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公开(公告)号:US12091331B2
公开(公告)日:2024-09-17
申请号:US17991124
申请日:2022-11-21
发明人: Lindy E. Dejarme , Kavitha Dasu , Russell R. Sirabian , Christopher F. Buurma , Jeffrey Ellis , Michael M. Miller , Dan Garbark , Nathan Bryant , John Tallarico , Joseph Casciano , Slawomir Winecki , David Holley , Joshua James , Keith Brown , Doug Hendry , Darwin Argumedo , Aaron Frank , Christopher Gordon Scheitlin
CPC分类号: C02F1/441 , B01J3/008 , B01J4/002 , C02F1/04 , C02F1/583 , C02F1/722 , C02F2101/36 , C02F2201/002
摘要: Per- and polyfluoroalkyl substances (PFAS) are destroyed by oxidation in supercritical conditions. PFAS in water can be concentrated and prepared for destruction in a pretreatment phase. Following annihilation of the PFAS in supercritical conditions to levels below 5 parts per trillion (ppt), the water effluent can be used to recover heat, returned to sub-critical conditions, and then released back into the environment.
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公开(公告)号:US11970409B2
公开(公告)日:2024-04-30
申请号:US17990765
申请日:2022-11-21
发明人: Lindy E. Dejarme , Kavitha Dasu , Russell R. Sirabian , Jeffrey Ellis , Dan Garbark , Nathan Bryant , John Tallarico , Joseph Casciano , Slawomir Winecki , David Holley , Joshua James , Keith Brown , Doug Hendry , Darwin Argumedo , Aaron Frank , Christopher Gordon Scheitlin , Michael M. Miller
CPC分类号: C02F1/441 , B01J3/008 , B01J4/002 , C02F1/04 , C02F1/583 , C02F1/722 , C02F2101/36 , C02F2201/002
摘要: Per- and polyfluoroalkyl substances (PFAS) are destroyed by oxidation in supercritical conditions. PFAS in water can be concentrated and prepared for destruction in a pretreatment phase. Following annihilation of the PFAS in supercritical conditions to levels below 5 parts per trillion (ppt), the water effluent can be used to recover heat, returned to sub-critical conditions, and then released back into the environment.
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公开(公告)号:US20230373824A1
公开(公告)日:2023-11-23
申请号:US18200506
申请日:2023-05-22
CPC分类号: C02F1/722 , C02F11/086 , C02F2101/36
摘要: Supercritical water oxidation (SCWO) is a destruction technology to quickly treat per- and polyfluoroalkyl substance (PFAS)-impacted groundwater, investigation derived waste, and other aqueous matrices such as landfill leachate and aqueous film forming foam. Laboratory-prepared and field-collected samples with inlet PFAS concentrations up to 50 parts per million were consistently destroyed to less than 70 parts per trillion for all PFAS, when running at the determined optimal operating conditions (≥600° C. and 3,500 pounds per square inch). We investigated the correlation between temperature and flowrate of the system, finding that reactor temperatures ≥450° C. destroys perfluorinated carbonic acids, but higher temperatures and specified conditions are necessary to destroy perfluorosulfonic acids. Using a higher density oxygen source also increases the throughput of a SCWO reactor, here up to 140 mL/min, without affecting PFAS destruction. Continuous 5-log reduction in the concentration of PFAS (99.999% destruction) is demonstrated for 3 hours at steady-state operation. The destruction efficiency is not impacted by the addition of co-contaminants such as petroleum and other organic hydrocarbons, and the SCWO process is successfully applied to waste streams without pretreatment. The treated effluent is largely comprised of complete combustion products including carbon dioxide, water, and the corresponding anion acids; hence, the treated liquid can be released back into the environment after neutralization.
