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公开(公告)号：US06420300B1
公开(公告)日：2002-07-16
申请号：US09616198
申请日：2000-07-14
申请人： John McMeeking , Xiaoliang Gao , Rupert Edward von Haken Spence , Stephen John Brown , Dusan Jeremic
发明人： John McMeeking , Xiaoliang Gao , Rupert Edward von Haken Spence , Stephen John Brown , Dusan Jeremic
IPC分类号： B01J3118
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F210/16 , C08F2420/05 , Y10S526/901 , Y10S526/943 , C08F4/6592 , C08F2500/12 , C08F2500/03 , C08F210/14
摘要： A catalyst system comprises an organometallic complex of a group 4 metal having a ketimide ligand. The organometallic complex preferably also contains a cyclic ligand which forms a delocalized pi-bond with the metal (such as a cyclopentadienyltype ligand). Preferred organometallic complexes may be activated with a so-called “substantially non coordinating anion” to form a low cost cocatalyst system which is excellent for the preparation of olefin copolymers having both high molecular weight and very low density.
摘要翻译： 催化剂体系包括具有酮亚胺配体的第4族金属的有机金属络合物。 有机金属络合物优选还含有与金属形成离域π键的环状配体（如环戊二烯基型配体）。 优选的有机金属络合物可以用所谓的“基本上非配位阴离子”活化以形成低成本助催化剂体系，其对于制备具有高分子量和非常低密度的烯烃共聚物是优异的。
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公开(公告)号：US08829137B2
公开(公告)日：2014-09-09
申请号：US13405487
申请日：2012-02-27
申请人： Patrick Lam , Victoria Ker , Charles Ashton Garret Carter , Benjamin Milton Shaw , Cliff Robert Baar , Alexei Kazakov , Ian Douglas McKay , Dusan Jeremic
发明人： Patrick Lam , Victoria Ker , Charles Ashton Garret Carter , Benjamin Milton Shaw , Cliff Robert Baar , Alexei Kazakov , Ian Douglas McKay , Dusan Jeremic
IPC分类号： C08F210/16 , C08F210/14
CPC分类号： C08J5/18 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F210/16 , C08F2420/04 , C08J2323/08 , C08F210/14 , C08F2500/03 , C08F2500/11 , C08F2500/12 , C08F2500/18 , C08F2500/26 , C08F4/6592
摘要： Polyethylene films having a good balance of optical and mechanical properties are disclosed. The films are derived from ethylene copolymer compositions made with a suitably substituted phosphinimine catalyst. The ethylene copolymers have very narrow molecular weight distributions and broadened comonomer distributions.
摘要翻译： 公开了具有光学和机械性能的良好平衡的聚乙烯膜。 该膜由适当取代的次膦酸催化剂制备的乙烯共聚物组合物得到。 乙烯共聚物具有非常窄的分子量分布和扩大的共聚单体分布。
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公开(公告)号：US07863213B2
公开(公告)日：2011-01-04
申请号：US11800773
申请日：2007-05-07
IPC分类号： C08F4/6592 , B01J31/22 , B01J31/14
CPC分类号： C08F10/02 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F110/02 , C08F210/16 , C08F2410/02 , Y10S526/943 , C08F4/65908 , C08F210/14 , C08F2500/03
摘要： A supported catalyst for olefin polymerization comprises a selected ionic activator, a selected organometallic catalyst and a support material. The selected activator must contain an active hydrogen moeity. The organometallic catalyst is characterized by having a phosphinimine ligand and a substituted cyclopentadienyl ligand (which contains from 7 to 30 carbon atoms). The supported catalyst exhibits excellent activity in gas phase olefin polymerizations and may be used under substantially “non-fouling” polymerization conditions.
摘要翻译： 用于烯烃聚合的负载催化剂包括选择的离子活化剂，选择的有机金属催化剂和载体材料。 选择的活化剂必须含有活性氢气。 有机金属催化剂的特征在于具有膦亚胺配体和取代的环戊二烯基配体（其含有7至30个碳原子）。 载体催化剂在气相烯烃聚合中表现出优异的活性，并且可以在基本上“非污染”的聚合条件下使用。
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公开(公告)号：US07476715B2
公开(公告)日：2009-01-13
申请号：US11800590
申请日：2007-05-07
IPC分类号： C08F2/34
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F10/02 , C08F210/16 , C08F2410/02 , Y10S526/901 , Y10S526/943 , C08F4/025 , C08F2/002 , C08F4/65912 , C08F210/14
摘要： The use of high activity “Single Site” polymerization catalysts often causes the fouling of polymerization reactors. The problem is particularly acute with gas phase polymerizations. While not wishing to be bound by theory it is believed that the fouling is initiated by the buildup of static charges in the reactor. The use of anti-static agents mitigates this problem, but typical antistatic agents contain polar species, which can deactivate the polymerization catalyst. We have now discovered that the use of a porous metal oxide support allows large levels of a selected antistatic agent to be used in a manner that reduces static/fouling problems in highly active polymerization catalysts.
