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1.
公开(公告)号:US5783514A
公开(公告)日:1998-07-21
申请号:US307759
申请日:1994-09-26
Applicant: Klaus-Peter Schick , Franz-Josef Carduck , Gerd Goebel , Hans-Georg Rollberg
Inventor: Klaus-Peter Schick , Franz-Josef Carduck , Gerd Goebel , Hans-Georg Rollberg
CPC classification number: B01J23/44 , B01J37/0207 , C11C3/126
Abstract: The invention is an improved palladium-containing catalyst and process for preparing the catalyst. The catalyst is prepared by impregnating a dry activated carbon with a pH above 8 with a solution of palladium salt, separating the aqueous phase from the impregnated activated carbon when the aqueous phase has reached a pH of at least 1 and reducing the palladium which is supported on the activated carbon.
Abstract translation: PCT No.PCT / EP93 / 00643 Sec。 371日期:1994年9月26日 102(e)1994年9月26日PCT 1993年3月18日PCT公布。 公开号WO93 / 18856 日期1993年9月30日本发明是一种改进的含钯催化剂及其制备方法。 催化剂是通过用钯盐溶液浸渍pH高于8的干活性炭制备的,当水相达到至少1的pH并且还原负载的钯时,将水相与浸渍的活性炭分离 在活性炭上。
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2.
公开(公告)号:US4808562A
公开(公告)日:1989-02-28
申请号:US80192
申请日:1987-07-30
Applicant: Hans-Peter Kubersky , Hans-Georg Rollberg
Inventor: Hans-Peter Kubersky , Hans-Georg Rollberg
IPC: C07C29/136 , B01J23/80 , B01J31/02 , B01J33/00 , B01J37/02 , B01J37/18 , C07B61/00 , C07C27/00 , C07C29/149 , C07C31/125 , C07C67/00 , B01J31/34 , B01J31/26 , B01J31/28
CPC classification number: B01J31/0209 , B01J23/80 , B01J31/0202 , B01J33/00 , B01J37/0219 , B01J37/0221 , B01J37/18 , B01J2231/641 , Y10S502/50
Abstract: A process for the production of catalyst materials stabilized in the active state, comprising activating the catalyst starting materials in a reducing gas atmosphere, impregnating the activated catalysts with the melt of a solid inert to the active catlayst, and solidifying the melt impregnation by cooling. The particulate catalyst starting material is passed under the reaction conditions of the activation stage through a reaction zone filled with the reducing gas atmosphere which is in direct contact with the melt of the impregnating solid; the activated catalyst material is introduced into this melt; subsequently removed therefrom; and the molten solid left to solidify. If desired, the impregnated catalyst material may be mechanically size-reduced.
Abstract translation: 一种制备稳定在活性状态的催化剂材料的方法,包括在还原气体气氛中活化催化剂原料,用活性催化剂惰性的固体熔体浸渍活化的催化剂,并通过冷却固化熔融浸渍。 颗粒催化剂原料在活化阶段的反应条件下通过填充有与浸渍固体的熔体直接接触的还原气体气氛的反应区; 将活化的催化剂材料引入该熔体中; 随后从中除去; 并使熔融固体固化。 如果需要,可以机械地减小浸渍的催化剂材料。
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