摘要:
The present invention relates to composite materials comprising a reaction product of (A) at least one organic polymer, (B) sulfur, (C) carbon in a polymorph which comprises at least 60% sp2-hybridized carbon atoms, and (D) 2-20% by weight of a perfluorinated or partly fluorinated polymer, based on the total weight of components (A), (B) and (C) used before reaction, and also to a process for producing inventive composite materials and to the use of inventive composite materials.
摘要:
Process for working up an exhaust gas from a system for producing hydroxylamine or hydroxylammonium salts by catalytic reduction of nitrogen monoxide with hydrogen, the exhaust gas containing nitrogen monoxide, hydrogen, dinitrogen monoxide, nitrogen and ammonia. At least some of the hydrogen present in the exhaust gas is separated off from the exhaust gas by means of a gas-tight membrane-electrode assembly which comprises at least one selectively proton-conducting membrane, a retentate side, a permeate side, and, on each side of the membrane, at least one electrode catalyst, wherein, on the retentate side of the membrane, at least some of the hydrogen is oxidized to protons at the anode catalyst and the protons, after crossing the membrane, are, on the permeate side, at the cathode catalyst according to (I) reduced to hydrogen and/or (II) reacted with oxygen to form water, the oxygen originating from an oxygen-containing stream which is contacted with the permeate side.
摘要:
The invention relates to a process for the continuous production of a catalyst comprising an alloy of a metal of the platinum group and at least a second metal as alloying metal selected from among the metals of the platinum group and the transition metals, in which a catalyst comprising the metal of the platinum group is mixed with at least one complex each comprising the alloying metal to give an alloy precursor and the alloy precursor is heated in a continuously operated furnace to produce the alloy.
摘要:
The present invention relates to composite materials comprising a reaction product of (A) at least one organic polymer, (B) sulfur, (C) carbon in a polymorph which comprises at least 60% sp2-hybridized carbon atoms, and (D) 2-20% by weight of a perfluorinated or partly fluorinated polymer, based on the total weight of components (A), (B) and (C) used before reaction, and also to a process for producing inventive composite materials and to the use of inventive composite materials.
摘要:
The invention relates to a process for converting aliphatic hydrocarbons having from 1 to 4 carbon atoms into aromatic hydrocarbons, which comprises the steps: a) reaction of a feed stream E comprising at least one aliphatic hydrocarbon having from 1 to 4 carbon atoms in the presence of a catalyst under nonoxidative conditions to give a product stream P comprising aromatic hydrocarbons and hydrogen and b) electrochemical removal of at least part of the hydrogen formed in the reaction from the product stream P by means of a gastight membrane-electrode assembly comprising at least one selectively proton-conducting membrane and at least one electrode catalyst on each side of the membrane, where at least part of the hydrogen is oxidized to protons over the anode catalyst on the retentate side of the membrane and the protons are, after passing through the membrane on the permeate side, reacted with oxygen to form water over the cathode catalyst, with the oxygen originating from an oxygen-comprising stream O which is brought into contact with the permeate side of the membrane.
摘要:
Process for the direct amination of hydrocarbons to aminohydrocarbons, which comprises the steps: a) reaction of a feed stream E comprising at least one hydrocarbon and at least one aminating reagent to form a reaction mixture R comprising aminohydrocarbons and hydrogen and b) electrochemical separation of at least part of the hydrogen formed in the reaction from the reaction mixture R by means of a gastight membrane-electrode assembly having at least one selectively proton-conducting membrane and at least one electrode catalyst on each side of the membrane, where at least part of the hydrogen is oxidized to protons over the anode catalyst on the retentate side of the membrane and the protons are, after passing through the membrane, b1) reduced to hydrogen and/or b2) reacted with oxygen from an oxygen-comprising stream O which is brought into contact with the permeate side of the membrane to form water over the cathode catalyst on the permeate side.
摘要:
The present invention relates to a process for converting aliphatic hydrocarbons having 1 to 4 carbon atoms to aromatic hydrocarbons in the presence of a catalyst under nonoxidative conditions, wherein at least some of the hydrogen formed in the conversion electrochemically removed is by means of a gas-tight membrane-electrode assembly.
摘要:
The present invention relates to electrode materials for charged electrical cells, comprising at least one polymer comprising polysulfide bridges, and carbon in a polymorph comprising at least 60% sp2-hybridized carbon atoms. The present invention further relates to electrical cells comprising the inventive electrode material, to specific polymers comprising polysulfide bridges, to processes for preparation thereof and to the use of the inventive cells.
摘要:
The present invention relates to a novel particulate porous carbon material containing a carbon phase and at least one pore phase, and to the use of such materials in lithium cells, especially lithium-sulfur cells. The carbon phase forms, with the pore phase, essentially unordered co-continuous phase domains, such that the distance between adjacent domains of the pore phase is not more than 50 nm. The invention also relates to a process for producing such carbon materials and to composite materials comprising elemental sulfur and at least one inventive particulate porous carbon material.
摘要:
Process for the direct amination of hydrocarbons to aminohydrocarbons by reaction of a feed stream E comprising at least one hydrocarbon and at least one aminating reagent to form a reaction mixture R comprising aminohydrocarbon and hydrogen in a reaction zone RZ and electrochemical separation of at least part of the hydrogen formed in the reaction from the reaction mixture R by means of a gastight membrane-electrode assembly having at least one selectively proton-conducting membrane and at least one electrode catalyst on each side of the membrane, where at least part of the hydrogen is oxidized to protons at the anode catalyst on the retentate side of the membrane and the protons pass through the membrane and on the permeate side are reacted with oxygen to form water, where the oxygen originates from an oxygen-comprising stream O which is brought into contact with the permeate side of the membrane, over the cathode catalyst.