公开(公告)号：US4560813A

公开(公告)日：1985-12-24

申请号：US594269

申请日：1984-03-28

Applicant: Joseph A. Collier

Inventor： Joseph A. Collier

IPC: B01J23/00 ,  B01J23/22 ,  B01J23/24 ,  B01J31/00 ,  B01J31/22 ,  B01J31/24 ,  C07B61/00 ,  C07C27/00 ,  C07C29/10 ,  C07C29/132 ,  C07C31/20 ,  C07C67/00 ,  C07C29/76 ,  C07C31/27 ,  C07C33/26

CPC classification number: C07C29/106 ,  Y02P20/52

Abstract: In processes for making alkylene glycols by the hydrolysis of alkylene oxides in the presence of selectivity-enhancing metalate anion-containing material, metalate anion can be recovered from the alkylene glycol-containing hydrolysis product by contact with a solid having electropositive complexing sites thereon such as anion exchange resins.

Abstract translation: 在通过在选择性增强的含金属化合物阴离子材料的存在下通过环氧烷水解制备亚烷基二醇的方法中，金属化物阴离子可以通过与其上具有正电性络合位点的固体接触而从含亚烷基二醇的水解产物中回收，例如 阴离子交换树脂。

公开(公告)号：US4982021A

公开(公告)日：1991-01-01

申请号：US206894

申请日：1988-06-08

Applicant: Robert D. Best ,  Joseph A. Collier ,  Brian T. Keen ,  John H. Robson

Inventor： Robert D. Best ,  Joseph A. Collier ,  Brian T. Keen ,  John H. Robson

IPC: C07C29/10

CPC classification number: C07C29/106 ,  C07C2101/14

Abstract: Alkylene glycols are produced by the reaction of alkylene oxide with water in the presence of a metalate-containing solid wherein the metalate is in association with electropositive complexing sites on a solid support such as an anion exchange resin.

Abstract translation: 在含金属盐的固体的存在下，通过烯化氧与水的反应制备亚烷基二醇，其中金属盐与固体载体如阴离子交换树脂上的正电性络合位点结合。