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公开(公告)号：US5134224A
公开(公告)日：1992-07-28
申请号：US654983
申请日：1991-02-14
摘要： According to this invention, improved results in terms of molecular weight and percent yield of aromatic sulfide/sulfone polymers are achieved by the employment of a low level modifying agent within a specific range in the polymerization reaction mixture. The modifying agent employed is a salt of an amino carboxylic acid. The salt can be employed as an already existing salt of an amino carboxylic acid or can be formed in situ by employing either an amino carboxylic acid and a base; or a lactam and a base.
摘要翻译： 根据本发明，通过在聚合反应混合物中使用特定范围内的低水平改性剂，可以获得芳族硫化物/砜聚合物的分子量和产率百分数的改进结果。 所用的改性剂是氨基羧酸的盐。 盐可以用作氨基羧酸的已经存在的盐，或者可以通过使用氨基羧酸和碱来原位形成; 或内酰胺和碱。
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2.发明授权Method to recover particulate poly(arylene) sulfides with vaporized separation agent 失效用蒸发分离剂回收颗粒状聚（亚芳基）硫化物的方法
公开(公告)号：US5045629A
公开(公告)日：1991-09-03
申请号：US349562
申请日：1989-05-08
申请人： Afif M. Nesheiwat
发明人： Afif M. Nesheiwat
IPC分类号： C08G75/02
CPC分类号： C08G75/0281
摘要： A method for recovering a crystalline poly(arylene sulfide) from a slurry comprising a particulate poly(arylene sulfide), a polar organic compound, and water, said method comprising:(a) substantially liquefying said particulate poly(arylene sulfide) to form a liquid mixture comprising said substantially liquified poly(arylene sulfide) and said polar organic compound;(b) contacting said liquid mixture with a vaporized separation agent in an amount sufficient to effect a separation between said poly(arylene sulfide) and said polar organic compound;(c) reducing the temperature of said liquid mixture sufficiently to solidify said substantially liquified poly(arylene sulfide) to form a slurry comprising a particulate poly(arylene sulfide); and(d) recovering said particulate poly(arylene sulfide) from said slurry.
摘要翻译： 一种从包含聚（亚芳基硫醚），极性有机化合物和水的颗粒的浆料中回收结晶聚（亚芳基硫醚）的方法，所述方法包括：（a）基本上液化所述聚（亚芳基硫醚）颗粒以形成 液体混合物，其包含所述基本上液化的聚（亚芳基硫醚）和所述极性有机化合物; （b）使所述液体混合物与蒸发的分离剂接触，其量足以使所述聚（亚芳基硫醚）和所述极性有机化合物分离; （c）充分降低所述液体混合物的温度以固化所述基本上液化的聚（亚芳基硫醚）以形成包含聚（亚芳基硫醚）颗粒的浆料; 和（d）从所述浆料中回收所述颗粒状聚（亚芳基硫醚）。
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公开(公告)号：US4963651A
公开(公告)日：1990-10-16
申请号：US349561
申请日：1989-05-08
申请人： Afif M. Nesheiwat
发明人： Afif M. Nesheiwat
IPC分类号： C08G75/02
CPC分类号： C08G75/0281
摘要： A method is provided for recovering poly(arylene sulfide) from a liquid reaction mixture, comprising a liquid-phase poly(arylene sulfide) and a polar organic compound which can also function as a solvent for the polymer, and water. The liquid reaction mixture is contacted by an amount of a vaporized phase separation agent at least sufficient to effect or enhance a phase separation of the liquid-phase poly(arylene sulfide) component from the polar organic compound. The poly(arylene sulfide resins recovered according to this invention exhibit greater particle size than those recovered according to prior art methods, and do not tend to adhere to vessel walls during recovery.
