Triazinyl reactive dyestuffs in which triazinyl group is further
substituted with a beta-chloroethylsulfonyl- or
vinylsulfonylbutyrylamino moiety
    1.
    发明授权
    Triazinyl reactive dyestuffs in which triazinyl group is further substituted with a beta-chloroethylsulfonyl- or vinylsulfonylbutyrylamino moiety 失效
    三嗪基活性染料,其中三嗪基进一步被β-氯乙基磺酰基或乙烯基磺酰基丁酰氨基部分取代

    公开(公告)号:US4801694A

    公开(公告)日:1989-01-31

    申请号:US73323

    申请日:1987-07-13

    CPC分类号: C09B62/02 C09B62/4403

    摘要: Reactive dyes of the formula ##STR1## in which D is the radical of an organic dye of the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthrone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, R is hydrogen or substituted or unsubstituted C.sub.1-4 -alkyl, X is a substituent which is detachable as an anion, B is a radical of the formula ##STR2## R.sub.1 and R.sub.2, independently of each other, are hydrogen or substituted or unsubstituted C.sub.1-4 -alkyl or phenyl, A is a substituted or unsubstituted aliphatic or aromatic bridge member, Y is a --CO--Z or --SO.sub.2 --Z radical, Z is an aliphatic, aromatic or heterocyclic reactive radical, and n is 1 or 2, are suitable for dyeing or printing cellulose-containing and nitrogen-containing materials and in high dyeing yield produce dyeings and prints having good fastness properties.

    摘要翻译: 式(1)的活性染料其中D是单偶氮,多偶氮,金属络合物偶氮,蒽醌,酞菁,甲an,偶氮甲碱,二恶嗪,吩嗪,二苯乙烯,三苯基甲烷,呫吨,噻吨酮的有机染料的基团 硝基芳基,萘醌,芘醌或苝四碳酰亚胺系列,R为氢或取代或未取代的C1-4 - 烷基,X为可作为阴离子取代的取代基,B为下式的基团:R1和R2,独立地为 彼此是氢或取代或未取代的C1-4 - 烷基或苯基,A是取代或未取代的脂族或芳族桥连构件,Y是-CO-Z或-SO2-Z基团,Z是脂族,芳族或 杂环反应性基团,n为1或2,适用于染色或印刷含纤维素和含氮材料,并且在高染色率下产生具有良好牢度性能的染色和印花。

    Reactive dyestuffs comprising a triazine moiety and a vinylsulfonyl
moiety both being linked by a substituted alkylene bridge member
    2.
    发明授权
    Reactive dyestuffs comprising a triazine moiety and a vinylsulfonyl moiety both being linked by a substituted alkylene bridge member 失效
    包含三嗪部分和乙烯基磺酰基部分的反应性染料都被取代的亚烷基桥连接

    公开(公告)号:US4754023A

    公开(公告)日:1988-06-28

    申请号:US821213

    申请日:1986-01-23

    CPC分类号: C09B62/4403

    摘要: A reactive dye of the formula ##STR1## in which: F is a radical selected from the group consisting of metal-free or metal-containing monoazo or disazo dyes containing at least one --SO.sub.3 H group, anthraquinone dyes, sulfophthalocyanine dyes, formazan dyes, phenazine dyes, oxazine dyes and nitroaryl dyes,R is hydrogen, C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted with --COOH or --SO.sub.3 H, cyanoethyl, or hydroxyethyl,X is fluorine, chlorine, bromine, --SO.sub.3 H, phenylsulfonyl or C.sub.1 -C.sub.4 -alkylsulfonyl,p is 1 or 2 andA is a radical of the formula ##STR2## in which: Y is chlorine, bromine, fluorine, --OH, --OSO.sub.3 H, --O-acyl, --CN, --COOH, --COO--C.sub.1 -C.sub.4 -alkyl, --CONH.sub.2 or --SO.sub.2 --Z,the group designated "alk" is a straight or branched polymethylene radical having 2 to 6 carbon atoms,V is ##STR3## hydrogen or C.sub.1 -C.sub.4 -alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.2 -alkoxy, carboxyl, sulfo, halogen or hydroxy,Z is .beta.-halogenoethyl, vinyl or .beta.-acetoxyethyl, or A is a radical of the formulae ##STR4## in all of which R' is C.sub.1-6 -alkyl or hydrogen, Z is as defined above, o is 0 to 6, and m is 2 to 6.

