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公开(公告)号：US08541542B2
公开(公告)日：2013-09-24
申请号：US12374807
申请日：2007-07-13
CPC分类号： C08F12/08 , C08F6/006 , C08F212/08 , Y10T428/31794 , Y10T428/31804 , C08L25/00 , C08F220/06
摘要： The present invention relates to a process for reducing residuals content in a vinyl aromatic polymer, said residuals comprising essentially unpolymerized vinyl aromatic monomer, wherein the vinyl aromatic polymer in the molten state is brought in contact with a solid in powder capable to catalyze the alkylation of said residual vinyl aromatic monomer on the vinyl aromatic polymer. Advantage of the present invention is a sharp reduction of the unpolymerized vinyl aromatic monomer in the vinyl aromatic polymer without generating a new residual and without inducing a colored vinyl aromatic polymer. The present invention also relates to said vinyl aromatic polymer having a low residuals content.
摘要翻译： 本发明涉及一种减少乙烯基芳族聚合物中残留物含量的方法，所述残余物包含基本上未聚合的乙烯基芳族单体，其中熔融状态的乙烯基芳族聚合物与能够催化烷基化的粉末中的固体接触 所述乙烯基芳族聚合物上的所述残余乙烯基芳族单体。 本发明的优点是在乙烯基芳族聚合物中未聚合的乙烯基芳族单体的急剧减少，而不会产生新的残留物并且不引起着色的乙烯基芳族聚合物。 本发明还涉及具有低残留含量的所述乙烯基芳族聚合物。
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2.发明申请公开(公告)号：US20100179296A1
公开(公告)日：2010-07-15
申请号：US12530860
申请日：2008-03-10
申请人： Walter Vermeiren , Nikolai Nesterenko , Carolina Petitto , Francesco Di Renzo , Francois Fajula
发明人： Walter Vermeiren , Nikolai Nesterenko , Carolina Petitto , Francesco Di Renzo , Francois Fajula
IPC分类号： C08F110/02 , B01J27/18 , B01J27/182 , C07C1/20 , C07C1/32 , C08F110/06
CPC分类号： B01J29/85 , B01J29/005 , B01J29/84 , B01J35/026 , B01J2029/062 , C01B37/06 , C01B37/08 , C01B39/54 , C07C1/20 , C07C1/26 , C07C1/322 , C07C2529/85 , Y02P20/52 , Y02P30/42 , C07C11/04 , C07C11/06
摘要： The present invention relates to metalloaluminophosphate (MeAPO) molecular sieve with lamellar crystal morphology having an empirical chemical composition on an anhydrous basis, after synthesis and calcination, expressed by the formula HxMeyAlzPkO2 wherein, y+z+k=1 x =10 and advantageously ranges from 10 to 100. In a preferred embodiment T is
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公开(公告)号：US4847224A
公开(公告)日：1989-07-11
申请号：US64321
申请日：1987-06-19
IPC分类号： B01J29/70 , B01J29/06 , B01J29/18 , B01J29/50 , B01J29/80 , C01B39/00 , C01B39/04 , C01B39/06 , C01B39/26 , C01B39/30 , C10G11/05
CPC分类号： B01J29/80 , C10G11/05 , B01J2229/62 , B01J29/18 , B01J29/50 , B01J29/7011 , C10G2300/70 , Y10S423/25 , Y10S423/26
摘要： The present invention concerns binary zeolitic systems comprising two zeolites A and B having different crystalline structures while having common structural units. The crystals of the zeolite A form a central core surrounded by a crown of crystals of zeolite B, the zeolites A and B being disposed concentrically and following the same longitudinal axis. These systems are formed by the introduction of a nucleation gel containing seeds of the zeolite A in a growth gel where the crystallization parameters are favorable to the crystallization of the zeolite B. The binary zeolitic systems are useful as catalysts for transforming hydrocarbons and more especially as cracking catalysts.
摘要翻译： 本发明涉及包含具有不同结晶结构的两个沸石A和B的二元沸石体系，同时具有共同的结构单元。 沸石A的晶体形成由沸石B的晶体顶部包围的中心核心，沸石A和B同心地设置并且沿着相同的纵向轴线。 这些体系通过在生长凝胶中引入含有沸石A的种子的成核凝胶形成，其中结晶参数有利于沸石B的结晶。二元沸石体系可用作转化烃的催化剂，更特别地作为 裂解催化剂。
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4.发明授权Process for the synthesis of lauryllactam (L12) by gas phase catalytic rearrangement of cyclododecanone oxime 有权通过环十二酮肟气相催化重排合成十二烷基内酰胺（L12）的方法公开(公告)号：US07893255B2
公开(公告)日：2011-02-22
申请号：US11472024
申请日：2006-06-21
申请人： Eric Lacroix , Serge Hub , Wolfgang Holderich , Wilm Eickelberg , Francois Fajula , Francesco DiRenzo , Markus Brandhorst
发明人： Eric Lacroix , Serge Hub , Wolfgang Holderich , Wilm Eickelberg , Francois Fajula , Francesco DiRenzo , Markus Brandhorst
IPC分类号： C07D225/02 , B01J29/06
CPC分类号： C07D201/04
摘要： The present invention relates to a process for the preparation of lauryllactam in which a Beckmann rearrangement of cyclododecanone oxime is carried out. Said process is carried out in the gas phase at a temperature of between 180 and 450° C. in the presence of a microporous material having a three-dimensional inorganic main structure composed of tetrahedra connected via a common edge, called zeolite.