摘要翻译： 提供了用于从液体反应混合物中回收聚（亚芳基硫醚）的方法，该液体反应混合物包含液相聚（亚芳基硫醚）和也可用作聚合物溶剂的极性有机化合物和水。 液体反应混合物与一定量的气相分离剂接触，至少足以使液相聚（亚芳基硫醚）组分与极性有机化合物相分离。 根据本发明回收的聚（亚芳基硫醚树脂）比根据现有技术方法回收的那些具有更大的粒度，并且在回收期间不倾向于粘附到容器壁上。
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公开(公告)号：US4882418A
公开(公告)日：1989-11-21
申请号：US284169
申请日：1988-12-13
申请人： Guy Senatore , Afif M. Nesheiwat , Fred T. Sherk
发明人： Guy Senatore , Afif M. Nesheiwat , Fred T. Sherk
IPC分类号： C08G75/02
CPC分类号： C08G75/0231 , C08G75/0281 , C08G75/0286
摘要： A process is provided for removing solid and liquid impurities from a particulate arylene sulfide polymer recovered from a polymerization reaction mixture slurry, without significantly discoloring the resulting washed polymer. The process of this invention comprises the steps of: (a) preparing a first slurry, wherein the solid component thereof comprises a particulate arylene sulfide polymer recovered from a reaction mixture slurry, and wherein the liquid component thereof comprises a mixture of water and a reducing agent; (b) heating the first slurry to a temperature of at least about 185.degree. C. (365.degree. F.) but below the melting point of the particulate polymer, to wash the polymer contained therein; (c) cooling the first slurry to a temperature below about 100.degree. C. (212.degree. F.), to form a second slurry, wherein the solid component thereof comprises a washed particulate arylene sulfide polymer; and (d) recovering the washed particulate arylene sulfide polymer from the second slurry.
摘要翻译： 提供一种从聚合反应混合物浆料中回收的颗粒状亚芳基硫醚聚合物中除去固体和液体杂质的方法，而不会使得到的洗涤聚合物显着变色。 本发明的方法包括以下步骤：（a）制备第一浆料，其中其固体组分包含从反应混合物浆料中回收的颗粒状亚芳基硫醚聚合物，并且其中其液体组分包括水和还原剂的混合物 代理人 （b）将第一浆料加热到至少约185℃（365°F）但低于颗粒状聚合物熔点的温度，以洗涤其中所含的聚合物; （c）将第一浆料冷却至低于约100℃（212°F）的温度，以形成第二浆料，其中其固体组分包含经洗涤的颗粒亚芳基硫醚聚合物; 和（d）从第二浆料中回收洗涤的颗粒状亚芳基硫醚聚合物。
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公开(公告)号：US4510316A
公开(公告)日：1985-04-09
申请号：US385756
申请日：1982-06-07
IPC分类号： C07C37/72 , C07C27/00 , C07C39/04 , C07C67/00 , C07D207/26 , C07D207/263 , C07D207/267
CPC分类号： C07D207/267
摘要： Phenol is extracted with a chlorinated aromatic extractant, such as p-dichlorobenzene, from an aqueous mixture containing phenol and N-methylpyrrolidone. In an embodiment of this invention the purified N-methylpyrrolidone is recycled for use in a poly(phenylene sulfide) polymerization process.
摘要翻译： 苯酚用含有苯酚和N-甲基吡咯烷酮的含水混合物用氯化芳族萃取剂如对二氯苯提取。 在本发明的一个实施方案中，纯化的N-甲基吡咯烷酮被再循环用于聚（苯硫醚）聚合方法中。
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6.发明授权Higher molecular weight arylene sulfide resin and process for its preparation 失效较高分子量的亚芳基硫醚树脂及其制备方法
公开(公告)号：US5110901A
公开(公告)日：1992-05-05
申请号：US580720
申请日：1990-09-11
IPC分类号： C08G75/02
CPC分类号： C08G75/0259
摘要： In a first embodiment, arylene sulfide resins are provided by contacting, in a polymerization mixture, during a polymerization process, reactants comprising: an alkali metal sulfide, an organic amide, an alkali metal carboxylate, water and a monomer source which comprises at least one dihaloaromatic compound. The amount of alkali metal carboxylate present during the polymerization process ranges from about 0.01 to about 0.03 mole per each mole of sulfur present in the resulting arylene sulfide resin. The total amount of water present during the polymerization process ranges from about 1.02 to about 2.1 moles per each mole of sulfur present in the resulting arylene sulfide resin.In a second embodiment, arylene sulfide resins are provided by contacting, in a polymerization mixture, during a polymerization process, reactants comprising: an alkali metal sulfide, an organic amide, an alkali metal carboxylate, water and a monomer source which comprises a mixture of at least one dihaloaromatic compound and at least one polyhaloaromatic compound having more than two halogen substituents per molecule. The ranges of the amount of alkali metal carboxylate present during the polymerization process and the total amount of water present during the polymerization process are identical to those amounts disclosed in the first embodiment. The amount of polyhaloaromatic compound initially present ranges from about 0.0001 to about 0.01 mole per each mole of dihaloaromatic compound present prior to the initiation of the polymerization process.