摘要翻译： 使用高活性“单点”聚合催化剂通常会导致聚合反应器的结垢。 气相聚合问题尤其严重。 虽然不希望被理论束缚，但据信污垢是由反应器中静电荷的累积引起的。 使用抗静电剂减轻了这个问题，但是典型的抗静电剂含有极性物质，这可以使聚合催化剂失活。 我们现在已经发现，使用多孔金属氧化物载体允许以降低高活性聚合催化剂中静电/结垢问题的方式使用大量选定的抗静电剂。
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公开(公告)号：US6140264A
公开(公告)日：2000-10-31
申请号：US76139
申请日：1998-05-12
申请人： Mark Kelly , Dusan Jeremic , Victoria Ker , Charles Russell
发明人： Mark Kelly , Dusan Jeremic , Victoria Ker , Charles Russell
IPC分类号： C08F10/00 , C08F210/16 , B01J21/00 , B01J21/06 , B01J21/08
CPC分类号： C08F10/00 , C08F210/16
摘要： The present invention provides a novel process for preparing a catalyst, preferably free of electron donor, useful in gas phase polymerization of olefins having a broad polydispersity.
摘要翻译： 本发明提供了一种制备催化剂的新方法，该催化剂优选不含电子给体，可用于具有广泛多分散性的烯烃的气相聚合。
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公开(公告)号：US08536081B2
公开(公告)日：2013-09-17
申请号：US11667466
申请日：2005-11-10
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F2420/02 , C08F2420/04 , Y02P20/52 , C08F4/6592 , C08F210/14 , C08F2500/12 , C08F2500/09
摘要： Supported catalyst system for the polymerization of olefins, having at least two different monocyclopentadienyl transition metal compounds, one or more activators including an ionic compound having (i) a cation and (ii) an anion having up to 100 non-hydrogen atoms and the anion containing at least one substituent comprising a moiety having an active hydrogen, and one or more support materials. The supported “mixed or dual site” catalyst systems having different monocyclopentadienyl catalysts when activated by specific ionic activators lead to catalyst systems showing an improved balance of properties which may be used to prepare LLDPE polymers having broad melt flow ratios.
摘要翻译： 用于烯烃聚合的负载催化剂体系，其具有至少两种不同的单环戊二烯基过渡金属化合物，一种或多种活化剂，其包括具有（i）阳离子和（ii）具有至多100个非氢原子的阴离子的离子化合物和阴离子 含有至少一个包含具有活性氢的部分的取代基和一种或多种载体材料。 当由特定的离子活化剂活化时，具有不同单环戊二烯基催化剂的“混合或双位点”催化剂体系导致催化剂体系显示改进的性能平衡，其可用于制备具有宽熔体流动比的LLDPE聚合物。
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公开(公告)号：US20070282085A1
公开(公告)日：2007-12-06
申请号：US11800590
申请日：2007-05-07
IPC分类号： C08F4/44
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65916 , C08F4/6592 , C08F10/02 , C08F210/16 , C08F2410/02 , Y10S526/901 , Y10S526/943 , C08F4/025 , C08F2/002 , C08F4/65912 , C08F210/14
摘要： The use of high activity “Single Site” polymerization catalysts often causes the fouling of polymerization reactors. The problem is particularly acute with gas phase polymerizations. While not wishing to be bound by theory it is believed that the fouling is initiated by the buildup of static charges in the reactor. The use of anti-static agents mitigates this problem, but typical antistatic agents contain polar species, which can deactivate the polymerization catalyst. We have now discovered that the use of a porous metal oxide support allows large levels of a selected antistatic agent to be used in a manner that reduces static/fouling problems in highly active polymerization catalysts.
