High strength SAPO-34 microsphere catalyst, method for preparing same, and method for preparing light olefins using same

    公开(公告)号:US10112187B2

    公开(公告)日:2018-10-30

    申请号:US13502496

    申请日:2010-10-04

    摘要: The present invention relates to a high-strength silicoaluminophasphate-34 (SAPO-34) microsphere catalyst, a method for preparing the same, and a method for preparing light olefins by using the same, and when described in more detail, the present invention relates to a method for preparing a SAPO-34 microsphere catalyst, including: spray drying a mixed slurry including a matrix, a binder, an additive, and the like to a SAPO-34 slurry prepared by a hydrothermal synthesizing method using various organic templates such as tetraethylammonium hydroxide (TEAOH), and the like alone or in mixtures to prepare microspheres, and firing the microspheres, and to a SAPO-34 microsphere catalyst for a circulating-fluidized bed reactor, prepared by the preparation method. The SAPO-34 microsphere catalyst of the present invention has excellent reaction activity while having high strength, and thus is appropriate for use in a circulating-fluidized bed reactor requiring high strength of the catalyst. Further, the SAPO-34 microsphere catalyst has a long life-span and excellent conversion rate of C1 to C4 oxygen-including compounds (oxygenates), and thus is appropriate for use in the preparation of light olefins such as ethylene, propylene, butene, and the like.

    METHOD FOR PREPARING DIALKYL CARBONATE
    2.
    发明申请
    METHOD FOR PREPARING DIALKYL CARBONATE 有权
    制备碳酸二乙酯的方法

    公开(公告)号:US20120130111A1

    公开(公告)日:2012-05-24

    申请号:US13388078

    申请日:2009-11-27

    IPC分类号: C07C68/00

    CPC分类号: C07C68/00 C07C69/96

    摘要: The present invention provides a method for preparing dialkyl carbonate from urea or alkyl carbamate and alkyl alcohol using an ionic liquid comprising a cation, which produces a hydrogen ion, and a hydrophobic anion containing fluorine with high temperature stability in the presence of catalyst containing a metal oxide or hydrotalcite. Since the present invention can prepare dialkyl carbonate at a pressure lower than those of existing methods, it does not require an expensive pressure control device and peripheral devices for maintaining high pressure including the installation cost. It is also the method for preparing a dialkyl carbonate with high yield, thus improving economical efficiency. Moreover, the method of the present invention hardly produces any waste during the process and is thus an eco-friendly method.

    摘要翻译: 本发明提供一种在含有金属的催化剂存在下,使用含有产生氢离子的阳离子的离子液体和含有氟的疏水性阴离子,由脲或烷基氨基甲酸酯和烷基醇制备碳酸二烷基酯的方法, 氧化物或水滑石。 由于本发明可以以比现有方法低的压力制备碳酸二烷基酯,所以不需要昂贵的压力控制装置和用于保持高压的外围装置,包括安装成本。 也是以高产率制备碳酸二烷基酯的方法,从而提高了经济性。 此外,本发明的方法在该方法中几乎不产生浪费,因此是一种环保方法。

    Process for preparing controlled-released chitosan microcapsule
    3.
    发明授权
    Process for preparing controlled-released chitosan microcapsule 有权
    制备受控释放的壳聚糖微胶囊的方法

    公开(公告)号:US06228291B1

    公开(公告)日:2001-05-08

    申请号:US09342070

    申请日:1999-06-29

    IPC分类号: B01J1302

    摘要: The present invention relates to a process for preparing the controlled-release chitosan microcapsule, more specifically to a process for preparing the sustained-release chitosan microcapsule capable of releasing at an appropriate rate for a long time, which is characterized by: a) Biodegradable chitosan polymer is used for the capsule material; b) The capsule is kept stable during the release time by the rapid and effective crosslinking reaction between the chitosan polymer and the double crosslinking agent on the surface of tiny particles formed by a new emulsion interface reaction method using a double crosslinking agent of sulfuric acid and glutaraldehyde; and c) The microcapsule which is smaller than several &mgr;m s can be easily formed and the capsule is kept stable for a long release time because an insoluble polymer film whose source material is biodegradable is formed after the release.