摘要翻译： 在第一个实施方案中，亚芳基硫醚树脂通过在聚合反应过程中使聚合反应中的反应物与碱金属硫化物，有机酰胺，碱金属羧酸盐，水和单体源接触来提供，所述反应物包括至少一种 二卤化合物。 在聚合过程中存在的碱金属羧酸盐的量为所得亚芳基硫醚树脂中存在的每摩尔硫的约0.01至约0.03摩尔。 在聚合过程中存在的水的总量范围为所得亚芳基硫醚树脂中存在的每摩尔硫的约1.02至约2.1摩尔。 在第二个实施方案中，亚芳基硫醚树脂是通过在聚合反应过程中使聚合反应中的反应物与碱金属硫化物，有机酰胺，碱金属羧酸盐，水和单体来源接触来提供的， 至少一种二卤代芳族化合物和每分子具有多于两个卤素取代基的至少一种多卤芳族化合物。 在聚合过程中存在的碱金属羧酸盐的量的范围和在聚合过程中存在的水的总量与第一实施方案中公开的量相同。 在开始聚合过程之前，存在的每摩尔二卤代芳族化合物最初存在的多卤代芳族化合物的量为约0.0001至约0.01摩尔。
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7.发明授权Recovery of poly(arylene sulfide ketone) and poly(arylene sulfide diketone) resins 失效回收聚（亚芳基硫醚酮）和聚（亚芳基硫醚二酮）树脂
公开(公告)号：US5091509A
公开(公告)日：1992-02-25
申请号：US459011
申请日：1989-12-29
申请人： Afif M. Nesheiwat , Jon F. Geibel
发明人： Afif M. Nesheiwat , Jon F. Geibel
CPC分类号： C08G75/0281 , C08G85/00
摘要： A poly(arylene sulfide ketone) or poly(arylene sulfide diketone) resin having improved handling characteristics is prepared by a process comprising preparing in a first enclosed vessel a slurry comprising a solid poly(arylene sulfide ketone) or poly(arylene sulfide diketone) resin and a liquid polar organic compound, and optionally water; then substantially liquifying the resin to form a mixture comprising substantially liquified resin and polar organic compound; then flashing the mixture into a second vessel having a pressure lower than the first vessel, thereby removing a portion of the polar organic compound and solidifying the resin.When the slurry further comprises water, the invention method optionally includes a venting step prior to the substantial liquification of the resin and/or a concentration step after the substantial liquification of the resin.
摘要翻译： 通过包括在第一封闭容器中制备包含固体聚（亚芳基硫醚酮）或聚（亚芳基硫醚二酮）树脂的浆料的方法制备具有改进的处理特性的聚（亚芳基硫醚酮）或聚（亚芳基硫醚二酮）树脂 和液体极性有机化合物，和任选的水; 然后基本上液化树脂以形成基本上液化的树脂和极性有机化合物的混合物; 然后将混合物闪蒸成具有低于第一容器的压力的第二容器，从而除去一部分极性有机化合物并固化树脂。 当浆料还包含水时，本发明方法任选地包括在树脂基本上液化之前的排气步骤和/或在树脂基本上液化之后的浓缩步骤。
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公开(公告)号：US4958004A
公开(公告)日：1990-09-18
申请号：US80283
申请日：1987-07-31
CPC分类号： C08G75/0259 , C08G75/0236 , C08G75/20
摘要： A process is provided for the production of aromatic sulfide/sulfone polymers which involves contacting under suitable polymerization reaction conditions: (1) at least one dihaloaromatic sulfone, (2) at least one organic amide, (3) at least one alkali metal hydrosulfide, (4) water, and (5) at least one member selected from the group consisting of (a) alkali metal carbonates and (b) mixtures of alkali metal carbonates with alkali metal hydroxides wherein said mixtures have at least about 0.5 mole percent alkali metal carbonate.