摘要翻译： 使用高活性“单点”聚合催化剂通常会导致聚合反应器的结垢。 气相聚合问题尤其严重。 虽然不希望被理论束缚，但据信污垢是由反应器中静电荷的累积引起的。 使用抗静电剂减轻了这个问题，但是典型的抗静电剂含有极性物质，这可以使聚合催化剂失活。 我们现在已经发现，使用多孔金属氧化物载体允许以降低高活性聚合催化剂中静电/结垢问题的方式使用大量选定的抗静电剂。
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8.发明授权公开(公告)号：US06235853B1
公开(公告)日：2001-05-22
申请号：US09440613
申请日：1999-11-15
申请人： Ian McKay , Dusan Jeremic , Qinyan Wang , P. Scott Chisholm
发明人： Ian McKay , Dusan Jeremic , Qinyan Wang , P. Scott Chisholm
IPC分类号： C08F208
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F110/06 , C08F210/02 , C08F210/16 , Y10S526/943 , C08F4/6592 , C08F2500/03 , C08F236/20 , C08F212/08 , C08F236/06 , C08F210/06
摘要： A slurry polymerization process uses an unsupported catalyst component which is an organometallic complex having a phosphinimine ligand and a cyclopentadienyl-type ligand. The use of the unsupported catalyst component allows simple, inexpensive catalyst addition techniques to be used in a slurry polymerization process. The catalyst component is highly active for ethylene (co)polymerization in the process of this invention.
摘要翻译： 淤浆聚合方法使用无载体催化剂组分，其是具有膦亚胺配体和环戊二烯基型配体的有机金属络合物。 使用未负载的催化剂组分允许在淤浆聚合方法中使用简单，便宜的催化剂添加技术。 催化剂组分在本发明方法中对乙烯（共）聚合具有高活性。
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公开(公告)号：US20120238720A1
公开(公告)日：2012-09-20
申请号：US13405487
申请日：2012-02-27
申请人： Patrick Lam , Victoria Ker , Charles Ashton Garret Carter , Benjamin Milton Shaw , Cliff Robert Baar , Alexei Kazakov , Ian Douglas McKay , Dusan Jeremic
发明人： Patrick Lam , Victoria Ker , Charles Ashton Garret Carter , Benjamin Milton Shaw , Cliff Robert Baar , Alexei Kazakov , Ian Douglas McKay , Dusan Jeremic
IPC分类号： C08F210/16
CPC分类号： C08J5/18 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F210/16 , C08F2420/04 , C08J2323/08 , C08F210/14 , C08F2500/03 , C08F2500/11 , C08F2500/12 , C08F2500/18 , C08F2500/26 , C08F4/6592
摘要： Polyethylene films having a good balance of optical and mechanical properties are disclosed. The films are derived from ethylene copolymer compositions made with a suitably substituted phosphinimine catalyst. The ethylene copolymers have very narrow molecular weight distributions and broadened comonomer distributions.
摘要翻译： 公开了具有光学和机械性能的良好平衡的聚乙烯膜。 该膜由适当取代的次膦酸催化剂制备的乙烯共聚物组合物得到。 乙烯共聚物具有非常窄的分子量分布和扩大的共聚单体分布。
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公开(公告)号：US20080139763A1
公开(公告)日：2008-06-12
申请号：US11667466
申请日：2005-11-10
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F210/16 , C08F2420/02 , C08F2420/04 , Y02P20/52 , C08F4/6592 , C08F210/14 , C08F2500/12 , C08F2500/09
摘要： Supported catalyst systems for the polymerisation of olefins, comprise (a) at least two different monocyclopentadienyl transition metal compounds, (b) one or more activators comprising an ionic compound comprising (i) a cation and (ii) an anion having up to 100 non-hydrogen atoms and the anion containing at least one substituent comprising a moiety having an active hydrogen, and (c) one or more support materials. The, supported “mixed or dual site” catalyst systems comprising different monocyclopentadienyl catalysts when activated by specific ionic activators lead to catalyst systems showing an improved balance of properties which may be used to prepare LLDPE polymers having broad melt flow ratios.
摘要翻译： 用于烯烃聚合的负载催化剂体系包括（a）至少两种不同的单环戊二烯基过渡金属化合物，（b）一种或多种包含离子化合物的活化剂，其包含（i）阳离子和（ii） 氢原子和含有至少一个取代基的阴离子，所述取代基包含具有活性氢的部分，和（c）一种或多种载体材料。 当通过特定的离子活化剂活化时，包含不同单环戊二烯基催化剂的“混合或双位点”催化剂体系导致催化剂体系显示改进的性能平衡，其可用于制备具有宽熔体流动比的LLDPE聚合物。
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