摘要翻译： 本发明涉及一种制备十二烷基内酰胺的方法，其中进行了环十二烷酮肟的贝克曼重排。 所述方法在气相中，在具有三维无机主体结构的微孔材料的存在下，在180-450℃的温度下进行，所述三维无机主体结构由通过共同边缘连接的四面体称为沸石。
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公开(公告)号：US20070032629A1
公开(公告)日：2007-02-08
申请号：US11498298
申请日：2006-07-27
申请人： Phillipe Banet , Daniel Brunel , Francois Fajula , Dan Lerner , Abbas Razavi
发明人： Phillipe Banet , Daniel Brunel , Francois Fajula , Dan Lerner , Abbas Razavi
IPC分类号： C08G64/00
CPC分类号： C08F10/00 , C08F4/64058 , C08F4/025 , C08F4/7042 , C08F4/7006
摘要： The present invention discloses a method for supporting a transition metal complex and the resulting supported catalyst component which is characterised in that the metallic sites are kept away from one another and kept away from the surface of the support.
摘要翻译： 本发明公开了一种负载过渡金属络合物的方法及所得到的负载型催化剂成分，其特征在于金属部位彼此远离并远离支持体表面。
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6.发明授权
公开(公告)号：US06063944A
公开(公告)日：2000-05-16
申请号：US195
申请日：1998-05-04
IPC分类号： B01J29/89 , C01B39/06 , C01B39/08 , C01B39/12 , C01B39/20 , C01B39/26 , C01B39/46 , C07D301/12
CPC分类号： C01B39/085 , B01J29/89 , C01B39/065 , C01B39/12
摘要： A method is provided for preparing fully lattice-inserted titanium zeolites by post-synthesis processing of the synthetic zeolite optionally containing titanium with an inorganic acid, wherein the post-synthesis processing comprises processing the zeolite in the presence of at least one titanium source with a solution containing at least one oxidizing inorganic acid having a higher redox potential than an acidic tetravalent titanium solution. The invention is also directed to the use of the zeolites.
摘要翻译： PCT No.PCT / FR96 / 01209 Sec。 371日期：1998年5月4日 102（e）日期1998年5月4日PCT提交1996年7月31日PCT公布。 出版物WO97 / 05060 日期1997年2月13日提供了一种用于通过后处理合成沸石制备完全晶格插入的钛沸石的方法，所述合成沸石任选地含有钛与无机酸，其中后合成工艺包括在至少存在下处理沸石 一种钛源与含有至少一种具有比酸性四价钛溶液更高的氧化还原电位的氧化性无机酸的溶液。 本发明还涉及沸石的用途。
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7.发明授权Zeolite from the class of mazzite, process for its synthesis, and its use as a catalyst 失效沸石来自于mazzite类，其合成方法及其用作催化剂
公开(公告)号：US5277791A
公开(公告)日：1994-01-11
申请号：US917162
申请日：1992-07-20
IPC分类号： B01J20/18 , B01J29/06 , B01J29/70 , C01B39/04 , C01B39/06 , C01B39/24 , C01B39/30 , C01B39/34 , C01B39/46 , C01B39/48 , C10G11/05 , C10G25/03 , C10G35/095 , C10G45/64 , C10G49/08 , C01B33/34
CPC分类号： C01B39/34 , B01J29/70 , B01J29/7011 , Y10S423/26
摘要： This invention relates to a new zeolite from the class of mazzite, containing a fraction of non-exchangeable potassium cations, and also to a process for its synthesis. The crystallinity and the adsorption capacity of the protonated form of this zeolite are maintained after a prolonged hydrothermal treatment.