    摘要翻译: 式“IMAGE”的活性染料,其中:F是选自含有至少一个-SO 3 H基团的无金属或含金属单偶氮或双偶氮染料的基团,蒽醌染料,磺酞菁染料,甲an染料, 吩嗪染料,恶嗪染料和硝基芳基染料,R为氢,未被取代或被-COOH或-SO 3 H取代的C 1 -C 4烷基,氰乙基或羟乙基,X为氟,氯,溴,-SO 3 H,苯磺酰基或C 1 -C 4 - 烷基磺酰基,p是1或2,A是下式的基团,其中:Y是氯,溴,氟,-OH,-OSO 3 H,-O-酰基,-CN,-COOH,-COO- C 1 -C 4 - 烷基,-CONH 2或-SO 2 - Z,被称为“alk”的基团是具有2至6个碳原子的直链或支链多亚甲基,V是氢或未被取代的C 1 -C 4烷基, 被C 1 -C 2烷氧基,羧基,磺基,卤素或羟基取代,Z是β-卤代乙基,乙烯基或β-乙酰氧基乙基,或A是下式的基团: 其中R'为C 1-6 - 烷基或氢,Z如上所定义,o为0至6,m为2至6,>

    Reactive dyes, process for their preparation and use thereof
    4.
    发明授权
    Reactive dyes, process for their preparation and use thereof 失效
    活性染料,其制备方法和用途

    公开(公告)号:US4631065A

    公开(公告)日:1986-12-23

    申请号:US767246

    申请日:1985-08-20

    CPC分类号: C09B62/02 Y10S8/918

    摘要: The invention relates to reactive dyes of the formula ##STR1## wherein D is the radical of a dye of the monoazo or polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, each of R.sub.1 and R.sub.2 independently is hydrogen or an unsubstituted or substituted C.sub.1 -C.sub.4 alkyl radical, X.sub.1 is an unsubstituted or substituted aminofluoro-s-triazine radical, and X.sub.2 is a heterocyclic reactive radical which is attached direct to the radical D through the --N(R.sub.2) bridge member, excepting an unsubstituted or substituted aminofluoro-s-triazine.These dyes are particularly suitable for dyeing and printing cellulosic fibre material by the cold pad-batch method and give dyeings and prints of good fastness properties and high tinctorial strength.

    摘要翻译: 本发明涉及式(1)的活性染料,其中D是单偶氮或多偶氮,金属络合物偶氮,蒽醌,酞菁,甲an,偶氮甲碱,二恶嗪,吩嗪,二苯乙烯,三苯甲烷,呫吨的染料的基团 ,噻吨酮,硝基芳基,萘醌,芘醌或苝四碳酰亚胺系列,R 1和R 2各自独立地为氢或未取代或取代的C 1 -C 4烷基,X 1为未取代或取代的氨基氟三嗪基,X 2为杂环反应性基团 除了未取代或取代的氨基氟三嗪以外,它直接通过-N(R2)桥连接在基团D上。 这些染料特别适用于通过冷垫分批法对纤维素纤维材料进行染色和印花,并提供良好的牢度性能和高着色强度的染色和印花。

    Process for the staining of wood with aqueous wood stains
    5.
    发明授权
    Process for the staining of wood with aqueous wood stains 有权
    用木材污渍染色木材的方法

