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公开(公告)号:US3897508A
公开(公告)日:1975-07-29
申请号:US40488973
申请日:1973-10-10
发明人: TKATCHENKO IGOR
IPC分类号: C07C2/40 , B01J31/26 , C07C1/00 , C07C2/38 , C07C2/46 , C07C2/52 , C07C11/21 , C07C13/20 , C07C13/64 , C07C67/00 , C08F4/26 , C07C3/00
CPC分类号: B01J31/30 , B01J31/1815 , B01J31/20 , B01J31/26 , B01J2231/323 , B01J2231/326 , B01J2531/26 , B01J2531/42 , B01J2531/842 , C07C2/52 , C07C2527/06 , C07C2531/18 , C07C2531/20 , C07C2601/16 , C07C13/20
摘要: A process for the dimerization or codimerization of diolefins in the liquid phase in an inert solvent solution using a catalyst comprising a complex obtained by reacting the alkali metal or alkaline earth metal salt of tricarbonyl nitrosyl ferrate anion with a metallic halogen or pseudohalogen or complex thereof is disclosed.
摘要翻译: 使用包含通过使三羰基亚硝酰基高铁酸盐阴离子的碱金属或碱土金属盐与金属卤素或假卤素或其络合物反应获得的络合物的催化剂在惰性溶剂溶液中使液相中二烯烃二聚或共二聚的方法是: 披露
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公开(公告)号:US3917730A
公开(公告)日:1975-11-04
申请号:US40488873
申请日:1973-10-10
发明人: TKATCHENKO IGOR
IPC分类号: C07C2/40 , B01J31/18 , B01J31/20 , C07C1/00 , C07C2/02 , C07C2/38 , C07C2/52 , C07C11/21 , C07C13/20 , C07C67/00 , C07C3/10
CPC分类号: B01J31/1805 , B01J31/20 , B01J2531/842 , B01J2531/845 , C07C2/02 , C07C2/52 , C07C2531/20 , C07C2601/16 , C07C13/20
摘要: A liquid phase dimerization or codimerization of diolefins is effected by maintaining the diolefins in solution in an inert solvent in contact with a catalyst which is the product of the interaction between two metal complexes, each of which is a nitrosyl and/or carbonyl ligand, said interaction product containing at least one nitrosyl group.
摘要翻译: 通过将溶液中的二烯烃保持在与催化剂接触的惰性溶剂中来实现二烯烃的液相二聚或共二聚作用,所述催化剂是两种金属配合物(其各自为亚硝酰基和/或羰基配体)之间的相互作用的产物, 包含至少一个亚硝酰基的相互作用产物。
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