公开(公告)号：US4754023A

公开(公告)日：1988-06-28

申请号：US821213

申请日：1986-01-23

申请人： Athanassios Tzikas ,  Herbert Seiler ,  Peter Scheibli

发明人： Athanassios Tzikas ,  Herbert Seiler ,  Peter Scheibli

IPC分类号： C09B62/04 ,  C09B62/44 ,  C09B62/503 ,  C09B62/505 ,  C09B62/51 ,  C09B62/513 ,  C09B62/517 ,  C09B62/06 ,  C09B62/08 ,  C09B62/10

CPC分类号： C09B62/4403

摘要： A reactive dye of the formula ##STR1## in which: F is a radical selected from the group consisting of metal-free or metal-containing monoazo or disazo dyes containing at least one --SO.sub.3 H group, anthraquinone dyes, sulfophthalocyanine dyes, formazan dyes, phenazine dyes, oxazine dyes and nitroaryl dyes,R is hydrogen, C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted with --COOH or --SO.sub.3 H, cyanoethyl, or hydroxyethyl,X is fluorine, chlorine, bromine, --SO.sub.3 H, phenylsulfonyl or C.sub.1 -C.sub.4 -alkylsulfonyl,p is 1 or 2 andA is a radical of the formula ##STR2## in which: Y is chlorine, bromine, fluorine, --OH, --OSO.sub.3 H, --O-acyl, --CN, --COOH, --COO--C.sub.1 -C.sub.4 -alkyl, --CONH.sub.2 or --SO.sub.2 --Z,the group designated "alk" is a straight or branched polymethylene radical having 2 to 6 carbon atoms,V is ##STR3## hydrogen or C.sub.1 -C.sub.4 -alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.2 -alkoxy, carboxyl, sulfo, halogen or hydroxy,Z is .beta.-halogenoethyl, vinyl or .beta.-acetoxyethyl, or A is a radical of the formulae ##STR4## in all of which R' is C.sub.1-6 -alkyl or hydrogen, Z is as defined above, o is 0 to 6, and m is 2 to 6.

摘要翻译： 式“IMAGE”的活性染料，其中：F是选自含有至少一个-SO 3 H基团的无金属或含金属单偶氮或双偶氮染料的基团，蒽醌染料，磺酞菁染料，甲an染料， 吩嗪染料，恶嗪染料和硝基芳基染料，R为氢，未被取代或被-COOH或-SO 3 H取代的C 1 -C 4烷基，氰乙基或羟乙基，X为氟，氯，溴，-SO 3 H，苯磺酰基或C 1 -C 4 - 烷基磺酰基，p是1或2，A是下式的基团，其中：Y是氯，溴，氟，-OH，-OSO 3 H，-O-酰基，-CN，-COOH，-COO- C 1 -C 4 - 烷基，-CONH 2或-SO 2 - Z，被称为“alk”的基团是具有2至6个碳原子的直链或支链多亚甲基，V是氢或未被取代的C 1 -C 4烷基， 被C 1 -C 2烷氧基，羧基，磺基，卤素或羟基取代，Z是β-卤代乙基，乙烯基或β-乙酰氧基乙基，或A是下式的基团： 其中R'为C 1-6 - 烷基或氢，Z如上所定义，o为0至6，m为2至6，> 。

公开(公告)号：US4298536A

公开(公告)日：1981-11-03

申请号：US33404

申请日：1979-04-26

申请人： Athanassios Tzikas

发明人： Athanassios Tzikas

IPC分类号： C07C225/34 ,  C09B1/22 ,  C07C97/24

CPC分类号： C09B1/22

摘要： A process for the manufacture of 1,2-diaminoanthraquinone, which comprises reacting 1-nitro-2-acetylaminoanthraquinone with hydrazine or hydroxylamine, or with derivatives thereof, in protic solvents.

