公开(公告)号：US4139218A

公开(公告)日：1979-02-13

申请号：US828533

申请日：1977-08-29

申请人： Gerald T. Davis ,  Gerhart Schwab ,  Dale R. Shackle

发明人： Gerald T. Davis ,  Gerhart Schwab ,  Dale R. Shackle

IPC分类号： B41L1/36 ,  B41M5/132 ,  B41M5/155 ,  B41M5/165 ,  B41M5/22

CPC分类号： B41L1/36 ,  B41M5/132 ,  Y10S428/914 ,  Y10T428/264 ,  Y10T428/265 ,  Y10T428/277 ,  Y10T428/2984 ,  Y10T428/2987

摘要： A pressure-sensitive carbonless transfer sheet comprising a paper substrate having a front and back surface and a coating composition adhered to at least one of the front and back surfaces of the paper substrate. A novel process is provided for producing a pressure-sensitive carbonless transfer sheet which comprises the steps of preparing a hot melt suspending medium, the hot melt suspending medium being water insoluble and having a melting point of from about 60.degree. C. to about 140.degree. C. and a melting point range of less than about 15.degree. C. A microencapsulated chromogenic material is prepared and dispersed in the hot melt suspending medium, the chromogenic material being a color precursor of the electron donating type. A coating dispersion is prepared by combining the hot melt suspending medium with the microencapsulated chromogenic color precursor material, the hot melt suspending medium being compatible with the color forming or developing characteristics of the chromogenic material. The coating dispersion is then applied to a substrate, the coating dispersion being applied at a coat weight of from about 1.0 pounds to about 8.0 pounds per 3300 square feet of substrate at a coat thickness of from about 1 micron to about 50 microns. The coated substrate is set by cooling the coating dispersion.

摘要翻译： 一种压敏无碳转印片，其包含具有前表面和后表面的纸基材和粘附到纸基材的前表面和后表面中的至少一个上的涂料组合物。 提供一种用于生产压敏无碳转印片的新方法，其包括制备热熔悬浮介质的步骤，该热熔悬浮介质是水不溶性的，熔点为约60℃至约140℃ 并且熔点范围小于约15℃。制备微胶囊化的显色材料并将其分散在热熔悬浮介质中，显色材料是供电类型的彩色前体。 通过将热熔悬浮介质与微胶囊化的显色前体材料组合，制备涂层分散体，热熔悬浮介质与显色材料的成色或显色特性相容。 然后将涂料分散体施加到基材上，涂层分散体以约1磅至约8.0磅/ 3300平方英尺的基材以约1微米至约50微米的涂层厚度施用。 涂覆的基材通过冷却涂层分散体来设定。

公开(公告)号：US3932695A

公开(公告)日：1976-01-13

申请号：US610766

申请日：1967-01-23

申请人： Gerald T. Davis ,  Robert A. Fetters

发明人： Gerald T. Davis ,  Robert A. Fetters

IPC分类号： A01K63/00 ,  A01K67/033 ,  B41M5/155 ,  B32B27/08 ,  B32B27/42 ,  B41M3/12 ,  B41M5/00

CPC分类号： B41M5/155 ,  A01K63/003 ,  A01K67/033 ,  Y10S428/914 ,  Y10T428/265 ,  Y10T428/277 ,  Y10T428/31967 ,  Y10T428/31993

摘要： A relatively uniform thin coating of a solid phenolic reactant can be applied to a paper base by contacting said paper base with a thin film of a solution consisting essentially of said phenolic reactant in a volatile organic solvent and immediately evaporating said solvent and, unexpectedly, said phenolic reactant is retained essentially completely on the contacted surface of the paper base. Thusly applied, it has been found that well defined colored marks are formed on the surface of the paper base on marking the surface with a colorless marking ink.