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公开(公告)号:US11780753B2
公开(公告)日:2023-10-10
申请号:US17871907
申请日:2022-07-23
发明人: Lindy E. Dejarme , Kavitha Dasu , Russel R. Sirabian , Jeffrey Ellis , Dan Garbark , Nathan Bryant , John Tallarico , Joseph Casciano , Slawomir Winecki , David Holley , Joshua James , Keith Brown , Doug Hendry , Darwin Argumedo , Aaron Frank , Christopher Gordon Scheitlin , Michael M. Miller , Matthew Vaughan
IPC分类号: C02F1/44 , C02F1/04 , C02F1/72 , B01J4/00 , C02F101/36
CPC分类号: C02F1/441 , B01J4/002 , C02F1/04 , C02F1/722 , C02F2101/36 , C02F2201/002
摘要: Per- and polyfluoroalkyl substances (PFAS) are destroyed by oxidation in supercritical conditions. PFAS in water can be concentrated and prepared for destruction in a pretreatment phase. Following annihilation of the PFAS in supercritical conditions to levels below 5 parts per trillion (ppt), the water effluent can be used to recover heat, returned to sub-critical conditions, and then released back into the environment.
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公开(公告)号:US11891323B2
公开(公告)日:2024-02-06
申请号:US17883600
申请日:2022-08-09
发明人: Stephen H. Rosansky , Michael Miller , Patrick Norris , Darwin Argumedo , Douglas Hendry , Ian Haggerty , Keith Brown , Joshua James , Joseph Casciano , Slawomir Winecki , Vivek Lal , Tom McGuinness
IPC分类号: B01D61/02 , B01D61/08 , B01D61/10 , C02F1/02 , C02F1/38 , C02F1/44 , C02F1/52 , C02F1/72 , C02F101/36 , C02F103/06 , C02F9/00 , B04C5/04 , B04C5/081 , B04C5/085 , B04C5/20 , C04B35/12 , C04B35/622
CPC分类号: C02F9/00 , B01D61/025 , B01D61/08 , B01D61/10 , B04C5/04 , B04C5/081 , B04C5/085 , B04C5/20 , C04B35/12 , C04B35/62222 , B01D2311/08 , B01D2311/103 , B01D2311/12 , B01D2311/2634 , B01D2311/2642 , B01D2311/2649 , B01D2311/2676 , B01D2313/221 , C02F1/02 , C02F1/38 , C02F1/441 , C02F1/52 , C02F1/72 , C02F2101/36 , C02F2103/06 , C02F2303/10 , C04B2235/9692
摘要: Per- and polyfluoroalkyl substances (PFAS) are destroyed by oxidation in supercritical conditions. PFAS in water is concentrated in a reverse osmosis step and salt from the resulting solution is removed in supercritical conditions prior to destruction of PFAS in supercritical conditions.
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公开(公告)号:US20240182341A1
公开(公告)日:2024-06-06
申请号:US18408471
申请日:2024-01-09
发明人: Stephen H. Rosansky , Michael Miller , Patrick Norris , Darwin Argumedo , Douglas Hendry , Ian Haggerty , Keith Brown , Joshua James , Joseph Casciano , Slawomir Winecki , Vivek Lal , Tom McGuinness
IPC分类号: C02F9/00 , B01D61/02 , B01D61/08 , B01D61/10 , B04C5/04 , B04C5/081 , B04C5/085 , B04C5/20 , C02F1/02 , C02F1/38 , C02F1/44 , C02F1/52 , C02F1/72 , C02F101/36 , C02F103/06 , C04B35/12 , C04B35/622
CPC分类号: C02F9/00 , B01D61/025 , B01D61/08 , B01D61/10 , B04C5/04 , B04C5/081 , B04C5/085 , B04C5/20 , C04B35/12 , C04B35/62222 , B01D2311/08 , B01D2311/103 , B01D2311/1031 , B01D2311/12 , B01D2311/2634 , B01D2311/2642 , B01D2311/2649 , B01D2311/2676 , B01D2313/221 , C02F1/02 , C02F1/38 , C02F1/441 , C02F1/52 , C02F1/72 , C02F2101/36 , C02F2103/06 , C02F2303/10 , C04B2235/9692
摘要: Per- and polyfluoroalkyl substances (PFAS) are destroyed by oxidation in supercritical conditions. PFAS in water is concentrated in a reverse osmosis step and salt from the resulting solution is removed in supercritical conditions prior to destruction of PFAS in supercritical conditions.
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