摘要翻译： 制备1,2-二氨基蒽醌的方法，其包括使1-硝基-2-乙酰氨基蒽醌与肼或羟胺或其衍生物在质子溶剂中反应。

公开(公告)号：US4284770A

公开(公告)日：1981-08-18

申请号：US36622

申请日：1979-05-07

申请人： Athanassios Tzikas

发明人： Athanassios Tzikas

IPC分类号： C09B1/46 ,  C09B1/467 ,  C09B1/48 ,  C09B1/54 ,  C09B1/58 ,  C09B3/00 ,  C09B5/00 ,  C09B5/24 ,  C07D251/48 ,  C07D401/12 ,  C07D403/12 ,  C07D413/12

CPC分类号： C09B5/00 ,  C09B1/467 ,  C09B1/48 ,  C09B1/545 ,  C09B1/585 ,  C09B3/00

摘要： A process for the manufacture of vat dyes of the formula ##STR1## wherein each of A.sub.1 and A.sub.2 independently is a vattable radical, which comprises reacting compounds of the formula ##STR2## wherein X is halogen and A.sub.1 and A.sub.2 are as defined for formula (1), in a basic medium with hydrazine compounds.

摘要翻译： 制备式（1）的还原染料的方法，其中A1和A2中的每一个独立地是可以包含的基团，其包括使下式的化合物（2）其中X是卤素和A1和A2 在具有肼化合物的碱性介质中如式（1）所定义。

公开(公告)号：US4202827A

公开(公告)日：1980-05-13

申请号：US935035

申请日：1978-08-18

申请人： Athanassios Tzikas

发明人： Athanassios Tzikas

IPC分类号： C07C243/22 ,  C07C67/00 ,  C07C241/00 ,  C07D231/54 ,  C07C109/04 ,  C07C103/75

CPC分类号： C07D231/54 ,  C07C241/02 ,  C07C243/22

摘要： A process for the production of 1-anthraquinonyl hydrazines of the formula ##STR1## wherein X is hydrogen or --NH--NH.sub.2, which comprises reacting 1-nitroanthraquinones of the formula ##STR2## wherein Z is hydrogen or nitro, in aprotic dipolar solvents, with hydrazine or hydrazine hydrate, at normal or slightly elevated temperature, to give 1-anthraquinonyl hydrazines of the formula (1).

摘要翻译： 制备式（1）的1-蒽醌基肼的方法，其中X是氢或-NH-NH 2，其包括使式（1）的1-硝基蒽醌反应，其中Z是氢 或硝基，在非质子偶极溶剂中，与肼或水合肼反应，在正常或轻微升高的温度下，得到式（1）的1-蒽醌基肼。

公开(公告)号：US20130283546A1

公开(公告)日：2013-10-31

申请号：US13816966

申请日：2011-06-22

申请人： Athanassios Tzikas ,  Georg Roentgen ,  Jean-Francois Landre ,  Remo Codemo

发明人： Athanassios Tzikas ,  Georg Roentgen ,  Jean-Francois Landre ,  Remo Codemo

IPC分类号： D06P1/00

CPC分类号： D06P1/0096 ,  C09B67/0057 ,  C09B67/0073 ,  D06P1/0032 ,  D06P1/38 ,  D06P1/382 ,  D06P1/384 ,  D06P3/66 ,  D06P3/663 ,  D06P3/666

摘要： Dye mixtures, comprising least one yellow dye of the formula (1), at least one yellow dye of the formula (2), at least one red dye of the formula (3), at least one blue dye of the formula (4), wherein the radicals have the definitions given in the claims, are suitable especially for the trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.

