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公开(公告)号：US4935467A
公开(公告)日：1990-06-19
申请号：US166954
申请日：1988-03-11
申请人： Tai C. Cheng , Bruce A. Kaduk , Ashok K. Mehan , David D. Taft , Carl J. Weber , Steven C. Zingheim
发明人： Tai C. Cheng , Bruce A. Kaduk , Ashok K. Mehan , David D. Taft , Carl J. Weber , Steven C. Zingheim
CPC分类号： H01B1/24 , C08L23/08 , C08L27/16 , C08L27/18 , C08L53/00 , H01B1/20 , H01B1/22 , Y10T428/294
摘要： Novel compositions comprise a blend of(A) a thermoplastic polymer selected from copolymers of ethylene and tetrafluoroethylene, and thermoplastic vinylidene fluoride polymers; and(B) a thermoplastic elastomer having (i) at least one elastomeric segment comprising (a) vinylidene fluoride, hexa- or pentafluoropropylene, and tetrafluoroethylene repeating units in a mole ratio of 45-90:5-50:0-35 or (b) perfluoro(alkyl vinyl ether), tetrafluoroethylene and vinylidene fluoride repeating units in a mole ratio of 15-75:0-85:0-85; and (ii) at least one nonelastomeric segment selected from segments comprising ethylene and tetrafluoroethylene repeating units in a mole ratio of 40-60:60-40, and segments comprising vinylidene fluoride, hexafluoropropylene and tetrafluoroethylene repeating units in a mole ratio of 0-100:0-50:0-100,with the proviso that if the thermoplastic polymer is a vinylidene fluoride polymer, the blend is crosslinked.
摘要翻译： 新型组合物包含（A）选自乙烯和四氟乙烯的共聚物的热塑性聚合物和热塑性偏二氟乙烯聚合物的共混物; 和（B）热塑性弹性体，其具有（i）至少一种弹性体链段，其包含（a）偏二氟乙烯，六氟丙烯和五氟丙烯，和四氟乙烯重复单元，其摩尔比为45-90：5-50：0-35或（ b）摩尔比为15-75:0-85:0-85的全氟（烷基乙烯基醚），四氟乙烯和偏二氟乙烯重复单元; 和（ii）选自摩尔比为40-60:60-40的乙烯和四氟乙烯重复单元的段的至少一个非弹性链段，以及摩尔比为0-100的偏二氟乙烯，六氟丙烯和四氟乙烯重复单元的链段 ：0-50：0-100，条件是如果热塑性聚合物是偏二氟乙烯聚合物，则共混物是交联的。
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2.发明授权Copolymers of polyarylates with polyethylene arylates and process for their preparation 失效聚芳酯与聚乙烯芳基化物的共聚物及其制备方法
公开(公告)号：US4358568A
公开(公告)日：1982-11-09
申请号：US187768
申请日：1980-09-16
IPC分类号： C08G63/195 , C08G63/64 , C08L67/02 , C08L69/00
CPC分类号： C08G63/64 , C08G63/195
摘要： Novel copolymers are prepared by the interaction of low or high molecular weight polyarylates, such as bisphenol A-isophthalate-terephthalate polyarylates, or bisphenol A-isophthalate-terephthalate-carbonate polyarylates and a high molecular weight diprimary dialcohol polyester polymer, such as polyethylene terephthalate polymer. The resulting copolymers are transparent and tough. They maintain their dimensional stability over a wide range of temperature from 75.degree.-175.degree. C., are soluble in chlorinated solvents, and have one glass transition point.
摘要翻译： 新型共聚物可通过低分子量或高分子量的多芳基化合物如双酚A-间苯二甲酸酯 - 对苯二甲酸酯多芳基酯或双酚A-间苯二甲酸酯 - 对苯二甲酸酯 - 碳酸酯多芳酯和高分子量二元二元醇聚酯聚合物如聚对苯二甲酸乙二醇酯聚合物 。 所得共聚物是透明和韧性的。 它们在75°-175℃的宽温度范围内保持其尺寸稳定性，可溶于氯化溶剂，并具有一个玻璃化转变点。
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3.发明授权Copolymers of polyarylates with polyethylene arylates and process for their preparation 失效聚芳酯与聚乙烯芳基化物的共聚物及其制备方法
公开(公告)号：US4440912A
公开(公告)日：1984-04-03
申请号：US371263
申请日：1982-04-23
IPC分类号： C08G63/195 , C08G63/64 , C08L67/00 , C08L69/00
CPC分类号： C08G63/64 , C08G63/195
摘要： Novel copolymers are prepared by the interaction of low or high molecular weight polyarylates, such as bisphenol A-isophthalate-terephthalate polyarylates, or bisphenol A-isophthalate-terephthalate-carbonate polyarylates and a high molecular weight diprimary dialcohol polyester polymer, such as polyethylene terephthalate polymer. The resulting copolymers are transparent and tough. They maintain their dimensional stability over a wide range of temperature from 75.degree.-175.degree. C., are soluble in chlorinated solvents, and have one glass transition point.
摘要翻译： 新型共聚物可通过低分子量或高分子量的多芳基化合物如双酚A-间苯二甲酸酯 - 对苯二甲酸酯多芳基酯或双酚A-间苯二甲酸酯 - 对苯二甲酸酯 - 碳酸酯多芳酯和高分子量二元二元醇聚酯聚合物如聚对苯二甲酸乙二醇酯聚合物 。 所得共聚物是透明和韧性的。 它们在75°-175℃的宽温度范围内保持其尺寸稳定性，可溶于氯化溶剂，并具有一个玻璃化转变点。
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公开(公告)号：US4507442A
公开(公告)日：1985-03-26
申请号：US400902
申请日：1982-07-22
CPC分类号： C08G63/64
摘要： Novel copolymers are prepared by the interaction of a melt mix of a high molecular weight or low molecular weight bisphenol A polycarbonate polymer and a high molecular weight diprimary dialcohol polyester polymer such as polyethylene terephthalate polymer. The resulting copolymers are transparent, relatively tough and are useful as glazing materials or molding compounds and are capable of maintaining dimensional stability at temperatures approaching their glass transition temperature.
摘要翻译： 通过高分子量或低分子量双酚A聚碳酸酯聚合物和高分子量二元二元二醇聚酯聚合物如聚对苯二甲酸乙二醇酯聚合物的熔融混合物的相互作用来制备新型共聚物。 所得共聚物是透明的，相对坚韧的并且可用作玻璃材料或模塑料，并且能够在接近其玻璃化转变温度的温度下保持尺寸稳定性。
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公开(公告)号：US4367317A
公开(公告)日：1983-01-04
申请号：US188177
申请日：1980-09-17
CPC分类号： C08G63/64
摘要： Novel copolymers are prepared by the interaction of a melt mix of a high molecular weight or low molecular weight bisphenol A polycarbonate polymer and a high molecular weight diprimary dialcohol polyester polymer such as polyethylene terephthalate polymer. The resulting copolymers are transparent, relatively tough and are useful as glazing materials or molding compounds and are capable of maintaining dimensional stability at temperatures approaching their glass transition temperature.
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