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公开(公告)号：US4672052A
公开(公告)日：1987-06-09
申请号：US768508
申请日：1985-08-22
申请人： Dietrich Wagener , Karl H. Laue , Egmar Wunderlich , Theo Sander , Claus Flockenhaus , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein
发明人： Dietrich Wagener , Karl H. Laue , Egmar Wunderlich , Theo Sander , Claus Flockenhaus , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein
CPC分类号： B01D53/8631 , B01J35/04 , F01N2330/06
摘要： A catalyst for use in a process for the removal of nitrogen oxides from exhaust gases contaminated with dust in which the process uses ammonia. The catalyst is made of a material which is easily disposable. Furthermore, the catalyst should be completely used up in the catalysis. The catalyst comprises individual ceramic bricks with a porous surface, and passages therethrough for the flow of the exhaust gases. The bricks exhibit a resistance to abrasion which is designed so that the dust of the exhaust gas which flows through the passages erodes the catalyst surface, thereby reactivating the catalyst. The exhaust gas carries the dust and the eroded material along with it.
摘要翻译： 一种催化剂，用于从其中使用氨的灰尘污染的废气中除去氮氧化物的方法。 催化剂由易于一次性的材料制成。 此外，催化剂应在催化中完全消耗。 该催化剂包括具有多孔表面的单个陶瓷砖，以及用于排气流动的通道。 砖表现出耐磨性，其设计为使得流过通道的排气的灰尘侵蚀催化剂表面，从而使催化剂再次活化。 废气携带灰尘和侵蚀的材料。
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2.发明授权Process and apparatus for drying and preheating coking coal by means of flue gas 失效通过烟气干燥和预热焦煤的方法和设备
公开(公告)号：US4308102A
公开(公告)日：1981-12-29
申请号：US123474
申请日：1980-02-21
摘要： Flue gas discharged from a recuperator or regenerator of a coke oven battery has the steam thereof removed by means of a direct or indirect cooling and condensation operation. After the steam is removed from the flue gas it is then passed through a coke dry cooling plant in direct contact with hot coke therein to form dry cooled coke while simultaneously increasing the temperature of the flue gas. The flue gas is then passed through a coal preheating plant to directly contact and dry and preheat moist coking coal contained therein. The entire system is open, such that a given quantity of the flue gas passes only once through the system. When the temperature of the flue gas as received from a coke oven battery is extremely high, then the flue gas may be subjected to a partial cooling operation prior to the cooling and condensation operation. Further, a portion of the heat of the flue gas, after the discharge thereof from the coke dry cooling plant and prior to the introduction thereof into the coal preheating plant, may be used to generate steam and/or electricity.
摘要翻译： 从焦炉电池的再生器或再生器排出的烟道气通过直接或间接冷却和冷凝操作除去蒸汽。 蒸汽从废气中除去后，然后通过焦炭干燥冷却设备直接与其中的热焦炭接触，形成干燥的冷却焦炭，同时提高烟气的温度。 然后将烟道气通过煤炭预热装置直接接触并干燥并预热其中所含的湿焦碳。 整个系统是开放的，使得给定量的烟道气仅通过一次通过系统。 当从焦炉电池接收到的烟道气的温度非常高时，在冷却和冷凝操作之前，烟道气可以进行部分冷却操作。 此外，废气的一部分在从焦炭干燥冷却装置排出之后并且在其被引入到煤炭预热装置中之前，可用于产生蒸汽和/或电力。
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公开(公告)号：US4289585A
公开(公告)日：1981-09-15
申请号：US112439
申请日：1980-01-16
CPC分类号： C10B39/08
摘要： A method and apparatus for the wet quenching of coke is disclosed wherein hot coke is sprayed from above with quenching water, the steam generated by the heat of the coke is condensed by a spray of condensation water from the top of the quenching tower, and the hot condensate-water mixture is collected at the bottom of the quenching tower and recirculating to the top of the tower where it is sprayed between quenching operations to be cooled by a counterflowing stream of air. The cooled condensate-water mixture is suitable for reuse as the condensation spray water.
摘要翻译： 公开了一种用于冷焦的焦炭的方法和装置，其中用焦炭从上方喷射热焦炭，焦炭热量产生的蒸汽通过来自淬火塔顶部的冷凝水喷雾而冷凝， 在冷凝塔的底部收集热的冷凝水混合物，并且再循环到塔的顶部，在其顶部喷洒淬火操作之间，以便由逆流的空气流冷却。 冷凝水冷却水混合物适合作为冷凝喷水的再利用。
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4.发明授权
公开(公告)号：US4284476A
公开(公告)日：1981-08-18
申请号：US123475
申请日：1980-02-21
摘要： A heat carrier gas is passed through a coke dry cooling plant in direct contact with hot coke therein to form dry cooled coke while simultaneously increasing the temperature of the heat carrier gas. The heat carrier gas is then passed through a coal preheating plant to directly contact and dry and preheat moist coking coal contained therein. The entire system is open, such that a given quantity of the heat carrier gas passes only once through the dry cooling plant and the coal drying and preheating plant. The heat carrier gas may be a flue gas which is passed directly to the coke dry cooling plant without any preliminary pretreatment, and preferably is a flue gas which is supplied directly from a regenerator or recuperator of a coke oven battery. Alternatively, the heat carrier gas may be in the form of a fuel gas which is inert with respect to the hot coke, for example a waste gas or stack gas supplied from an adjacent metallurgical installation, such as a steel mill.
