Graphite electrode for electrothermic reduction furnaces, electrode column, and method of producing graphite electrodes
    2.
    发明申请
    Graphite electrode for electrothermic reduction furnaces, electrode column, and method of producing graphite electrodes 审中-公开
    用于电热还原炉的石墨电极,电极柱和生产石墨电极的方法

    公开(公告)号:US20050254545A1

    公开(公告)日:2005-11-17

    申请号:US11123768

    申请日:2005-05-05

    申请人: Johann Daimer

    发明人: Johann Daimer

    摘要: A graphite electrode for an electrothermic reduction furnace is formed from anode grade coke and graphitized at a graphitization temperature below 2700° C. The resulting electrode is particularly suited for carbothermal reduction of alumina. It has an iron content of about 0.05% by weight, a specific electrical resistivity of above 5 μOhm·m, and a thermal conductivity of less than 150 W/m·K. The graphite electrode is manufactured by first mixing calcined anode coke with a coal-tar pitch binder, and a green electrode is formed from the mixture at a temperature close to the softening point of the pitch binder. The green electrode is then baked to carbonize the pitch binder to solid coke. The resultant carbonized electrode, after further optional processing is then graphitized at a temperature below 2700° C. for a time sufficient to cause the carbon atoms in the carbonized electrode to organize into the crystalline structure of graphite.

    摘要翻译: 用于电热还原炉的石墨电极由阳极级焦炭形成,并在低于2700℃的石墨化温度下石墨化。所得电极特别适用于氧化铝的碳热还原。 其铁含量为约0.05重量%,比电阻率高于5欧姆·米,热导率小于150瓦/米·克。 石墨电极通过首先将煅烧阳极焦炭与煤焦油沥青粘合剂混合而制成,并且在接近于沥青粘合剂的软化点的温度下由混合物形成绿色电极。 然后烘烤绿色电极,将沥青粘合剂碳化成固体焦炭。 然后在进一步任选的处理之后,将所得的碳化电极在低于2700℃的温度下石墨化足以使碳化电极中的碳原子组织成石墨的晶体结构的时间。

    Method for siliconizing carbon-containing materials
    3.
    发明授权
    Method for siliconizing carbon-containing materials 有权
    含碳材料硅化方法

    公开(公告)号:US07763224B2

    公开(公告)日:2010-07-27

    申请号:US11712401

    申请日:2007-03-01

    IPC分类号: C01B31/36 B05C3/09

    摘要: A method for treating workpieces that consist of porous carbon material with liquid silicon with the formation of silicon carbide, comprising the steps: Preheating porous carbon workpieces under inert gas to the selected operating temperature TB1, feeding liquid silicon to the porous carbon workpieces at an operating pressure pB2 and an operating temperature TB2, and impregnating the porous carbon workpieces with liquid silicon, reaction of the liquid silicon in the workpiece at a temperature TB3 with the formation of silicon carbide that consists of carbon and silicon, gassing the workpiece with inert gas and cooling from the operating temperature TB3 to the conditioning temperature Tk, cooling the workpieces to room temperature, the temperature TB3 being greater than or equal to the temperature TB2, and the workpiece in step d of the method no longer being in contact with liquid silicon outside of the workpiece.

    摘要翻译: 一种用于处理由多孔碳材料与液态硅组成的工件的碳化硅形成方法,包括以下步骤:将惰性气体下的多孔碳工件预热至所选择的工作温度TB1,在操作中将液态硅供给到多孔碳工件 压力pB2和工作温度TB2,并用液态硅浸渍多孔碳工件,工件中液态硅在温度TB3下反应,形成由碳和硅组成的碳化硅,用惰性气体气化工件, 从工作温度TB3到调节温度Tk的冷却,将工件冷却至室温,温度TB3大于或等于温度TB2,并且该方法的步骤d中的工件不再与外部的液态硅接触 的工件。

