公开(公告)号：US07357982B2

公开(公告)日：2008-04-15

申请号：US10517832

申请日：2003-06-26

Applicant: Yukihiro Abe ,  Go Matsuoka ,  Kohei Kiriyama ,  Hiroki Murase ,  Muneatsu Nakamura ,  Yukihiro Nomura ,  Hironori Eguchi ,  Yukinari Okuyama ,  Tadao Kuroki ,  Takaharu Ichiryu ,  Hiroshi Tachimori

Inventor： Yukihiro Abe ,  Go Matsuoka ,  Kohei Kiriyama ,  Hiroki Murase ,  Muneatsu Nakamura ,  Yukihiro Nomura ,  Hironori Eguchi ,  Yukinari Okuyama ,  Tadao Kuroki ,  Takaharu Ichiryu ,  Hiroshi Tachimori

IPC: D02G3/00

CPC classification number: E04C5/07 ,  B63H9/0657 ,  B63H2009/0678 ,  D01F6/74 ,  D07B1/025 ,  D07B2205/2096 ,  E04C5/073 ,  Y10T428/2913 ,  Y10T428/2967 ,  Y10T428/2969 ,  D07B2801/10

Abstract: The present invention relates to polybenzazole fibers or filaments, staple fibers, spun yarns, and woven or knitted fabrics containing in themselves an organic pigment having heat resistance as high as a thermal decomposition temperature of 200° C. or higher, and soluble in a mineral acid and having group(s) of —N═ and/or NH— in the molecule, such as any of perinones and/or perylenes, any of phthalocyanines, any of quinacridones, and any of dioxazines, wherein they have a strength retention of 50% or higher when exposed to light from a xenon lamp for 100 hours and having a tensile strength retention of 85% or higher after exposed to an atmosphere of a temperature of 80° C. and a relative humidity of 80% for 700 hours.The polybenzazole fibers or filaments, staple fibers, spun yarns, and woven or knitted fabrics can be used for cords for reinforcing rubber, sheets and rods for reinforcing cement/concrete, composite materials, sail clothes, ropes, knife proof vests and bullet proof vests.

Abstract translation: 本发明涉及聚吲哚纤维或长丝，短纤维，短纤纱，以及其本身含有耐热性高达200℃或更高的热分解温度的有机颜料并可溶于矿物的机织或针织织物 酸和在分子中具有-N和/或NH-的基团，例如百里香酮和/或苝中的任何一种，酞菁，任何喹吖啶酮和任何二恶嗪，其中它们的强度保留为 当暴露于来自氙灯的光100小时并且在暴露于80℃的温度和80％的相对湿度的气氛中700小时之后的拉伸强度保持率为85％或更高时，为50％或更高。 聚吲哚纤维或长丝，短纤维，短纤纱和机织或针织织物可用于增强橡胶，用于增强水泥/混凝土，复合材料，帆衣，绳索，防刀背心和防弹背心的橡胶，片材和棒材的帘线 。

公开(公告)号：US20060046049A1

公开(公告)日：2006-03-02

申请号：US10518406

申请日：2003-06-26

Applicant: Yukihiro Abe ,  Go Matsuoka ,  Kohei Kiriyama ,  Hiroki Murase ,  Muneatsu Nakamura ,  Yokihiro Nomura ,  Hironori Eguchi ,  Yukinari Okuyama ,  Tadao Kuroki ,  Takaharu Ichiryu

Inventor： Yukihiro Abe ,  Go Matsuoka ,  Kohei Kiriyama ,  Hiroki Murase ,  Muneatsu Nakamura ,  Yokihiro Nomura ,  Hironori Eguchi ,  Yukinari Okuyama ,  Tadao Kuroki ,  Takaharu Ichiryu

IPC: D02G3/00

CPC classification number: C08G73/22 ,  C08G73/18 ,  D01F1/10 ,  D01F6/74 ,  Y10T428/2913

Abstract: There is provided a polybenzazole fiber or film containing a basic organic compound in the form of a monomer or a condensate, selected from the group consisting of guanidines, triazoles, quinazolines, piperidines, anilines, pyridines, cyanuric acids, and p-phenylenediamine, m-phenylenediamine and a mixture thereof. This fiber has characteristics in that the X-ray meridian diffraction half-width factor is 0.3°/GPa or less, that the elasticity decrement (Er) attributed to change of molecular orientation is 30 GPa or less, and that the breaking strength is 1 GPa or more. This fiber can be used in staple fiber, a spun yarn, a woven or knit fabric, a felt material, a composite material, a cord, a rod, a fibrous sheet, a knife proof vest or a bullet proof vest.

Abstract translation: 提供了含有选自胍，三唑，喹唑啉，哌啶，苯胺，吡啶，氰尿酸和对苯二胺的单体或缩合物形式的碱性有机化合物的聚吲唑纤维或膜 - 苯二胺及其混合物。 该纤维的特征在于X射线子午线衍射半值因子为0.3°/ GPa以下，归因于分子取向的变化引起的弹性减量（Er）为30GPa以下，断裂强度为1 GPa或更多。 该纤维可以用于短纤维，细纱，纺织或针织织物，毡材，复合材料，帘线，棒，纤维片，防刀背心或防弹背心中。

公开(公告)号：US06335419B2

公开(公告)日：2002-01-01

申请号：US09731394

申请日：2000-12-05

Applicant: Go Matsuoka ,  Fuyuhiko Kubota

Inventor： Go Matsuoka ,  Fuyuhiko Kubota

IPC: C08G6300

CPC classification number: C08G75/32 ,  C08G73/18 ,  C08G73/22 ,  D01F6/74

Abstract: A polybenzazoleolybenzazole having a residual content of a BB-PBZ monomer of not more than 0.010 wt %, which is obtained by dehydration polymerization condensation of an AA-PBZ monomer of the formula (I) wherein Ar is a quadrivalent aromatic organic residue and X is O, S or NH, and a BB-PBZ monomer of the formula (II) W—Z—W  (II) wherein Z is an optionally substituted divalent aromatic organic residue and W is a carboxyl group or a group derived from the carboxyl group, which is reactive with —XH in the AA-PBZ monomer. Because the residual content of the BB-PBZ monomer in polybenzazole is not more than 0.010 wt %, a polybenzazole fiber having a small filament denier can be produced stably at a high speed without suffering from thread breakage during the production.