公开(公告)号：US4356108A

公开(公告)日：1982-10-26

申请号：US105445

申请日：1979-12-20

申请人： Gerhart Schwab ,  Gerald T. Davis

发明人： Gerhart Schwab ,  Gerald T. Davis

IPC分类号： B01J13/16 ,  B41M5/165 ,  B01J13/02

CPC分类号： B41M5/165 ,  B01J13/16 ,  Y10S428/914

摘要： A process for the preparation of oil-containing microcapsules by interfacial condensation of a polyfunctional amine with a polyfunctional wall-forming material is disclosed. Microcapsules produced by this process have utility in the manufacture of carbonless copy paper. The process comprises emulsifying a mixture of a hydrophobic phase, which includes an oil, a chromogenic material and an oil soluble polyfunctional wall-forming material, and a hydrophilic phase, which includes water, a water soluble emulsifying agent and a water soluble salt of the desired polyfunctional amine. The amine salt may be formed in situ in the hydrophilic phase before the emulsification step. After emulsification, sufficient base is added to the emulsion to convert the polyfunctional amine salt to a polyfunctional amine and to neutralize acid formed during subsequent condensation reactions, thus initiating the reaction of the polyfunctional amine with the oil soluble polyfunctional wall-forming material and thus forming microcapsule walls around droplets of the hydrophobic phase.

摘要翻译： 公开了通过多官能胺与多官能壁形成材料的界面缩合来制备含油微胶囊的方法。 通过该方法生产的微胶囊可用于制造无碳复写纸。 该方法包括将包含油，显色材料和油溶性多官能壁形成材料的疏水相的混合物和亲水相乳化，所述亲水相包括水，水溶性乳化剂和水溶性盐 所需的多官能胺。 胺盐可以在乳化步骤之前在亲水相中原位形成。 乳化后，向乳液中加入足够的碱以将多官能胺盐转化为多官能胺并中和后续缩合反应中形成的酸，从而引发多官能胺与油溶性多官能壁形成材料的反应，从而形成 疏水相液滴周围的微胶囊壁。

公开(公告)号：US4296947A

公开(公告)日：1981-10-27

申请号：US9382

申请日：1979-02-02

申请人： Sydney M. Spatz ,  Robert C. Hydell ,  Gerald T. Davis

发明人： Sydney M. Spatz ,  Robert C. Hydell ,  Gerald T. Davis

IPC分类号： B41M5/132 ,  B41M5/22

CPC分类号： B41M5/132 ,  Y10S428/914 ,  Y10T428/31895 ,  Y10T428/31906

摘要： A process is provided for producing a pressure-sensitive carbonless transfer sheet comprising preparing a solution of a first chromogenic material, the solution of the first chromogenic material including at least one chromogenic compound dissolved in a carrier oil, and the first chromogenic material being reactive with a second chromogenic material in the presence of the carrier oil to form a color. The solution of the first chromogenic material is mixed with a liquid radiation curable substance to form a coating composition, the liquid radiation curable substance being curable to a frangible resin and compatible with the color-forming capabilities of said first chromogenic material. A film forming material is applied to a substrate, the film forming material being settable to form a barrier layer which substantially prevents penetration of the substrate by the coating composition upon application of the coating composition to the substrate. The film forming material is then set to form the barrier layer on the substrate, and a film of the coating composition is applied over the barrier layer. The coating composition is then cured by subjecting the coating composition to radiation for a period of time sufficient to cure the coating composition containing the radiation curable substance to a frangible resinous film, the frangible resinous film being cured to a frangibility that will permit passage of the solution of the first chromogenic material to the exposed surface of the frangible resinous film when the frangible resinous film is broken. A novel chromogenic composition is produced comprising at least one color precursor dissolved in a carrier oil, the carrier oil being a weakly polar solvent having a boiling point of from about 180.degree. C. to about 300.degree. C., the color precursor being of the electron donor type and being reactive with color developers of the electron acceptor type to form an image and a liquid radiation curable substance, the liquid radiation curable substance being selected from the group consisting of isocyanate modified acrylic, methacrylic and itaconic acid esters of polyhydric alcohols, acrylic prepolymers derived from partial esterification of pentaerythritol with acrylic acid and acrylic acid esters and mixtures thereof, the liquid radiation curable substance being curable to a frangible resin upon exposure to radiation. The coating composition has a viscosity in the range of about 1000 cps. to about 3500 cps. A pressure-sensitive, carbonless transfer sheet is produced comprising a paper substrate having coated thereon a barrier layer and a cured resinous film coated on said barrier layer, the cured resinous film being a radiation cured film of the novel chromogenic coating composition having a frangibility that will permit passage of the color precursor and the carrier oil to the surface of the cured resinous film when the cured resinous film is broken, the color precursor solution being retained as small occulsions within a matrix of closely packed cross-linked molecular chains of cured resin.

