Abstract:
This invention relates to an autodeposition bath composition comprising a nitrogen containing compound, said bath being suitable for generating a uniform autodeposition coating on two or more of ferrous, aluminum, magnesium and zinciferous multi-metal substrate surfaces, treated either sequentially or simultaneously. The invention also provides autodeposition concentrate compositions for use in the bath, methods of making and using the concentrate and bath, as well as metal articles comprising an autodeposition coating according to the invention.
Abstract:
This invention relates to an autodeposition bath composition comprising a nitrogen containing compound, said bath being suitable for generating a uniform autodeposition coating on two or more of ferrous, aluminum, magnesium and zinciferous multi-metal substrate surfaces, treated either sequentially or simultaneously. The invention also provides autodeposition concentrate compositions for use in the bath, methods of making and using the concentrate and bath, as well as metal articles comprising an autodeposition coating according to the invention.
Abstract:
The use of chelating type cation exchange resins, particularly those with iminodiacetic acid functionality, to remove dissolved multivalent cations such as iron, zinc, and chromium from used autodeposition compositions permits reuse of the autodeposition compositions without the need for added surfactant and without developing any undesirable graininess or other texture in the coatings formed. The cation exchange resins can be efficiently regenerated with 0.5 to 4% by weight aqueous hydrofluoric acid.
Abstract:
Autodepositing compositions of the type that form coatings which tend to crack in the wet stage are modified by including in the composition a fugitive plasticizer, such as 2,2,4-trimethylpentanediol-1,3 monoisobutyrate, tributoxyethyl phosphate, ethylene glycol monohexyl ether, diethylene glycol monohexyl ether, or a mixture of phenyl glycol ethers.
Abstract:
A coated article comprising a metal surface, a first layer of an uncured autodeposition coating and a second uncured paint layer deposited sequentially on the surface without intermediate curing of the autodeposition coating, a process of co-curing said autodeposition coating and paint layer or layers, and a cured coated article having chemical bonds between the cured autodeposition coating layer and at least the cured paint layer immediately adjacent to the cured autodeposition coating layer.
Abstract:
A coated article comprising a metal surface, a first layer of an uncured autodeposition coating and a second uncured paint layer deposited sequentially on the surface without intermediate curing of the autodeposition coating, a process of co-curing said autodeposition coating and paint layer or layers, and a cured coated article having chemical bonds between the cured autodeposition coating layer and at least the cured paint layer immediately adjacent to the cured autodeposition coating layer.
Abstract:
An apparatus and method is provided for automated periodic removal of metal ions and contaminants from a chemical bath comprising a latex solution containing charged latex particles and having an acidic pH, used for forming a coating by autodeposition. The system includes a tank containing a chemical bath, an ion exchange column for removing the metal ion contaminants, circulating pump, metal composition sensors, and equipment for regeneration of the ion exchange column. The system particularly includes a filter located at the inlet to the ion exchange column for removing solid particulates, including coagulated latex and debris from the coating solution, while permitting the uncoagulated latex particles to pass through to the ion exchange column.
Abstract:
Process for forming an autodeposition coating on a metallic substrate by applying an autodepositing composition from a motile source thereof such as by spraying or by treating the surface with a continuous stream of the autodepositing composition.
Abstract:
A reaction rinse containing strong alkali, betaine surfactants, and a complexing agent for iron enhances the gloss of a dried and cured autodeposited coating that is contacted with the reaction rinse while still wet, particularly if the autodeposited coating consists predominantly of a copolymer of vinylidene chloride.