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22 条记录 (耗时 0.012 秒)

    Method for the production of N-alkenyl-amides
    1.
    发明授权
    Method for the production of N-alkenyl-amides 失效
    制备N-烯基酰胺的方法

    公开(公告)号：US06673920B2

    公开(公告)日：2004-01-06

    申请号：US10168211

    申请日：2002-06-19

    申请人： Thomas Preiss ,  Arnd Böttcher ,  Rolf Pinkos ,  Rudolf Erich Lorenz

    发明人： Thomas Preiss ,  Arnd Böttcher ,  Rolf Pinkos ,  Rudolf Erich Lorenz

    IPC分类号： C07D22310

    CPC分类号： C07D207/267 ,  C07C231/08 ,  C07D211/76 ,  C07D223/10

    摘要： A process for preparing N-alkenyl-amides by reacting the corresponding NH-amides with acetylenes in the liquid phase in the presence of basic alkali metal compounds and of a cocatalyst comprises using as the cocatalyst diols of the general formula (I) where X is branched or unbranched alkylene selected from the group consisting of where R1 to R6 are independently hydrogen or C1- to C4-alkyl; or branched or unbranched cyclic alkylene of 3 to 14 carbon atoms including 3 to 12 ring carbon atoms, their monoalkenyl ethers, their dialkenyl ethers or mixtures thereof.

    摘要翻译： 在碱性碱金属化合物和助催化剂存在下，通过使液相中相应的NH-酰胺与乙炔反应来制备N-烯基酰胺的方法包括使用通式（I）的助催化剂二醇，其中X支化 或非支链的亚烷基，其中R 1至R 6独立地为氢或C 1至C 4 - 烷基;包含3至12个环碳原子的3至14个碳原子的支链或非支链环状亚烷基，它们的单链烯基醚，它们的二链烯基醚或 其混合物。

    Reaction of organic compounds over macroporous supported catalysts comprising boron oxide
    2.
    发明授权
    Reaction of organic compounds over macroporous supported catalysts comprising boron oxide 失效
    有机化合物与包含氧化硼的大孔载体催化剂反应

    公开(公告)号：US06432861B1

    公开(公告)日：2002-08-13

    申请号：US09349082

    申请日：1999-07-08

    申请人： Boris Breitscheidel ,  Uwe Diehlmann ,  Alois Kindler ,  Jochem Henkelmann ,  Arnd Böttcher

    发明人： Boris Breitscheidel ,  Uwe Diehlmann ,  Alois Kindler ,  Jochem Henkelmann ,  Arnd Böttcher

    IPC分类号： C08F804

    CPC分类号： C08F8/04 ,  B01J21/02

    摘要： In a process for reacting an organic compound in the presence of a catalyst comprising, as active metal, at least one metal of transition group VIII of the Periodic Table, either alone or together with at least one metal of transition group I or VII of the Periodic Table, in an amount of from 0.01 to 30% by weight, based on the total weight of the catalyst, applied to a support containing macropores, the support comprises, as a support component, boron(III) oxide in an amount of from 10 to 100% by weight, based on the total weight of the support.

    摘要翻译： 在一种催化剂存在下使有机化合物反应的方法，该催化剂包含作为活性金属的至少一种元素周期表第VIII族金属，单独或与至少一种第 周期表，以基于催化剂总重量的0.01至30重量％的量施用于含有大孔的载体，载体包含作为载体组分的氧化硼（III），其量为 10至100重量％，基于载体的总重量。

    Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores
    3.
    发明授权
    Method for hydrogenating benzene polycarboxylic acids or derivatives thereof by using a catalyst containing macropores 有权

    公开(公告)号：US06284917B1

    公开(公告)日：2001-09-04

    申请号：US09581843

    申请日：2000-06-19

    申请人： Melanie Brunner ,  Arnd Böttcher ,  Boris Breitscheidel ,  Klaus Halbritter ,  Jochem Henkelmann ,  Lucien Thil ,  Rolf Pinkos

    发明人： Melanie Brunner ,  Arnd Böttcher ,  Boris Breitscheidel ,  Klaus Halbritter ,  Jochem Henkelmann ,  Lucien Thil ,  Rolf Pinkos

