Method for preparing catalysts for partial oxidation of propylene and iso-butylene
    2.
    发明授权
    Method for preparing catalysts for partial oxidation of propylene and iso-butylene 有权
    制备用于丙烯和异丁烯部分氧化的催化剂的方法

    公开(公告)号:US07329628B2

    公开(公告)日:2008-02-12

    申请号:US10509645

    申请日:2004-03-19

    Abstract: The present invention relates to a process for preparing a catalyst for partial oxidation of propylene and iso-butylene, and more particularly to a process for preparing a catalyst for partial oxidation of propylene and iso-butylene that can stably prepare a catalyst that shows high activity for conversion of propylene and iso-butylene to obtain acrolein and methacrolein with a high yield, by dissolving salts of metals acting as a catalyst in a nitric acid aqueous solution or in an organic acid solution to prepare a catalyst suspension, drying the catalyst solution in a microwave oven, and then pulverizing and molding the dried catalyst, and calcining the catalyst.

    Abstract translation: 本发明涉及一种制备用于丙烯和异丁烯部分氧化的催化剂的方法,更具体地涉及一种制备用于丙烯和异丁烯的部分氧化的催化剂的方法,其可以稳定地制备显示高活性的催化剂 通过将作为催化剂的金属的盐溶解在硝酸水溶液或有机酸溶液中以制备催化剂悬浮液,将催化剂溶液干燥,从而将丙烯和异丁烯转化成高产率的丙烯醛和甲基丙烯醛 微波炉,然后粉碎和成型干燥的催化剂,并煅烧催化剂。

    CATALYST FOR WATER GAS SHIFT REACTION OF FUEL CELL AND PREPARATION METHOD THEREOF
    3.
    发明申请
    CATALYST FOR WATER GAS SHIFT REACTION OF FUEL CELL AND PREPARATION METHOD THEREOF 审中-公开
    燃料电池水汽转换反应催化剂及其制备方法

    公开(公告)号:US20070105716A1

    公开(公告)日:2007-05-10

    申请号:US11558319

    申请日:2006-11-09

    CPC classification number: B01J23/42 B01J23/50 B01J37/0238 C01B3/16 Y02P20/52

    Abstract: A catalyst for a water gas shift reaction of a fuel cell in which a titanium or silver is supported on a platinum, and a preparation method thereof, wherein the catalyst for the water gas shift reaction of the fuel cell can provide a superior conversion ratio of carbon monoxide and a superior generation ratio of hydrogen gas to thus supply a fuel having an enhanced quality to a stack unit of the fuel cell.

    Abstract translation: 用于钛或银负载在铂上的燃料电池的水煤气变换反应的催化剂及其制备方法,其中燃料电池的水煤气变换催化剂可提供优异的转化率 一氧化碳和优异的氢气发生率,从而向燃料电池的堆叠单元提供具有增强质量的燃料。

    Palladium-based catalyst for selective hydrogenation of acetylene
    4.
    发明授权
    Palladium-based catalyst for selective hydrogenation of acetylene 有权
    用于乙炔选择性氢化的钯基催化剂

    公开(公告)号:US07453017B2

    公开(公告)日:2008-11-18

    申请号:US10549774

    申请日:2004-03-26

    Abstract: The present invention describes a Pd-catalyst which further contains La, Ti, Nb, K or Si. The Pd-catalyst has a high ethylene selectivity even after a low temperature reduction in the selective hydrogenation of acetylene to ethylene. The invention also relates to the production of the catalyst. A catalyst of the invention consists essentially of 0.05 to 2.0% by weight, based on the supported catalyst, of palladium and one or two metals chosen form the group consisting of lanthanum, niobium, titanium, potassium and silicon. The catalyst can be prepared by the following procedure. (1) Impregnating a support in aqueous solution of tetra amine palladium hydroxide, followed by drying and calcination; (2) The second and, if necessary, a third metal is impregnated by impregnating the Pd-catalyst in the solution of the metal precursor followed by drying and calcination; (3) The catalyst according to step (2) is then reduced in hydrogen at 200° C. to 600° C. for 1 to 5 hours.

    Abstract translation: 本发明描述了还含有La,Ti,Nb,K或Si的Pd催化剂。 即使在乙炔选择性氢化成乙烯的低温还原之后,Pd-催化剂也具有高的乙烯选择性。 本发明还涉及催化剂的生产。 本发明的催化剂基本上由基于负载型催化剂的0.05-2.0重量%的钯和一种或两种选自镧,铌,钛,钾和硅的金属组成。 催化剂可以通过以下步骤制备。 (1)将载体浸渍在四胺氢氧化钯水溶液中,然后干燥和煅烧; (2)如果需要,通过将Pd催化剂浸渍在金属前体的溶液中,然后干燥和煅烧来浸渍第二金属和必要的第三金属; (3)然后将根据步骤(2)的催化剂在200℃至600℃的氢气中还原1至5小时。

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