    Method and Device For Siliconization of Carbon-Containing Materials
    4.
    发明申请
    Method and Device For Siliconization of Carbon-Containing Materials 有权
    含碳材料硅化的方法和装置

    公开(公告)号:US20090149308A1

    公开(公告)日:2009-06-11

    申请号:US12212452

    申请日:2008-09-17

    IPC分类号: C04B35/52 B01J8/04

    摘要: Method for treatment of workpieces of porous carbon material with liquid silicon with the formation of silicon carbide, comprising the following steps: preheating of porous carbon workpieces under an inert gas to a selected operating temperature TB1, delivery of liquid silicon to the porous carbon workpieces at an operating pressure pB2 and an operating temperature TB2 and impregnation of the porous carbon workpieces with liquid silicon, reaction of the liquid silicon in the workpiece at a temperature TB3 with formation of silicon carbide from carbon and silicon, gassing of the workpieces with inert gas, and cooling from the operating temperature TB3 to a conditioning temperature Tk, cooling of workpieces to room temperature, in step c the delivery of silicon and transport of the workpieces taking place over preferably cylindrical rolls which are porous at least in the exterior region and which are pivoted, and their speed of rotation determining the residence time for the delivery of silicon in step c, and the temperature TB3 being greater than or equal to the temperature TB2, and the workpieces for process step d no longer being in contact with liquid silicon outside the workpieces.

    摘要翻译: 用液态硅处理碳化硅的多孔碳材料工件的方法,包括以下步骤:将惰性气体下的多孔碳工件预热到选定的工作温度TB1,将液态硅输送到多孔碳工件上 操作压力pB2和操作温度TB2,并且用液态硅浸渍多孔碳工件,在温度TB3下工件中的液态硅与碳和硅形成碳化硅的反应,用惰性气体气化工件, 并从工作温度TB3到调节温度Tk的冷却,工件冷却至室温,步骤c中硅的输送和工件的运输,优选至少在外部区域是多孔的圆柱形辊, 枢转,并且其旋转速度决定了运送的停留时间 步骤c中的硅,温度TB3大于或等于温度TB2,并且处理步骤d的工件不再与工件外部的液态硅接触。

    Gas-tight electrode for carbothermic reduction furnace
    6.
    发明申请
    Gas-tight electrode for carbothermic reduction furnace 审中-公开
    用于碳热还原炉的气密电极

    公开(公告)号:US20050254544A1

    公开(公告)日:2005-11-17

    申请号:US11123774

    申请日:2005-05-05

    申请人: Johann Daimer

    发明人: Johann Daimer

    CPC分类号: C22B21/02 C22B4/02 H05B7/07

    摘要: A graphite electrode for an electrothermic reduction furnace in which aluminum is produced by carbothermic reduction of alumina is rendered substantially gas-impermeable. The graphite electrode is consumed during furnace operation and electrode columns connected by graphite pins are fed continuously fed in from the top into the furnace. The coating of the electrode withstands a temperature of up to 300° C. and more over a period of several hours without oxidation. Since the coating enters the furnace compartment at least partially, it is configured so that it will not contaminate the hot melt. That is, the chemistry of the coating materials is similar to 1o the ingredients of the overall reaction or, at a minimum, the amount of foreign elements is very low. The coating is provided so that it does not increase the electrical contact resistance at the connection between the electrode columns and the electrode holding clamps. Where the electrode inlet area is cooled by water, the coating is insoluble in water.

    摘要翻译: 通过氧化铝的碳热还原法制造铝的电热还原炉用石墨电极基本上不透气。 在炉操作期间消耗石墨电极,并且通过石墨引脚连接的电极柱从顶部连续地进料到炉中。 电极的涂层耐受高达300℃的温度,并在几个小时的时间内耐受氧化。 由于涂层至少部分地进入炉室,因此其被构造成不会污染热熔体。 也就是说,涂料的化学性质与总反应的成分相似,或至少外来元素的量非常低。 提供涂层,使得其不增加电极柱和电极夹持夹具之间的连接处的电接触电阻。 在电极入口区域被水冷却的地方,涂层不溶于水。