    IPC分类号： C07C6974

    CPC分类号： C08K5/12 ,  C07C51/36 ,  C07C67/303 ,  C07C69/75 ,  C07C2601/14 ,  C07C61/09

    摘要： A process for hydrogenating a benzenepolycarboxylic acid or a derivative thereof or a mixture of two or more thereof by bringing the benzenepolycarboxylic acid or the derivative thereof or the mixture of two or more thereof into contact with a hydrogen-containing gas is carried out in the presence of a catalyst which comprises as active metal at least one metal of transition group VIII of the Periodic Table alone or together with at least one metal of transition group I or VII of the periodic table applied to a support which contains macropores with the proviso that if dimethyl terephthalate is hydrogenated, the hydrogenation using a catalyst which comprises as active metal ruthenium either alone or together with at least one metal of transition group I, VII or VIII of the Periodic Table applied to a support, where the support has a mean pore diameter of at least 50 nm and a BET surface area of at most 30 m2/g and the amount of the active metal is from 0.01 to 30% by weight, based on the total weight of the catalyst, and the ratio of the surface areas of the active metal and the catalyst support is less than 0.05, and/or a catalyst which comprises as active metal ruthenium either alone or together with at least one metal of transition group I, VII or VIII of the Periodic Table in an amount of from 0.01 to 30% by weight, based on the total weight of the catalyst, applied to a support, where from 10 to 50% of the pore volume of the support is formed by macropores having a pore diameter in the range from 50 nm to 10,000 nm and from 50 to 90% of the pore volume of the support is formed by mesopores having a pore diameter in the range from 2 to 50 nm, where the sum of the pore volumes adds up to 100%, is excluded, and novel hydrogenation products, obtainable by hydrogenating benzenepolycarboxylic acid (derivatives) as well as their use as plasticizers in plastics.

    Preparation of pyrrole and pyridine
    4.
    发明授权
    Preparation of pyrrole and pyridine 有权
    制备吡咯和吡啶

    公开(公告)号：US06538139B1

    公开(公告)日：2003-03-25

    申请号：US10234169

    申请日：2002-09-05

    申请人： Martin Schäfer ,  Arnd Böttcher ,  Andreas Kramer ,  Arthur Höhn ,  Reinhard Kaczmarek ,  Erhard Henkes

    发明人： Martin Schäfer ,  Arnd Böttcher ,  Andreas Kramer ,  Arthur Höhn ,  Reinhard Kaczmarek ,  Erhard Henkes

    IPC分类号： C07D213133

    CPC分类号： C07D207/323 ,  B01J23/42 ,  B01J23/44 ,  B01J23/63 ,  C07D213/06

    摘要： Pyrroles of the formula (I) are prepared by dehydrogenating pyrrolidines of the formula (II) where R1 and R2, independently of one another, are hydrogen or an aliphatic radical of 1 to 6 carbon atoms, or pyridines of the formula (III) are prepared by dehydrogenating piperidines of the formula (IV) where R3, R4 and R5, independently of one another, are hydrogen or an aliphatic radical of 1 to 6 carbon atoms, in the presence of a supported noble metal catalyst, by a process in which the dehydrogenation is carried out in the presence of from 1 to 50% by weight, based on the pyrrolidine or piperidine and water, of water.

    摘要翻译： 式（I）的吡咯通过使式（II）的吡咯烷脱氢制备，其中R1和R2彼此独立地是氢或具有1至6个碳原子的脂肪族基团，或者制备式（III）的吡啶 通过使负载型贵金属催化剂存在下，式（IV）的哌啶脱氢，其中R 3，R 4和R 5彼此独立地是氢或1-6个碳原子的脂族基团，其中脱氢 在1至50重量％的存在下，基于吡咯烷或哌啶和水的水进行。

    Method for the production of cyclohexanol from benzene
    6.
    发明授权
    Method for the production of cyclohexanol from benzene 失效
    从苯生产环己醇的方法