    摘要翻译: 本发明涉及一种制备控制释放壳聚糖微胶囊的方法,更具体地涉及能够长时间以适当速率释放的缓释壳聚糖微胶囊的制备方法,其特征在于:a)可生物降解的壳聚糖 聚合物用于胶囊材料; b)胶囊在释放时间内通过壳聚糖聚合物和双交联剂之间的快速有效的交联反应在通过新的乳液界面反应方法形成的微小颗粒的表面上保持稳定,该方法使用 硫酸和戊二醛的双交联剂; 和)可以容易地形成小于几个微米的微胶囊,并且由于在释放后形成源材料是可生物降解的不溶性聚合物膜,所以胶囊保持稳定的长时间释放时间。

    Method for preparing dialkyl carbonate
    4.
    发明授权
    Method for preparing dialkyl carbonate 有权
    碳酸二烷基酯的制备方法

    公开(公告)号:US08629295B2

    公开(公告)日:2014-01-14

    申请号:US13388078

    申请日:2009-11-27

    IPC分类号: C07C68/00

    CPC分类号: C07C68/00 C07C69/96

    摘要: The present invention provides a method for preparing dialkyl carbonate from urea or alkyl carbamate and alkyl alcohol using an ionic liquid comprising a cation, which produces a hydrogen ion, and a hydrophobic anion containing fluorine with high temperature stability in the presence of catalyst containing a metal oxide or hydrotalcite. Since the present invention can prepare dialkyl carbonate at a pressure lower than those of existing methods, it does not require an expensive pressure control device and peripheral devices for maintaining high pressure including the installation cost. It is also the method for preparing a dialkyl carbonate with high yield, thus improving economical efficiency. Moreover, the method of the present invention hardly produces any waste during the process and is thus an eco-friendly method.

    摘要翻译: 本发明提供一种在含有金属的催化剂存在下,使用含有产生氢离子的阳离子的离子液体和含有氟的疏水性阴离子,由脲或烷基氨基甲酸酯和烷基醇制备碳酸二烷基酯的方法, 氧化物或水滑石。 由于本发明可以以比现有方法低的压力制备碳酸二烷基酯,所以不需要昂贵的压力控制装置和用于保持高压的外围装置,包括安装成本。 也是以高产率制备碳酸二烷基酯的方法,从而提高了经济性。 此外,本发明的方法在该方法中几乎不产生浪费,因此是一种环保方法。

    HIGH STRENGTH SAPO-34 MICROSPHERE CATALYST, METHOD FOR PREPARING SAME, AND METHOD FOR PREPARING LIGHT OLEFINS USING SAME
    5.
    发明申请
    HIGH STRENGTH SAPO-34 MICROSPHERE CATALYST, METHOD FOR PREPARING SAME, AND METHOD FOR PREPARING LIGHT OLEFINS USING SAME 审中-公开
    高强度SAPO-34微球催化剂,其制备方法以及使用其制备光油的方法

    公开(公告)号:US20120203046A1

    公开(公告)日:2012-08-09

    申请号:US13502496

    申请日:2010-10-04

    IPC分类号: B01J35/08 C07C1/20 B01J27/182

    摘要: The present invention relates to a high-strength silicoaluminophasphate-34 (SAPO-34) microsphere catalyst, a method for preparing the same, and a method for preparing light olefins by using the same, and when described in more detail, the present invention relates to a method for preparing a SAPO-34 microsphere catalyst, including: spray drying a mixed slurry including a matrix, a binder, an additive, and the like to a SAPO-34 slurry prepared by a hydrothermal synthesizing method using various organic templates such as tetraethylammonium hydroxide (TEAOH), and the like alone or in mixtures to prepare microspheres, and firing the microspheres, and to a SAPO-34 microsphere catalyst for a circulating-fluidized bed reactor, prepared by the preparation method. The SAPO-34 microsphere catalyst of the present invention has excellent reaction activity while having high strength, and thus is appropriate for use in a circulating-fluidized bed reactor requiring high strength of the catalyst. Further, the SAPO-34 microsphere catalyst has a long life-span and excellent conversion rate of C1 to C4 oxygen-including compounds (oxygenates), and thus is appropriate for use in the preparation of light olefins such as ethylene, propylene, butene, and the like.