摘要翻译： 包含至少一种式（1）的黄色染料，至少一种式（2）的黄色染料，至少一种式（3）的红色染料，至少一种式（4）的蓝色染料的染料混合物， 其中基团具有权利要求中给出的定义，特别适用于纤维素纤维材料的三色染色或印刷，并且具有良好的再现性和良好的全面牢度特性的产量染色或印花。

公开(公告)号：US20120117737A1

公开(公告)日：2012-05-17

申请号：US13384350

申请日：2010-06-30

申请人： Athanassios Tzikas ,  Herbert Klier ,  Georg Roentgen

发明人： Athanassios Tzikas ,  Herbert Klier ,  Georg Roentgen

IPC分类号： D06P1/38 ,  C09B43/00 ,  C09B62/00 ,  C09B31/14

CPC分类号： C09B62/4415 ,  C09D11/328

摘要： Reactive dyes of the formula (1) wherein B is an aliphatic bridging member, G is a sulfo naphthalene group or a sulfo benzene group of the formula (2a) or a pyridone radical of the formula (2b), R1, R2, R3 and R4 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, (R5)h denotes h identical or different substituents selected from the group sulfo, C1-C4alkyl and C1-C4alkoxy, R6 is hydrogen, sulfo, halogen, carboxy, C1-C4alkyl, C1-C4alkoxy or a fibre-reactive group Z1 of the formula —SO2—Y (3a), —NH—CO—(CH2)l—SO2—Y (3b), —CONH—(CH2)m—SO2—Y (3c), —NH—CO—CH(Hal)-CH2-Hal (3d) or —NH—CO—C(Hal)=CH2 (3e), R7 is amino, C1-C4alkyl or a fibre-reactive group Z2 of the formula —NH—(CH2)nSO2—Y (3a), (R8)j denotes j identical or different substituents selected from the group sulfo, C2-C4alkanoylamino, ureido, C1-C4alkyl and C1-C4alkoxy, R9 is hydrogen, C1-C4alkyl or C1-C4alkoxy, R10 is hydrogen or C1-C4alkyl, R11 is hydrogen, cyano, carbamoyl or sulfomethyl, and R12 is hydrogen, C1-C4alkyl, or phenyl which is unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, ureido, halogen or sulfo, X1 and X2 are halogen, Hal is chlorine or bromine, h and j are each independently of the other a number 0, 1 or 2; k is a number 1, 2 or 3; I, m and n are each independently of the other a number 2, 3 or 4, and Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, with the proviso that the dye of formula (1) contains at least one fibre-reactive group Z1 or Z2 are suitable for dyeing cellulosic or amide-group-containing fibre materials.

摘要翻译： 式（1）的反应性染料，其中B是脂族桥连构件，G是式（2a）的磺基萘基或磺基苯基或式（2b）的吡啶酮基，R1，R2，R3和 R 4各自独立地为氢或未取代的或取代的C 1 -C 4烷基，（R 5）h表示相同或不同的选自磺基，C 1 -C 4烷基和C 1 -C 4烷氧基的取代基，R 6是氢，磺基，卤素，羧基， C1-C4烷基，C1-C4烷氧基或式-SO2-Y（3a）的纤维反应性基团Z1，-NH-CO-（CH2）1-SO2-Y（3b），-CONH-（CH2）m- SO2-Y（3c），-NH-CO-CH（Hal）-CH2-Hal（3d）或-NH-CO-C（Hal）= CH2（3e），R7是氨基，C1-C4烷基或纤维 - 式-NH-（CH2）nSO2-Y（3a）的反应性基团Z2，（R8）j表示j个相同或不同的选自磺基，C 2 -C 4烷酰基氨基，脲基，C 1 -C 4烷基和C 1 -C 4烷氧基的取代基，R 9 是氢，C 1 -C 4烷基或C 1 -C 4烷氧基，R 10是氢或C 1 -C 4烷基，R 11是氢 氰基，氨基甲酰基或磺甲基，R12为氢，C1-C4烷基或未被取代或被C1-C4烷基，C1-C4烷氧基，C2-C4烷酰基氨基，脲基，卤素或磺基取代的苯基，X1和X2为卤素，Hal为 氯或溴，h和j各自独立地为数字0,1或2; k是数字1,2或3; I，m和n各自独立地为数2，3或4，Y为乙烯基或基团-CH 2 -CH 2 -U，U为在碱性条件下可除去的基团，条件是式 （1）含有至少一种纤维反应性基团Z 1或Z 2适于染色含纤维素或含酰胺基的纤维材料。