摘要翻译： 本发明涉及一种由一类不可交换的钾阳离子组成的一类新型沸石，也涉及一种其合成方法。 在长时间的水热处理后，保持该沸石的质子化形式的结晶度和吸附能力。
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8.发明授权Process for isomerizing normal paraffins in the presence of at least one catalyst based on a particular omega zeolite 失效基于特殊的OMEGA ZEOLITE在至少一种催化剂存在下异构化的方法
公开(公告)号：US5157198A
公开(公告)日：1992-10-20
申请号：US785192
申请日：1991-11-01
申请人： Francis Raatz , Christine Travers , Christian Marcilly , Thierry Descourieres , Francois Fajula , Francois Figueras
发明人： Francis Raatz , Christine Travers , Christian Marcilly , Thierry Descourieres , Francois Fajula , Francois Figueras
CPC分类号： B01J29/7223 , C07C5/2791 , B01J2229/22 , B01J2229/36 , B01J2229/37 , B01J2229/42
摘要： The invention relates to a process for isomerizing normal paraffins, particularly C.sub.5 -C.sub.6, in the presence of at least one catalyst based on an omega zeolite having a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 ranging from 6.5 to 80, a content by weight of sodium lower than 0.2%, crystalline parameters "a" and "c" respectively smaller than or equal to 1.814 nm and 0.760 nm, a capacity of adsorption of nitrogen, measured at 77K under a partial pressure of 0.19, higher than about 8% by weight, the catalyst also comprising at least one metal from group VIII of the periodic table of elements, preferably platinum or/and palladium.
摘要翻译： 本发明涉及一种在至少一种催化剂存在下使正构烷烃特别是C5-C6异构化的方法，该催化剂基于SiO 2 / Al 2 O 3的摩尔比为6.5至80的ω-沸石，钠的重量比低于 0.2％，分别小于或等于1.814nm和0.760nm的结晶参数“a”和“c”，在77K下在0.19Kg，高于约8％重量下测量的氮吸附容量， 催化剂还包含元素周期表第Ⅷ族中的至少一种金属，优选铂或/和钯。
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公开(公告)号：US20100216629A1
公开(公告)日：2010-08-26
申请号：US12530868
申请日：2008-03-10
申请人： Walter Vermeiren , Nikolai Nesterenko , Carolina Petitto , Francesco Di Renzo , Francois Fajula
发明人： Walter Vermeiren , Nikolai Nesterenko , Carolina Petitto , Francesco Di Renzo , Francois Fajula
CPC分类号： B01J29/84 , B01J29/85 , C01B37/06 , C01B37/08 , C07C1/20 , C07C1/26 , C07C1/322 , C07C2529/84 , C07C2529/85 , Y02P30/42 , C07C11/02
摘要： The present invention also relates to a method for preparing metalloaluminophosphate (MeAPO) molecular sieve said method comprising: a) forming a reaction mixture containing a texture influencing agent (TIA), an organic templating agent (TEMP), at least a reactive inorganic source of MeO2 insoluble in the TIA, reactive sources of Al2O3 and P2O5, b) crystallizing the above reaction mixture thus formed until crystals of the metalloaluminophosphate are formed, c) recovering a solid reaction product, d) washing it with water to remove the TIA and e) calcinating it to remove the organic template. In a usual embodiment said reaction mixture has a composition expressed in terms of molar oxide ratios of: TEMP/Al2O3=0.3-5, more desirable 0.5-2 MeO2/Al2O3=0.005-2.0, more desirable 0.022-0.8 P2O5/Al2O3=0.5-2, more desirable 0.8-1.2 TIA/Al2O3=3-30, more desirable 6-20 In a usual embodiment the metalloaluminophosphate (MeAPO) molecular sieves made with the above method have a lamellar crystal morphology having an empirical chemical composition on an anhydrous basis, after synthesis and calcination, expressed by the formula HxMeyAlzPkO2 wherein, y+z+k=1, x
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公开(公告)号：US20100113707A1
公开(公告)日：2010-05-06
申请号：US12374807
申请日：2007-07-13
IPC分类号： C08F8/02
CPC分类号： C08F12/08 , C08F6/006 , C08F212/08 , Y10T428/31794 , Y10T428/31804 , C08L25/00 , C08F220/06
摘要： The present invention relates to a process for reducing residuals content in a vinyl aromatic polymer, said residuals comprising essentially unpolymerized vinyl aromatic monomer, wherein the vinyl aromatic polymer in the molten state is brought in contact with a solid in powder capable to catalyze the alkylation of said residual vinyl aromatic monomer on the vinyl aromatic polymer.Advantage of the present invention is a sharp reduction of the unpolymerized vinyl aromatic monomer in the vinyl aromatic polymer without generating a new residual and without inducing a colored vinyl aromatic polymer.The present invention also relates to said vinyl aromatic polymer having a low residuals content.
摘要翻译： 本发明涉及一种减少乙烯基芳族聚合物中残留物含量的方法，所述残余物包含基本上未聚合的乙烯基芳族单体，其中熔融状态的乙烯基芳族聚合物与能够催化烷基化的粉末中的固体接触 所述乙烯基芳族聚合物上的所述残余乙烯基芳族单体。 本发明的优点是在乙烯基芳族聚合物中未聚合的乙烯基芳族单体的急剧减少，而不会产生新的残留物并且不引起着色的乙烯基芳族聚合物。 本发明还涉及具有低残留含量的所述乙烯基芳族聚合物。
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