摘要翻译： 热载体气体通过与其中的热焦直接接触的焦炭干燥冷却设备，以形成干燥的冷却焦炭同时增加热载体气体的温度。 然后将载热气体通过煤炭预热装置直接接触并干燥并预热其中所含的湿焦碳。 整个系统是开放的，使得给定量的载热气体只通过一次通过干燥冷却设备和煤干燥和预热设备。 载热气体可以是烟道气，其直接通过焦炭干燥冷却设备而没有预先预处理，优选是直接从焦炉电池的再生器或再生器供应的烟道气。 或者，热载体气体可以是相对于热焦炭惰性的燃料气体，例如从邻近的冶金设备（例如钢铁厂）供应的废气或者堆放气体。
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公开(公告)号：US4235604A
公开(公告)日：1980-11-25
申请号：US865725
申请日：1977-12-29
CPC分类号： C01B3/38 , Y02P20/129
摘要： Coke oven gas is subjected, immediately after the discharge thereof from coke ovens, and without any preliminary cooling operation or any purification operation other than desulfurization, to a catalytic cracking operation to form a hot cracked gas which is rich in hydrogen and carbon monoxide. The catalytic cracking reaction is carried out in the presence of a hydrogen-containing and/or CO.sub.2 -containing gas, with a steam reforming catalyst.
摘要翻译： 焦化炉气体在从焦炉排出之后立即进行，并且没有任何预冷却操作或除脱硫之外的任何净化操作，进行催化裂化操作以形成富氢和一氧化碳的热裂解气体。 催化裂化反应在含氢和/或含CO 2的气体存在下与蒸汽重整催化剂进行。
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公开(公告)号：US4133719A
公开(公告)日：1979-01-09
申请号：US751707
申请日：1976-12-17
申请人： Dietrich Wagener
发明人： Dietrich Wagener
CPC分类号： C10B11/00
摘要： An inclined chamber of a coke oven is defined by a heating side wall, a coke removal side, a horizontal chamber ceiling and a chamber floor inclined downwardly from the heating side wall to the coke removal side. Briquettes are charged into the chamber, through charging holes in the heating side wall arranged vertically one above the other and through charging holes in the chamber ceiling arranged one behind the other, in separate inclined fill layers. The charging operation is through separate charging holes, in a sequence from the lowermost charging hole in the heating side wall to the uppermost charging hole therein, and then from the chamber ceiling charging hole closest to the heating side wall to the chamber ceiling charging hole furthest therefrom. The vertical and horizontal spacing between adjacent charging holes is dimensioned to avoid breakage of the briquettes.
摘要翻译： 焦炉的倾斜室由加热侧壁，焦炭去除侧，水平室顶板和从加热侧壁向焦炭去除侧向下倾斜的室底板限定。 通过将加热侧壁中的一个上下放置的加热侧壁的充电孔和通过分开倾斜的填充层中的一个彼此靠后设置的室顶部的充电孔而将煤饼装入室中。 充电操作是从加热侧壁中的最下面的充电孔到其中最上面的充电孔，然后从最靠近加热侧壁的室顶部充电孔到室顶充电孔最远的顺序从单独的充电孔 由此。 相邻充电孔之间的垂直和水平间距的大小可以避免压块的破裂。
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公开(公告)号：US4734165A
公开(公告)日：1988-03-29
申请号：US860218
申请日：1986-05-06
摘要： Coke is produced from coal by coking the coal, and optionally by drying and/or preheating the coal prior to coking, and further optionally by dry cooling the coke subsequent to coking. At least the coking step is achieved in a pressure tight container which may be a transportable or tippable container. The coking step is performed in the container by conducting a gas through the container in direct or indirect heat exchange relationship with the coal and forming coke. The coking step includes a phase of lump coke formation achieved by heating the coal in a temperature range of between approximately 250.degree. and 600.degree. C. by indirect heat exchange only.