公开(公告)号：US4186115A

公开(公告)日：1980-01-29

申请号：US915506

申请日：1978-06-14

申请人： Sydney M. Spatz ,  Robert C. Hydell ,  Gerald T. Davis

发明人： Sydney M. Spatz ,  Robert C. Hydell ,  Gerald T. Davis

IPC分类号： B41M5/132 ,  C09D11/00 ,  C08L91/00

CPC分类号： C09D11/50 ,  B41M5/132 ,  Y10S428/914

摘要： A novel chromogenic composition is produced comprising at least one color precursor dissolved in a carrier oil, the carrier oil being a weakly polar solvent having a boiling point of from about 180.degree. C. to about 300.degree. C., the color precursor being of the electron donor type and being reactive with color developers of the electron acceptor type to form an image and a liquid radiation curable substance, the liquid radiation curable substance being selected from the group consisting of isocyanate modified acrylic, methacrylic and itaconic acid esters of polyhydric alcohols, acrylic prepolymers derived from partial esterification of pentaerythritol with acrylic acid and acrylic acid esters and mixtures thereof, the liquid radiation curable substance being curable to a frangible resin upon exposure to radiation. The coating composition has a viscosity in the range of about 1000 cps. to about 3500 cps. A pressure-sensitive, carbonless transfer sheet is produced comprising a paper substrate having coated thereon a barrier layer and a cured resinous film coated on said barrier layer, the cured resinous film being a radiation cured film of the novel chromogenic coating composition having a frangibility that will permit passage of the color precursor and the carrier oil to the surface of the cured resinous film when the cured resinous film is broken, the color precursor solution being retained as small occlusions within a matrix of closely packed cross-linked molecular chains of cured resin.

摘要翻译： 产生新的显色组合物，其包含溶解在载体油中的至少一种着色前体，所述载体油是沸点为约180℃至约300℃的弱极性溶剂，所述着色前体为 电子给体型，并与电子受体型的显影剂反应形成图像和液体可辐射固化物质，该液体辐射固化物质选自异氰酸酯改性的丙烯酸酯，甲基丙烯酸和多元醇的衣康酸酯， 衍生自季戊四醇与丙烯酸和丙烯酸酯及其混合物的部分酯化的丙烯酸类预聚物，该液体辐射固化性物质在暴露于辐射时可固化至易碎树脂。 涂料组合物的粘度在约1000cps的范围内。 至约3500 cps。 制造压敏的无碳转印片，其包括在其上涂覆有阻挡层的纸基材和涂覆在所述阻挡层上的固化树脂膜，所述固化树脂膜是新型显色涂料组合物的辐射固化膜，其易碎性为 当固化的树脂膜断裂时，允许着色前体和载体油通过到固化的树脂膜的表面，着色前体溶液被保持为紧密堆积的固化树脂交联分子链的基质内 。