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公开(公告)号：US4801664A
公开(公告)日：1989-01-31
申请号：US149760
申请日：1988-01-29
申请人： Afif M. Nesheiwat , Guy Senatore , Fred T. Sherk
发明人： Afif M. Nesheiwat , Guy Senatore , Fred T. Sherk
CPC分类号： C08G75/0281 , C08G75/0277 , C08G75/0295
摘要： In one embodiment, a process is provided for treating virgin poly(arylene sulfide) resins, wherein a heated polymer slurry, comprising a virgin poly(arylene sulfide) resin and water is contacted by an acidic treating solution comprising at least an acidic component, wherein the amount of the acidic component in the acidic treating solution is less than the amount necessary to result in at least a partial curing of the virgin poly(arylene sulfide) resin. In a second embodiment, the process is provided for treating a virgin poly(arylene sulfide) resin, wherein the virgin poly(arylene sulfide) resin is slurried with an aqueous acidic treating solution comprising an acidic component and an aqueous component and the concentration of the acidic component in the aqueous acidic treating solution is less than the amount necessary to result in at least a partial curing of the virgin poly(arylene sulfide) resin. The polymer slurry is then heated to an elevated temperature, below the melting point of the virgin resin, while in the substantial absence of a gaseous oxidizing atmosphere.
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公开(公告)号：US5314972A
公开(公告)日：1994-05-24
申请号：US410686
申请日：1989-09-21
申请人： Afif M. Nesheiwat , John F. Geibel
发明人： Afif M. Nesheiwat , John F. Geibel
IPC分类号： C08J3/00 , C08G75/02 , C08G75/06 , C08F283/00
CPC分类号： C08G75/0281
摘要： In one embodiment, a process is provided for treating virgin arylene sulfide resins, wherein a heated polymer slurry, comprising a virgin arylene sulfide resin and water, is contacted by a buffer solution having a pH less than about 9.35 but greater than that necessary to result in at least a partial curing of the virgin arylene sulfide resin. In a further embodiment, a process is provided for treating a virgin arylene sulfide resin, wherein a virgin arylene sulfide resin is slurried in a buffer solution having a pH less than about 9.35 but greater than that necessary to result in at least a partial curing of the virgin arylene sulfide resin. The treating process of this invention is conducted at an elevated temperature, below the melting point of the virgin arylene sulfide resin, while in the substantial absence of a gaseous oxidizing atmosphere. The treated arylene sulfide resins are recovered from the polymer slurry in a manner which does not result in at least a partial curing of the treated resin.
摘要翻译： 在一个实施方案中，提供了一种用于处理原始亚芳基硫醚树脂的方法，其中包含原始亚芳基硫醚树脂和水的加热聚合物浆料与pH小于约9.35但大于所得结果所需的缓冲溶液接触 在原始亚芳基硫醚树脂的至少部分固化中。 在另一个实施方案中，提供了一种处理原始亚芳基硫醚树脂的方法，其中将原始亚芳基硫醚树脂在pH小于约9.35但大于导致至少部分固化所需的pH缓冲溶液中浆化 原始亚芳硫醚树脂。 本发明的处理方法在基本上没有气态氧化气氛的高温下，低于原始亚芳基硫醚树脂的熔点进行。 经处理的亚芳基硫醚树脂以不会导致经处理的树脂的至少部分固化的方式从聚合物浆料中回收。
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