公开(公告)号：US20100251490A1

公开(公告)日：2010-10-07

申请号：US12739079

申请日：2008-10-07

申请人： Athanassios Tzikas ,  Thomas Verdugo ,  Georg Roentgen

发明人： Athanassios Tzikas ,  Thomas Verdugo ,  Georg Roentgen

IPC分类号： C07D498/04 ,  C09B62/00

CPC分类号： C09B62/5033 ,  C09B62/465 ,  C09B67/004

摘要： Reactive dyes of the formula (1) in which Q1 is hydrogen, halogen or a radical of the formula R1, R2 and R3 independently of one another are hydrogen or C1-C4alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato, and R1 in formula (1) and R1 in formula (2a) have identical or different meanings and R2 in formula (1) and R2 in formula (2a) have identical or different meanings, (R4)0-1 and (R5)0-1 independently of one another are 0 or 1 identical or different substituents from the group consisting of C1-C4alkyl, C1-C4alkoxy, halogen and sulfo, A is hydrogen or C1-C4alkyl which is unsubstituted or substituted by hydroxyl, sulfo, carboxyl or sulfato, phenyl which is unsubstituted or substituted by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, carbamoyl, sulfo or halogen, phenyl-C1-C2alkylene which is unsubstituted or substituted in the phenyl ring by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, hydroxyl, carboxyl, sulfo, carbamoyl or halogen, or C5-C7cycloalkyl which is unsubstituted or substituted by C1-C4alkyl, B is a C2-C12alkylene radical which can be interrupted by 1, 2 or 3 members from the group consisting of —NH—, —N(CH3)— or —O— and is unsubstituted or substituted by hydroxyl, sulfo, sulfato, cyano or carboxyl, a C5-C7cycloalkylene radical or C1-C2alkylene-C5-C7cycloalkylene radical which are unsubstituted or substituted in the cycloalkylring by C1-C4alkyl, C1-C2alkylenephenylene radical or phenylene radical which are unsubstituted or substituted in the phenyl ring by C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino, sulfo, halogen or carboxyl, V1 and V2 independently of one another are halogen, T is a radical of the formula —CO—(CH2)mSO2—Y   (3a), —CO—CH(Hal)—CH2—Hal   (3b) or —CO—C(Hal)=CH2   (3c), Hal is halogen, X is hydroxyl or Y, Y is vinyl or a radical —CH2—CH2—U and U is a group which can be split off under alkaline conditions, and m is the number 2, 3 or 4. are suitable for dyeing widely varying fibre materials, in particular cellulosic fibre materials, and produce dyeings with good allround properties.

公开(公告)号：US20100024138A1

公开(公告)日：2010-02-04

申请号：US12567172

申请日：2009-09-25

申请人： Athanassios Tzikas ,  Georg Roentgen

发明人： Athanassios Tzikas ,  Georg Roentgen

IPC分类号： C09B62/01 ,  C09B39/00 ,  C09D11/00 ,  B05D5/06

CPC分类号： C09B62/4415 ,  C09B67/0057

摘要： Dye mixtures comprising at least one dye of formula together with at least one dye of formula wherein the radicals indicated in the formulae are defined in accordance with the claims, are suitable for dyeing or printing cellulosic fibre materials with good build-up behaviour and yield dyeings of a deep shade having good fastness properties.