公开(公告)号：US4143890A

公开(公告)日：1979-03-13

申请号：US747682

申请日：1976-12-06

申请人： Gerald T. Davis ,  Gerhart Schwab ,  Dale R. Shackle

发明人： Gerald T. Davis ,  Gerhart Schwab ,  Dale R. Shackle

IPC分类号： B41L1/36 ,  B41M5/132 ,  B41M5/155 ,  B41M5/165 ,  B41M5/22

CPC分类号： B41L1/36 ,  B41M5/132 ,  Y10S428/914 ,  Y10T428/264 ,  Y10T428/265 ,  Y10T428/277 ,  Y10T428/2984 ,  Y10T428/2987

摘要： A pressure-sensitive carbonless transfer sheet comprising a paper substrate having a front and back surface and a coating compositon adhered to at least one of the front and back surfaces of the paper substrate. The coating composition is set to a flexible, tack-free coat, and the coating composition includes a solvent free non-aqueous hot melt suspending medium which is characterized by being substantially water insoluble, being characterized by the presence of one or more functional groups selected from the group consisting of: carboxyl, carbonyl, hydroxyl, ester, amide, amine, heterocyclic groups and combinations thereof to impart polarity thereto and having a melting point of from about 60.degree. C. to about 140.degree. C. and a melting point range of less than about 15.degree. C. In addition the coating composition includes an encapsulated, chromogenic material which is substantially dispersed therein, the hot melt suspending medium being compatible with the color forming characteristics of the capsular chromogenic material. This invention further includes a liquid chromogenic coating compositon which comprises a hot melt suspending medium in combination with a microencapsulated chromogenic material. The chromogenic material is a color precursor of the electron donating type which is mixed with a carrier oil to form an oil solution of the chromogenic color precursor material which is then combined with one or more wall forming compounds.

摘要翻译： 一种压敏无碳转印片，其包含具有前表面和后表面的纸基材和粘合到纸基材的前表面和后表面中的至少一个上的涂料组合物。 该涂料组合物被设定为柔性，无粘性的涂层，并且该涂料组合物包括无溶剂的非水热熔悬浮介质，其特征在于基本上不溶于水，其特征在于存在一个或多个选自 由羧基，羰基，羟基，酯，酰胺，胺，杂环基及其组合构成的组中，赋予极性，熔点为约60℃至约140℃，熔点范围为 小于约15℃。此外，涂料组合物包括基本上分散在其中的包封的显色材料，热熔悬浮介质与荚膜发色材料的着色特性相容。 本发明还包括液体显色涂料组合物，其包含与微胶囊化显色材料组合的热熔悬浮介质。 显色材料是供电类型的彩色前体，其与载体油混合以形成显色前体材料的油溶液，然后将其与一种或多种形成壁的化合物组合。

公开(公告)号：US4139392A

公开(公告)日：1979-02-13

申请号：US828535

申请日：1977-08-29

申请人： Gerald T. Davis ,  Gerhart Schwab ,  Dale R. Shackle

发明人： Gerald T. Davis ,  Gerhart Schwab ,  Dale R. Shackle

IPC分类号： B41L1/36 ,  B41M5/132 ,  B41M5/155 ,  B41M5/165 ,  C09K3/00

CPC分类号： B41L1/36 ,  B41M5/132 ,  Y10S428/914 ,  Y10T428/264 ,  Y10T428/265 ,  Y10T428/277 ,  Y10T428/2984 ,  Y10T428/2987

摘要： A pressure-sensitive carbonless transfer sheet comprising a paper substrate having a front and back surface and a coating composition adhered to at least one of the front and back surfaces of the paper substrate. The coating composition is set to a flexible, tack-free coat, and the coating composition includes a solvent free non-aqueous hot melt suspending medium which is characterized by being substantially water insoluble, being characterized by the presence of one or more functional groups selected from the group consisting of: carboxyl, carbonyl, hydroxyl, ester, amide, amine, heterocyclic groups and combinations thereof to impart polarity thereto and having a melting point of from about 60.degree. C. to about 140.degree. C. and a melting point range of less than about 15.degree. C. In addition the coating composition includes an encapsulated, chromogenic material which is substantially dispersed therein, the hot melt suspending medium being compatible with the color forming characteristics of the capsular chromogenic material. This invention further includes a liquid chromogenic coating composition which comprises a hot melt suspending medium in combination with a microencapsulated chromogenic material. The chromogenic material is a color precursor of the electron donating type which is mixed with a carrier oil to form an oil solution of the chromogenic color precursor material which is then combined with one or more wall forming compounds.