摘要翻译： 焦炭通过焦化煤而产生，并且任选地在焦化之前干燥和/或预热煤，并且进一步任选地通过在焦化之后干燥冷却焦炭。 至少焦化步骤在压力容器中实现，压力容器可以是可运输的或可翻转的容器。 通过与煤和成形焦直接或间接的热交换关系通过容器进行气体在容器中进行焦化步骤。 焦化步骤包括通过仅通过间接热交换在约250℃至600℃的温度范围内加热煤获得的块状焦炭形成阶段。
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8.发明授权
公开(公告)号：US4721699A
公开(公告)日：1988-01-26
申请号：US900824
申请日：1986-08-27
申请人： Dietrich Wagener , Karl H. Laue , Egmar Wunderlich , Theo Sander , Claus Flockenhaus , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein
发明人： Dietrich Wagener , Karl H. Laue , Egmar Wunderlich , Theo Sander , Claus Flockenhaus , Erich Hackler , Blagoje Levkov , Daniel Grimm , Hartmut Kainer , Hermann Stein
CPC分类号： B01D53/8631 , B01J35/04 , F01N2330/06
摘要： A structure made from catalyst for use in the separation of nitrogen oxides from combustion exhaust gases which contain dust. The catalytic structure has plates with spaces therebetween to carry a flow of the exhaust gas therethrough. The catalyst is constructed of individual ceramic plates. The abrasion or wear resistance of the plates is chosen such that the dust in the exhaust gases flowing through the spaces abrades the plate surface at a rate which is at least equivalent to the deactivation of the catalyst surface by action of the nitrogen oxides, which constantly provides a fresh catalyst surface for reaction with the nitrogen oxides. The movement of the exhaust gas through the catalytic structure carries the dust and abraded material along with it and out of the structure.
摘要翻译： 由用于从含有灰尘的燃烧废气中分离氮氧化物的催化剂制成的结构。 催化结构具有在其间具有间隔的板，以使废气流过其中。 催化剂由单独的陶瓷板构成。 选择板的磨损或耐磨性，使得流过空间的废气中的灰尘以至少等于通过氮氧化物的作用使催化剂表面的失活至少相当的速率磨损板表面，氮气氧化物的作用不断 提供了与氮氧化物反应的新鲜催化剂表面。 废气通过催化结构的运动将灰尘和磨损材料与其一起携带并离开结构。
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9.发明授权Apparatus for the production of ammonia synthesis gas from purified coke oven gas 失效用于从纯化焦炉气体生产氨合成气的装置
公开(公告)号：US4336229A
公开(公告)日：1982-06-22
申请号：US199566
申请日：1980-10-22
摘要： Apparatus for the production of ammonia synthesis gas by the catalytic cracking of coke oven gas in the presence of water vapor and air is disclosed. The apparatus includes concentric inner and outer pipes, a first annular reaction zone between the pipes and a second reaction zone inside the inner pipe, both zones containing a catalyst. The purified coke oven gas along with air and water vapor is introduced into the interior of the outer pipe, i.e., into the first reaction zone at one end. The gas flows along the length of the pipes and then into the inner pipe, i.e., the second reaction zone, through a number of openings in the end of the inner pipe opposite the end of the outer pipe where the coke oven gas was initially introduced. The gas then flows along the length of the inner pipe to the opposite end where the cracked gas is removed.
摘要翻译： 公开了在存在水蒸汽和空气的情况下通过焦炉气体的催化裂化生产氨合成气的装置。 该设备包括同心的内管和外管，管之间的第一环形反应区和内管内的第二反应区，两区含有催化剂。 纯化的焦炉气体以及空气和水蒸汽被引入外管的内部，即在一端进入第一反应区。 气体沿着管道的长度流动，然后通过在内管的端部中的多个开口进入内管，即第二反应区，内部管的最初引入焦炉气体的外管的端部 。 然后，气体沿着内管的长度流动到去除裂解气体的相对端。
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公开(公告)号：US4235624A
公开(公告)日：1980-11-25
申请号：US928468
申请日：1978-07-27
CPC分类号： C21B13/0073 , C01B3/22 , C01B3/36 , C10B27/00 , C10K3/00 , Y02P10/136
摘要： Hot coke oven gas is subjected, immediately after the discharge thereof from coke ovens, and without any preliminary cooling operation, to partial oxidation and cracking with an oxygen-containing gas, thereby forming a hot cracked gas rich in carbon monoxide and hydrogen. The hot coke oven gas may be subjected to a desulfurization operation prior to the partial oxidation and cracking. Alternatively, the hot cracked gas may be subjected to a desulfurization operation after the partial oxidation and cracking. When the coke ovens are part of an overall metallurgical installation which includes an air separation and dissociation plant for obtaining substantially pure oxygen, the oxygen-containing gas employed in the partial oxidation and cracking may comprise oxygen enriched gas which is taken from an intermediate stage of the air separation and dissociation plant.
摘要翻译： 热焦炉气体在从焦炉排出之后立即进行，并且在没有任何预冷却操作下，用含氧气体进行部分氧化和裂化，从而形成富含一氧化碳和氢气的热裂解气体。 可以在部分氧化和裂化之前对热焦炉气体进行脱硫操作。 或者，可以在部分氧化和裂化之后对热裂化气体进行脱硫操作。 当焦炉是整个冶金设备的一部分，其包括用于获得基本上纯氧的空气分离和解离设备时，用于部分氧化和裂化的含氧气体可以包含富氧气体，其从中间阶段 空气分离装置。
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