    Glass sealant containing lead borate glass and fillers of mullite and
cordierite
    7.
    发明授权
    Glass sealant containing lead borate glass and fillers of mullite and cordierite 失效
    玻璃密封胶含有铅玻璃和填充物

    公开(公告)号:US5145803A

    公开(公告)日:1992-09-08

    申请号:US600510

    申请日:1990-10-22

    IPC分类号: C04B37/00 C03C8/10 C03C8/24

    CPC分类号: C03C8/245

    摘要: A glass sealant comprises a mixture of about 70-90% of a solder glass powder of a low-melting lead-borate glass with a transformation temperature of 330.degree. C. or lower, 1-20% by weight of cordierite powder, and 1-25% by weight of mullite powder, with the combined content of cordierite and mullite powder being from about 10-30%. The lead-borate glass comprises from about 82-88% by weight of PbO, 12-17% by weight of B.sub.2 O.sub.3, 0-1% by weight of SiO.sub.2, and 0-1% by weight of Al.sub.2 O.sub.3. Both the cordierite and mullite powder are preferably synthetically produced to reduce the .alpha.-radiation. The synthetically produced cordierite powder preferably still contains up to about 9% by weight of a non-crystalline vitreous phase. The grain size of the powders is preferably under 100 microns. This glass sealant has well-balanced properties relative to thermal expansion, melting temperature, dielectric constant, loss angle, mechanical strength, thermal shock resistance, and chemical resistance. It is particularly suitable as ceramic dual-line package solder (CERDIP) for sealing of aluminum oxide housings for integrated circuits.

    摘要翻译: 玻璃密封剂包括约70-90%的低熔点硼酸铅玻璃的焊料玻璃粉末与转化温度为330℃或更低,1-20重量%的堇青石粉末和1 -25重量%的莫来石粉末,堇青石和莫来石粉末的组合含量为约10-30%。 铅硼酸盐玻璃包含约82-88重量%的PbO,12-17重量%的B 2 O 3,0-1重量%的SiO 2和0-1重量%的Al 2 O 3。 优选合成制备堇青石和莫来石粉末以减少α-辐射。 合成生产的堇青石粉末优选还含有至多约9重量%的非结晶玻璃质相。 粉末的粒径优选在100微米以下。 该玻璃密封剂相对于热膨胀,熔融温度,介电常数,损耗角,机械强度,耐热冲击性和耐化学性而具有良好的平衡性。 特别适用于用于集成电路的氧化铝壳体的密封的陶瓷双线包装焊料(CERDIP)。

    Process for producing ceramic materials using silicon carbide
    8.
    发明授权
    Process for producing ceramic materials using silicon carbide 有权
    使用碳化硅生产陶瓷材料的方法

    公开(公告)号:US08182738B2

    公开(公告)日:2012-05-22

    申请号:US12883361

    申请日:2010-09-16

    IPC分类号: B32B3/26 B28B1/00

    摘要: Process for producing bodies from ceramic materials using silicon carbide, comprising the steps: configuration of fiber-reinforced porous bodies (1, 5) that consist of carbon on a base (2) that is inert relative to liquid silicon, the bodies having cavities (3) that are accessible from the exterior or surface recesses (3′), and the cavities (3) being closed at the bottom in the porous bodies or the surface recesses (3′) together with the base (2) forming a reservoir that is sealed at the bottom; heating the configuration by introduction of energy to melt the silicon (6) that is present in the reservoir; and infiltrating the melted silicon in the bodies (1, 5) and reaction of the silicon with the carbon to form silicon carbide; and use of the thus produced bodies as brake disks and as clutch driving disks.