摘要翻译： 一种压敏无碳转印片，其包含具有前表面和后表面的纸基材和粘附到纸基材的前表面和后表面中的至少一个上的涂料组合物。 该涂料组合物被设定为柔性，无粘性的涂层，并且该涂料组合物包括无溶剂的非水热熔悬浮介质，其特征在于基本上不溶于水，其特征在于存在一个或多个选自 由羧基，羰基，羟基，酯，酰胺，胺，杂环基及其组合构成的组中，赋予极性，熔点为约60℃至约140℃，熔点范围为 小于约15℃。此外，涂料组合物包括基本上分散在其中的包封的显色材料，热熔悬浮介质与荚膜发色材料的着色特性相容。 本发明还包括液体显色涂料组合物，其包含与微囊化显色材料组合的热熔悬浮介质。 显色材料是供电类型的彩色前体，其与载体油混合以形成显色前体材料的油溶液，然后将其与一种或多种形成壁的化合物组合。

公开(公告)号：US4138508A

公开(公告)日：1979-02-06

申请号：US697019

申请日：1976-06-17

申请人： Sydney M. Spatz ,  Robert C. Hydell ,  Gerald T. Davis

发明人： Sydney M. Spatz ,  Robert C. Hydell ,  Gerald T. Davis

IPC分类号： B41M5/132 ,  B05D3/06 ,  B41M5/22

CPC分类号： B41M5/132 ,  Y10S428/914

摘要： A process is provided for producing a pressure-sensitive carbonless transfer sheet comprising preparing a solution of a first chromogenic material, the solution of the first chromogenic material including at least one chromogenic compound dissolved in a carrier oil, and the first chromogenic material being reactive with a second chromogenic material in the presence of the carrier oil to form a color. The solution of the first chromogenic material is mixed with a liquid radiation curable substance to form a coating composition, the liquid radiation curable substance being curable to a frangible resin and compatible with the color-forming capabilities of said first chromogenic material. A film forming material is applied to a substrate, the film forming material being settable to form a barrier layer which substantially prevents penetration of the substrate by the coating composition upon application of the coating composition to the substrate. The film forming material is then set to form the barrier layer on the substrate, and a film of the coating composition is applied over the barrier layer. The coating composition is then cured by subjecting the coating composition to radiation for a period of time sufficient to cure the coating composition containing the radiation curable substance to a frangible resinous film, the frangible resinous film being cured to a frangibility that will permit passage of the solution of the first chromogenic material to the exposed surface of the frangible resinous film when the frangible resinous film is broken.

摘要翻译： 提供了一种生产压敏无碳转印片的方法，包括制备第一显色材料的溶液，第一显色材料的溶液包括溶解在载体油中的至少一种显色化合物，第一显色材料与 在载体油存在下形成第二显色材料以形成颜色。 将第一显色材料的溶液与液体可辐射固化物质混合以形成涂料组合物，该液体辐射固化物质可固化至易碎树脂并与所述第一显色材料的着色能力相适应。 将成膜材料施加到基材上，成膜材料可被固化以形成阻挡层，当将涂料组合物施加到基材上时，基本上防止涂料组合物渗透基材。 然后将成膜材料设置成在基材上形成阻挡层，并将涂料组合物的膜施加在阻挡层上。 然后通过使涂料组合物辐射足以使含有可辐射固化物质的涂料组合物固化至易碎树脂膜的时间来使涂料组合物固化，该易碎树脂膜被固化成易碎物， 当易碎树脂膜破裂时，第一显色材料溶解于易碎树脂膜的暴露表面。

