，也能得到具有突出的耐久性保护的油过滤垫圈，而不降低高温密封性。