公开(公告)号：US08816041B2

公开(公告)日：2014-08-26

申请号：US13121350

申请日：2009-08-18

Applicant: Yoichiro Tanaka ,  Eri Hatano ,  Keisuke Honda

Inventor： Yoichiro Tanaka ,  Eri Hatano ,  Keisuke Honda

IPC: C08G63/00 ,  B01J23/00

CPC classification number: D01F6/62 ,  C08G63/183 ,  C08G63/85

Abstract: Provided are a polyester polymerization catalyst with which the generation of foreign materials caused by the catalyst or mold pollution at the time of molding are reduced and polyesters having remarkably superior thermal stability and color tone can be obtained.Provided is a polyester polymerization catalyst produced by the reaction of a titanium compound and a mannitol in a molar ratio of titanium atom to mannitol of from 1:1 to 1:3. A method for producing a polyester employs the polyester polymerization catalyst.

Abstract translation: 提供一种聚酯聚合催化剂，其在模塑时由催化剂或模具污染引起的异物的产生减少，并且可以获得具有非常优异的热稳定性和色调的聚酯。 提供了通过钛化合物和甘露醇与钛原子与甘露醇的摩尔比为1:1至1:3的反应制备的聚酯聚合催化剂。 聚酯的制造方法采用聚酯聚合催化剂。

公开(公告)号：US09732190B2

公开(公告)日：2017-08-15

申请号：US14237300

申请日：2012-08-13

Applicant: Koya Kato ,  Atsushi Masunaga ,  Eri Hatano ,  Hideo Matsuoka

Inventor： Koya Kato ,  Atsushi Masunaga ,  Eri Hatano ,  Hideo Matsuoka

IPC: C08L77/00 ,  C08G69/28 ,  C08G69/26 ,  C08L77/06 ,  C08G69/36 ,  C08K7/06 ,  C08K7/14 ,  C08K5/00

CPC classification number: C08G69/28 ,  C08G69/265 ,  C08G69/36 ,  C08K5/005 ,  C08K7/06 ,  C08K7/14 ,  C08L77/06

Abstract: There is provided a production method of a crystalline polyamide resin by thermal polycondensation of a mixture including at least a diamine component, a dicarboxylic acid component and water as a starting material, wherein the diamine component includes (A) pentamethylene diamine at a ratio that is equal to or greater than 10 mol % and less than 80 mol % relative to a gross amount of the diamine component; and the dicarboxylic acid component includes (B) at least one selected from the group consisting of an aromatic dicarboxylic acid, an alicyclic dicarboxylic acid and dialkyl ester derivatives thereof at a ratio that is equal to or greater than 76 mol % and equal to or less than 100 mol % relative to a gross amount of the dicarboxylic acid component.

公开(公告)号：US20110178265A1

公开(公告)日：2011-07-21

申请号：US13121350

申请日：2009-08-18

Applicant: Yoichiro Tanaka ,  Eri Hatano ,  Keisuke Honda

Inventor： Yoichiro Tanaka ,  Eri Hatano ,  Keisuke Honda

IPC: C08G63/85 ,  C07F7/28

CPC classification number: D01F6/62 ,  C08G63/183 ,  C08G63/85

Abstract: Provided are a polyester polymerization catalyst with which the generation of foreign materials caused by the catalyst or mold pollution at the time of molding are reduced and polyesters having remarkably superior thermal stability and color tone can be obtained.Provided is a polyester polymerization catalyst produced by the reaction of a titanium compound and a mannitol in a molar ratio of titanium atom to mannitol of from 1:1 to 1:3. A method for producing a polyester employs the polyester polymerization catalyst.

Abstract translation: 提供一种聚酯聚合催化剂，其在模塑时由催化剂或模具污染引起的异物的产生减少，并且可以获得具有非常优异的热稳定性和色调的聚酯。 提供了通过钛化合物和甘露醇与钛原子与甘露醇的摩尔比为1:1至1:3的反应制备的聚酯聚合催化剂。 聚酯的制造方法采用聚酯聚合催化剂。

公开(公告)号：US20140194570A1

公开(公告)日：2014-07-10

申请号：US14237300

申请日：2012-08-13

Applicant: Koya Kato ,  Atsushi Masunaga ,  Eri Hatano ,  Hideo Matsuoka

Inventor： Koya Kato ,  Atsushi Masunaga ,  Eri Hatano ,  Hideo Matsuoka

IPC: C08G69/28 ,  C08G69/26 ,  C08L77/06 ,  C08G69/36

CPC classification number: C08G69/28 ,  C08G69/265 ,  C08G69/36 ,  C08K5/005 ,  C08K7/06 ,  C08K7/14 ,  C08L77/06

Abstract: There is provided a production method of a crystalline polyamide resin by thermal polycondensation of a mixture including at least a diamine component, a dicarboxylic acid component and water as a starting material, wherein the diamine component includes (A) pentamethylene diamine at a ratio that is equal to or greater than 10 mol % and less than 80 mol % relative to a gross amount of the diamine component; and the dicarboxylic acid component includes (B) at least one selected from the group consisting of an aromatic dicarboxylic acid, an alicyclic dicarboxylic acid and dialkyl ester derivatives thereof at a ratio that is equal to or greater than 76 mol % and equal to or less than 100 mol % relative to a gross amount of the dicarboxylic acid component, the production method comprising: a first step that heats the above mixture, which has a water content equal to or less than 30% by weight, at a temperature equal to or higher than 200° C. under a pressure of 1.8 to 3.5 MPa to perform polycondensation with distillation of water; a second step that releases pressure to an atmospheric pressure level, subsequent to the first step; and a third step that continues thermal polycondensation subsequent to the second step, so as to obtain the crystalline polyamide resin, the third step performing high-degree melt polymerization at a temperature that is equal to or higher than a melting point of the crystalline polyamide resin until a relative viscosity at 25° C. of a solution prepared by dissolving the obtained crystalline polyamide resin at a concentration of 0.01 mg/mL in 98% sulfuric acid reaches between 1.8 and 3.5.

Abstract translation: 提供了一种结晶性聚酰胺树脂的制造方法，其特征在于，以至少二胺成分，二羧酸成分和水为原料的混合物进行热缩聚，其中二胺成分包含（A）五亚甲基二胺， 相对于二胺成分的总量为10摩尔％以上且小于80摩尔％ 并且所述二羧酸成分包含（B）选自芳香族二羧酸，脂环族二羧酸及其二烷基酯衍生物中的至少一种，其比例为76摩尔％以上且等于或小于 相对于二羧酸成分的总量为100摩尔％以下的制造方法，其特征在于，包括：第一工序，在等于或等于或等于30℃的温度下加热含水率等于或小于30重量％的上述混合物， 在1.8〜3.5MPa的压力下高于200℃，进行与水蒸馏的缩聚; 在第一步骤之后将压力释放到大气压力水平的第二步骤; 以及在第二步骤之后继续进行热缩聚以获得结晶性聚酰胺树脂的第三步骤，在等于或高于结晶聚酰胺树脂的熔点的温度下进行高度熔融聚合的第三步骤 直到通过将所得结晶聚酰胺树脂以0.01mg / mL的浓度溶解在98％硫酸中而制备的溶液在25℃下的相对粘度达到1.8至3.5之间。