公开(公告)号：US4137343A

公开(公告)日：1979-01-30

申请号：US828534

申请日：1977-08-29

申请人： Gerald T. Davis ,  Gerhart Schwab ,  Dale R. Shackle

发明人： Gerald T. Davis ,  Gerhart Schwab ,  Dale R. Shackle

IPC分类号： B41L1/36 ,  B41M5/132 ,  B41M5/155 ,  B41M5/165 ,  B41M5/22

CPC分类号： B41L1/36 ,  B41M5/132 ,  Y10S428/914 ,  Y10T428/264 ,  Y10T428/265 ,  Y10T428/277 ,  Y10T428/2984 ,  Y10T428/2987

摘要： A pressure-sensitive carbonless transfer sheet comprising a paper substrate having a front and back surface and a coating composition adhered to at least one of the surfaces of the paper substrate. A novel process is provided for producing a pressure-sensitive carbonless transfer sheet which comprises the steps of preparing a hot melt suspending medium, the hot melt suspending medium being water insoluble and having a melting point of from about 60.degree. C. to about 140.degree. C. and a melting point range of less than about 15.degree. C. A microencapsulated chromogenic material is prepared and dispersed in the hot melt suspending medium, the chromogenic material being a color precursor of the electron donating type. A coating dispersion is prepared by combining the hot melt suspending medium with the microencapsulated chromogenic color precursor material, the hot melt suspending medium being compatible with the color forming or developing characteristics of the chromogenic material. The coating dispersion is then applied to a substrate, the coating dispersion being applied at a coat weight of from about 1.0 pound to about 8.0 pounds per 3300 square feet of substrate at a coat thickness of from about 1 micron to about 50 microns. The coated substrate is set by cooling the coating dispersion.

摘要翻译： 一种压敏无碳转印片，其包含具有前表面和后表面的纸基材和粘附到所述纸基材的至少一个表面上的涂料组合物。 提供一种用于生产压敏无碳转印片的新方法，其包括制备热熔悬浮介质的步骤，该热熔悬浮介质是水不溶性的，熔点为约60℃至约140℃ 并且熔点范围小于约15℃。制备微胶囊化的显色材料并将其分散在热熔悬浮介质中，显色材料是供电类型的彩色前体。 通过将热熔悬浮介质与微胶囊化的显色前体材料组合，制备涂层分散体，热熔悬浮介质与显色材料的成色或显色特性相容。 然后将涂料分散体施加到基材上，涂层分散体以约1磅至约8磅/平方英尺的基材以大约1微米至大约50微米的涂层厚度施用。 涂覆的基材通过冷却涂层分散体来设定。

公开(公告)号：US4137084A

公开(公告)日：1979-01-30

申请号：US827124

申请日：1977-08-24

申请人： Gerald T. Davis ,  Dale R. Shackle

发明人： Gerald T. Davis ,  Dale R. Shackle

IPC分类号： B41M5/132 ,  B41L1/36 ,  B41M5/155 ,  B42C3/00 ,  C08F2/48 ,  C09D11/00

CPC分类号： B42C3/00 ,  B41L1/36 ,  B41M5/155

摘要： A process is provided for producing a pressure-sensitive carbonless transfer or record sheet comprising the steps of preparing a liquid chromogenic coating composition by mixing chromogenic material with a liquid radiation curable substance, the chromogenic material comprising either an acidic color developer of the electron donator type or a color precursor of the electron accepting type. The liquid coating composition is coated onto a web or substrate at a coat weight of from about 0.2 pounds to about 8.0 pounds per 3300 square feet of substrate. The coated web is then exposed to radiation for a time sufficient to cure the liquid coating composition to a tack-free film. A novel liquid chromogenic coating composition is produced, the coating composition comprising a chromogenic material and a radiation curable substance. A pressure-sensitive copy sheet is produced, the copy sheet comprising a substrate having a plurality of surfaces at least one of the surfaces being coated with a tack-free film, the film comprising a radiation cured resin containing a chromogenic material dispersed.