    摘要翻译: 该方法包括以下步骤:在相对于液态硅为惰性的基体(2)上由碳组成的纤维增强多孔体(1,5)的构造,所述主体具有空腔( 3),其可从外部或表面凹部(3')接近,并且空腔(3)与底部(2)一起在多孔体或表面凹部(3')的底部封闭,形成储存器 在底部密封; 通过引入能量来熔化存在于储存器中的硅(6)来加热构造; 并浸入体(1,5)中的熔融硅并使硅与碳反应形成碳化硅; 并使用如此制造的本体作为制动盘和离合器驱动盘。

    Method for using fracture resistant electrodes in a carbothermic reduction furnace
    9.
    发明授权
    Method for using fracture resistant electrodes in a carbothermic reduction furnace 失效
    在碳热还原炉中使用断裂电极的方法

    公开(公告)号:US07736413B2

    公开(公告)日:2010-06-15

    申请号:US12233216

    申请日:2008-09-18

    申请人: Johann Daimer

    发明人: Johann Daimer

    IPC分类号: C22B4/08 C25B11/12

    摘要: Graphite electrodes for the production of aluminum by carbothermic reduction of alumina are either submerged in the molten bath in the low temperature compartment or they are horizontally arranged in the side walls of the high temperature compartment. The electrodes are manufactured by using a mixture of coke particles covering the complete particle size range between 25 μm to 3 mm and by using an intensive mixer to effectively wet all coke particles with pitch. The electrodes have a flexural strength of at least 20 N/mm2. By using a complete range (continuum) of particle sizes in conjunction with an intensive mixer, the geometric packing of the particles is significantly improved, hence the material density is increased and thus a higher mechanical strength as well as improved electrical conductivity in comparison to conventional graphite electrodes is achieved.

    摘要翻译: 通过碳氧化还原氧化铝生产铝的石墨电极被浸没在低温隔室中的熔池中,或者水平地布置在高温隔室的侧壁中。 通过使用覆盖25μm至3mm之间的完整粒度范围的焦炭颗粒的混合物并通过使用强化混合器来有效地润湿所有具有沥青的焦炭颗粒来制造电极。 电极的弯曲强度至少为20N / mm2。 通过与浓缩混合器结合使用粒度的完整范围(连续体),颗粒的几何填料显着提高,因此与常规的相比,材料密度增加,因此具有更高的机械强度以及改善的导电性 实现石墨电极。

    Method for siliconizing carbon-containing Materials
    10.
    发明申请
    Method for siliconizing carbon-containing Materials 有权
    含碳材料硅化方法

    公开(公告)号:US20080213155A1

    公开(公告)日:2008-09-04

    申请号:US11712401

    申请日:2007-03-01

    IPC分类号: C01B31/36 B01J19/00

    摘要: A method for treating workpieces that consist of porous carbon material with liquid silicon with the formation of silicon carbide, comprising the steps: Preheating porous carbon workpieces under inert gas to the selected operating temperature TB1, feeding liquid silicon to the porous carbon workpieces at an operating pressure pB2 and an operating temperature TB2, and impregnating the porous carbon workpieces with liquid silicon, reaction of the liquid silicon in the workpiece at a temperature TB3 with the formation of silicon carbide that consists of carbon and silicon, gassing the workpiece with inert gas and cooling from the operating temperature TB3 to the conditioning temperature Tk, cooling the workpieces to room temperature, the temperature TB3 being greater than or equal to the temperature TB2, and the workpiece in step d of the method no longer being in contact with liquid silicon outside of the workpiece.

    摘要翻译: 一种用于处理由多孔碳材料与液态硅组成的工件,形成碳化硅的方法,包括以下步骤:将惰性气体下的多孔碳工件预热至所选择的操作温度T B 1, 硅在工作压力p B 2 2和工作温度T B 2下与多孔碳工件接触,并用液态硅浸渍多孔碳工件,液态硅 在由碳和硅组成的碳化硅形成的温度为T 3 B 3的工件中,用惰性气体吹送工件,并从工作温度T B B 3到调理温度T k,将工件冷却至室温,温度T B 3 3大于或等于温度T B 2,并且步骤d中的工件不再与外部的液态硅接触 工件。