    摘要翻译: 本发明涉及一种高强度硅铝硅酸盐-S34(SAPO-34)微球体催化剂及其制备方法,以及使用该微球体催化剂的轻质烯烃的制备方法,更详细地说明本发明涉及 涉及一种制备SAPO-34微球催化剂的方法,包括:将包含基质,粘合剂,添加剂等的混合浆料喷雾干燥至通过水热合成法制备的SAPO-34浆料,使用各种有机模板如 四乙基氢氧化铵(TEAOH)等单独或以混合物形式制备微球,并烧制微球,以及通过制备方法制备的循环流化床反应器的SAPO-34微球催化剂。 本发明的SAPO-34微球催化剂具有优异的反应活性,同时具有高强度,因此适用于需要高强度催化剂的循环流化床反应器。 此外,SAPO-34微球催化剂具有长寿命和优异的C1至C4含氧化合物(含氧化合物)的转化率,因此适用于制备轻质烯烃如乙烯,丙烯,丁烯, 等等。

    Method and apparatus for on-line measurement of the permeation characteristics of a permeant through dense nonporous membrane
    7.
    发明授权
    Method and apparatus for on-line measurement of the permeation characteristics of a permeant through dense nonporous membrane 失效
    用于在线测量渗透物通过致密无孔膜的渗透特性的方法和装置

    公开(公告)号:US06335202B1

    公开(公告)日:2002-01-01

    申请号:US09329492

    申请日:1999-06-10

    IPC分类号: G01N3002

    摘要: This invention relates to a method and apparatus for on-line measurement of permeation characteristics (transmitting chemicals) through dense nonporous membrane. This invention is intended to facilitate various research activities, such as simultaneous analyses of diffusion coefficient, solubility coefficient, permeation rate and permeant composition, and presentation of new analysis about the permeation behavior, kinetics and so on. The object of this invention is to provide the method and apparatus for measurement of permeation characteristics of permeants in liquid, vapor or gas phase through dense nonporous membrane and more practicuraly, to provide permeation apparatus for measurement of permeation characteristics by analyzing permeation rate and permeation concentration of permeants through an on-line type dense porous membrane with time, not only for a steady state but also for an unsteady state in an accurate and reliable manner.

    摘要翻译: 本发明涉及通过致密无孔膜在线测量渗透特性(透射化学品)的方法和设备。 本发明旨在促进各种研究活动,例如扩散系数的同时分析,溶解度系数,渗透速率和渗透物组成,以及关于渗透行为,动力学等的新分析的呈现。 本发明的目的是提供用于通过致密无孔膜测量渗透液渗透特性的方法和装置,并且更实用,以便通过分析渗透速率和渗透浓度来提供用于测量渗透特性的渗透装置 的渗透剂通过在线型致密多孔膜随时间而变化,不仅用于稳定状态,而且以准​​确可靠的方式进行非稳态。

    Polyion complex separation membrane with a double structure
    8.
    发明授权
    Polyion complex separation membrane with a double structure 失效
    Polyion复合分离膜具有双重结构

    公开(公告)号:US06325218B1

    公开(公告)日:2001-12-04

    申请号:US09486238

    申请日:2000-02-24

    IPC分类号: B01D2905

    摘要: This invention relates to a polyion complex separation membrane with a double structure, which is applicable in the separation process of a water-soluble mixture having ionic molecules or particles by means of reverse osmotic pressure for the purposes of recovering expensive ionic organic materials such as anionic emulsifiers from the waste water. More particularly, this invention relates to said membrane having anionic polymers, as substrate, which is immersed into a cationic polymer solution containing a multivalent ion cross-linking agent, by which a cross-linkage within the internal of the separation membrane is achieved, thereby forming an ion complex between ionic polymers of opposite ion at the surface of the separation membrane to yield a stable separation membrane of a double structure.

    摘要翻译: 本发明涉及具有双重结构的聚离子络合物分离膜,其可应用于具有离子分子或颗粒的水溶性混合物通过反渗透压力的分离过程,用于回收昂贵的离子有机材料如阴离子 来自废水的乳化剂。 更具体地说,本发明涉及具有阴离子聚合物作为底物的所述膜,其被浸入含有多价离子交联剂的阳离子聚合物溶液中,由此实现了分离膜内部的交联,由此 在分离膜表面的相对离子的离子聚合物之间形成离子络合物,得到双重结构的稳定的分离膜。