    公开(公告)号：US06943274B2

    公开(公告)日：2005-09-13

    申请号：US10505705

    申请日：2003-02-28

    申请人： Werner Peschel ,  Till Adrian ,  Harald Rust ,  Arnd Böttcher ,  Thomas Hill ,  Ulrich Müller ,  Rainer Papp

    发明人： Werner Peschel ,  Till Adrian ,  Harald Rust ,  Arnd Böttcher ,  Thomas Hill ,  Ulrich Müller ,  Rainer Papp

    IPC分类号： C07C5/11 ,  C07B61/00 ,  C07C29/04 ,  C07C35/08 ,  C07C29/20

    CPC分类号： C07C29/04 ,  C07C2601/14 ,  C07C35/08

    摘要： A process for preparing cyclohexanol from benzene by: a) preparing cyclohexene by hydrogenating benzene in the presence of a catalyst, and b) preparing cyclohexanol by hydrating the cyclohexene in the presence of a catalyst, comprises: carrying out steps a) and b) in a reaction facility which has a bottom region at the lower end, a top region at the upper end, and a reaction zone between the top region and the bottom region which contains the catalyst according to steps a) and b), evaporating a portion of the benzene using the heat of reaction in the reaction zone, condensing it in the top region and returning it to the reaction zone, and withdrawing a reaction mixture containing cyclohexanol in the bottom region.

    摘要翻译： 一种通过以下步骤由苯制备环己醇的方法：a）在催化剂存在下，通过氢化苯来制备环己烯，和b）通过在催化剂存在下使环己烯水合制备环己醇，包括：进行步骤a）和b） 具有下端的底部区域，上端的顶部区域和顶部区域和底部区域之间的反应区域的反应设备，其包含根据步骤a）和b）的催化剂，蒸发一部分 苯在反应区中使用反应热，在顶部区域冷凝并将其返回到反应区，并在底部区域中抽出含有环己醇的反应混合物。

    Method for preparing a catalyst and catalysts prepared accordingly
    10.
    发明授权
    Method for preparing a catalyst and catalysts prepared accordingly 失效
    制备相应的催化剂和催化剂的方法

    公开(公告)号：US06350714B1

    公开(公告)日：2002-02-26

    申请号：US09555603

    申请日：2000-05-31

    申请人： Arnd Böttcher ,  Jochem Henkelmann ,  Thomas Preiss ,  Melanie Brunner

    发明人： Arnd Böttcher ,  Jochem Henkelmann ,  Thomas Preiss ,  Melanie Brunner

    IPC分类号： B01J3100

    CPC分类号： B01J31/1616 ,  B01J31/2286 ,  B01J2231/346 ,  B01J2531/10 ,  B01J2531/16 ,  B01J2531/20 ,  C07C29/42 ,  C07C209/60 ,  C07C213/00 ,  C07C211/23 ,  C07C215/24 ,  C07C33/042 ,  C07C33/046

    摘要： The present invention relates to a process for preparing a catalyst by activating a catalytic composition which comprises a) at least one metal of group IB or IIB or a compound thereof, b) where appropriate a carrier which comprises treating the composition with an alkyne of the general formula I R1—C≡C—R2  (I) in which R1 is alkyl, cycloalkyl, aryl, hydroxyalkyl, haloalkyl, alkoxy or alkoxyalkyl, R2 is a hydrogen atom, alkyl, cycloalkyl or aryl, and a carbonyl compound of the general formula II in which R3 and R4 are, independently of one another, a hydrogen atom, alkyl, haloalkyl, cycloalkyl or aryl, to catalysts obtainable by this process, and to alkynylations and aminoalkylations employing these catalysts.

    摘要翻译： 本发明涉及通过活化催化组合物来制备催化剂的方法，所述催化组合物包含：a）至少一种IB或IIB族金属或其化合物，b）适当的载体包括用通式 其中R 1是烷基，环烷基，芳基，羟烷基，卤代烷基，烷氧基或烷氧基烷基，R 2是氢原子，烷基，环烷基或芳基，和通式IIin的羰基化合物，其中R 3和R 4彼此独立地是氢 原子，烷基，卤代烷基，环烷基或芳基，可通过该方法获得的催化剂，以及使用这些催化剂的炔基化和氨基烷基化。