Abstract translation: 通过其中Ar是四价芳族有机残基的式（I）的AA-PBZ单体和X是通过其脱水聚合缩合获得的具有不大于0.010重量％的BB-PBZ单体的残留含量的聚苯并唑聚吲哚 O，S或NH，和式（II）的BB-PBZ单体，其中Z是任选取代的二价芳族有机残基，W是羧基或衍生自羧基的基团，其与-XH的反应性 AA-PBZ单体。 由于聚吲哚中的BB-PBZ单体的残留量不大于0.010重量％，所以可以高速稳定地制造具有小丝旦数的聚吲哚纤维，而在生产过程中不会发生断线。

公开(公告)号：US5911908A

公开(公告)日：1999-06-15

申请号：US95366

申请日：1998-06-10

Applicant: Go Matsuoka ,  Fuyuhiko Kubota

Inventor： Go Matsuoka ,  Fuyuhiko Kubota

IPC: C07C213/10 ,  C07C215/80 ,  C08G73/22 ,  C09K3/00

CPC classification number: C08G73/22 ,  C07C213/10

Abstract: A method for stabilizing DAR during storage, comprising storing DAR in the presence of a reducing agent having a standard redox potential of not less than -0.20 volt and not more than 0.34 volt, in a proportion of not less than 100 ppm and not more than 10,000 ppm of DAR. The present invention improves storage stability of DAR. This in turn results in easy handling and long-term preservation of DAR. Thus, a high quality polymer PBO can be easily produced and the invention greatly contributes to the industrial field.

Abstract translation: 一种用于在储存期间稳定DAR的方法，包括在具有不低于100ppm且不大于0.34V的比例的标准氧化还原电位不低于-0.20V且不大于0.34伏的存在下存储DAR 10,000 ppm的DAR。 本发明提高了DAR的储存稳定性。 这反过来导致DAR的易于处理和长期保存。 因此，可以容易地制造高质量的聚合物PBO，并且本发明对工业领域有很大的贡献。

公开(公告)号：US20060083923A1

公开(公告)日：2006-04-20

申请号：US10517832

申请日：2003-06-26

Applicant: Yukihiro Abe ,  Go Matsuoka ,  Kohei Kiriyama ,  Hiroki Murase ,  Muneatsu Nakamura ,  Yukihiro Nomura ,  Hironori Eguchi ,  Yukinari Okuyama ,  Tadao Kuroki ,  Takaharu Ichiryu ,  Hiroshi Tachimori

Inventor： Yukihiro Abe ,  Go Matsuoka ,  Kohei Kiriyama ,  Hiroki Murase ,  Muneatsu Nakamura ,  Yukihiro Nomura ,  Hironori Eguchi ,  Yukinari Okuyama ,  Tadao Kuroki ,  Takaharu Ichiryu ,  Hiroshi Tachimori

IPC: B32B27/34

CPC classification number: E04C5/07 ,  B63H9/0657 ,  B63H2009/0678 ,  D01F6/74 ,  D07B1/025 ,  D07B2205/2096 ,  E04C5/073 ,  Y10T428/2913 ,  Y10T428/2967 ,  Y10T428/2969 ,  D07B2801/10

Abstract: The present invention relates to polybenzazole fibers or filaments, staple fibers, spun yarns, and woven or knitted fabrics containing in themselves an organic pigment having heat resistance as high as a thermal decomposition temperature of 200° C. or higher, and soluble in a mineral acid and having group(s) of —N=and/or NH— in the molecule, such as any of perinones and/or perylenes, any of phthalocyanines, any of quinacridones, and any of dioxazines, wherein they have a strength retention of 50% or higher when exposed to light from a xenon lamp for 100 hours and having a tensile strength retention of 85% or higher after exposed to an atmosphere of a temperature of 80° C. and a relative humidity of 80% for 700 hours. The polybenzazole fibers or filaments, staple fibers, spun yarns, and woven or knitted fabrics can be used for cords for reinforcing rubber, sheets and rods for reinforcing cement/concrete, composite materials, sail clothes, ropes, knife proof vests and bullet proof vests.

Abstract translation: 本发明涉及聚吲哚纤维或长丝，短纤维，短纤纱，以及其本身含有耐热性高达200℃或更高的热分解温度的有机颜料并可溶于矿物的机织或针织织物 酸和在分子中具有-N =和/或NH-的基团，例如百里香酮和/或苝中的任何一种，酞菁，任何喹吖啶酮和任何二恶嗪，其中它们具有 当暴露于来自氙灯的光100小时并且在暴露于80℃的温度和80％的相对湿度的气氛中700小时之后的拉伸强度保持率为85％或更高时，为50％或更高。 聚吲哚纤维或长丝，短纤维，短纤纱和机织或针织织物可用于增强橡胶，用于增强水泥/混凝土，复合材料，帆衣，绳索，防刀背心和防弹背心的橡胶，片材和棒材的帘线 。