摘要翻译： 包含至少一种式的染料的染料混合物与至少一种下式的染料一起使用，其中式中所示的基团根据权利要求书定义，适用于染色或印刷具有良好聚集行为和产率染色的纤维素纤维材料 具有良好的牢度特性的深色阴影。

公开(公告)号：US20070294842A1

公开(公告)日：2007-12-27

申请号：US11667616

申请日：2005-11-02

申请人： Athanassios Tzikas ,  Georg Roentgen ,  Herbert Klier

发明人： Athanassios Tzikas ,  Georg Roentgen ,  Herbert Klier

IPC分类号： C09B62/09 ,  C07D251/50 ,  C09B62/475 ,  C09D11/02

CPC分类号： C09B62/4415

摘要： Reactive dyes of formula (1) wherein R1 is hydrogen or unsubstituted or substituted C1-C4alkyl, R2 is hydrogen; C1-C4alkyl; C1-C4alkoxy unsubstituted or substituted by sulfato, hydroxy or by C1-C4alkoxy; halogen; carboxy or sulfo, R3 is hydrogen; C1-C4alkyl; C1-C4alkoxy unsubstituted or substituted by sulfato, hydroxy or by C1-C4alkoxy; halogen; nitro; C2-C4alkanoylamino; ureido; carboxy or sulfo, (R4)k denotes k identical or different substituents selected from the group halogen, C1-C4-alkyl, C1-C4alkoxy, carboxy and sulfo, X is halogen and V is a radical of formula (2a), 2(b) wherein R5 is unsubstituted or substituted C1-C4alkyl, (R6)l denotes I identical or different substituents from the group C1-C4alkyl, C1-C4alkoxy and sulfo, and I is the number O, 1 or 2, Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)═CH2 group, Hal is halogen and k is the number O, 1 , 2 or 3, are suitable especially for dyeing cotton and yield dyeings having good allround fastness properties.

摘要翻译： 式（1）的反应性染料，其中R 1是氢或未取代或取代的C 1 -C 4烷基，R 2， / SUB>是氢; C 1 -C 4烷基; 未取代或被硫酸酯，羟基或C 1 -C 4烷氧基取代的C 1 -C 4烷氧基; 卤素; 羧基或磺基，R 3是氢; C 1 -C 4烷基; 未取代或被硫酸酯，羟基或C 1 -C 4烷氧基取代的C 1 -C 4烷氧基; 卤素; 硝基 C 2 -C 4烷酰基氨基; 脲基 羧基或磺基，（R 4）N表示k个相同或不同的选自卤素，C 1 -C 4烷基的取代基 C 1 -C 4烷基，C 1 -C 4烷氧基，羧基和磺基，X是卤素，V是式（2a），2（b）的基团， 其中R 5是未取代或取代的C 1 -C 4烷基，（R 6 N）1 表示I相同或不同的取代基C 1 -C 4烷基，C 1 -C 4烷基，C 1 -C 4烷基，C 1 -C 4烷基， 烷氧基和磺基，I是数字O，1或2，Y是乙烯基或-CH 2 CH 2 -CH 2 - 基团，U是 基团，其在碱性条件下是可除去的，Q是-CH（Hal）-CH 2 H 2 - 或-C（Hal）-CH 2 H 2基团，Hal是卤素， k是数字O，1,2或3，特别适用于染色棉和具有良好全面牢度性能的产量染色。

公开(公告)号：US20060207038A1

公开(公告)日：2006-09-21

申请号：US10551319

申请日：2004-03-24

申请人： Athanassios Tzikas ,  Georg Roentgen

发明人： Athanassios Tzikas ,  Georg Roentgen

IPC分类号： C09B62/00

CPC分类号： C09B62/4415 ,  C09B67/0057

摘要： Dye mixtures comprising at least one dye of formula together with at least one dye of formula wherein the radicals indicated in the formulae are defined in accordance with the claims, are suitable for dyeing or printing cellulosic fibre materials with good build-up behaviour and yield dyeings of a deep shade having good fastness properties.

摘要翻译： 包含至少一种式的染料的染料混合物与至少一种下式的染料一起使用，其中式中所示的基团根据权利要求书定义，适用于染色或印刷具有良好聚集行为和产率染色的纤维素纤维材料 具有良好的牢度特性的深色阴影。