    公开(公告)号:US06630002B2

    公开(公告)日:2003-10-07

    申请号:US09850493

    申请日:2001-05-07

    IPC分类号: D06P362

    CPC分类号: C09D15/00

    摘要: The present invention relates to a process for the staining of wood, which comprises treating the unstained wood with an aqueous preparation comprising a) at least one dye, and b) at least one dye stabilizer of the formula (I) or (II)  in which G1 and G2, independently of one another, are C1-C4alkyl or together are pentamethylene, Z1 and Z2 are methyl, or Z1 and Z2 form a bridging member which is unsubstituted or substituted by an ester, ether, hydroxyl, oxo, cyanohydrin, amido, amino, carboxyl or urethane radical, E is oxyl or hydroxyl, and X is an inorganic or organic anion, and the total number of cations h corresponds to the total number of anions j, to a wood stain comprising a dye and a dye stabilizer of the formula (I) or (II), and to the use of this wood stain for the staining of wood.

    摘要翻译: 本发明涉及木材染色方法,其包括用含有a)至少一种染料的水性制剂处理未染色的木材,和b)至少一种式(I)或(II)的染料稳定剂,其中G 1和 G2彼此独立地是C1-C4烷基或一起是五亚甲基,Z1和Z2是甲基,或Z1和Z2形成未被取代或被酯,醚,羟基,氧代,羟腈,酰氨基,氨基 ,羧基或氨基甲酰基,E是氧基或羟基,X是无机或有机阴离子,并且阳离子总数h对应于阴​​离子总数j,包括染料和染料稳定剂的木材染色剂 式(I)或(II),以及该木材染色剂用于木材染色的用途。

    Process for printing cellulosic fibres with reactive dye and C.sub.3-18
aliphatic carboxylate salt fixing agent
    7.
    发明授权
    Process for printing cellulosic fibres with reactive dye and C.sub.3-18 aliphatic carboxylate salt fixing agent 失效
    用活性染料和C3-18脂肪族羧酸盐固定剂印刷纤维素纤维的方法

    公开(公告)号:US4647285A

    公开(公告)日:1987-03-03

    申请号:US778110

    申请日:1985-09-20

    摘要: The invention relates to a process for printing cellulosic fibres or cellulose-containing blend fibres with reactive dyes or dye mixtures which contain a reactive dye and subsequent fixation, which comprises printing these materials with a print paste containing at least one water-soluble reactive dye of the formulaD--(X).sub.m (1)in which D is the radical of an organic dye of the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, nitroaryl, dioxazine, phenazine or stilbene series, X is a fibre-reactive radical of the aliphatic, aromatic or heterocyclic series which is bonded to the radical D either directly or via a bridge member and m is 1, 2, 3, 4, 5 or 6, and salts of aliphatic carboxylic acids having 3 to 18 carbon atoms, and subsequently fixing the print; and to the print pastes used and to their use for printing textile materials.

    摘要翻译: 本发明涉及一种用活性染料或染料混合物印刷含纤维素纤维或含纤维素的共混纤维的方法,该活性染料或染料混合物含有活性染料和随后的固定,其包括用含有至少一种水溶性活性染料 其中D是单偶氮,多偶氮,金属络合物偶氮,蒽醌,酞菁,甲an,偶氮甲碱,硝基芳基,二恶嗪,吩嗪或二苯乙烯系列的有机染料的基团的式D-(X)m(1) 脂肪族,芳香族或杂环系列的纤维反应性基团直接或通过桥连构件与基团D键合,m为1,2,3,4,5或6,脂族羧酸的盐为3 至18个碳原子,随后固定印刷; 以及所使用的印刷浆料及其用于印刷纺织材料的用途。

    Reactive disazo dyes which contain two aminofluoro-1,3,5-triazinyl
radicals
    9.
    发明授权
    Reactive disazo dyes which contain two aminofluoro-1,3,5-triazinyl radicals 失效
    含有两个氨基磺酰基-1,3,5-三嗪基的反应性灭菌剂

    公开(公告)号:US5073631A

    公开(公告)日:1991-12-17

    申请号:US246031

    申请日:1988-09-14

    申请人: Peter Scheibli

    发明人: Peter Scheibli

    IPC分类号: C09B62/09 D06P1/382

    CPC分类号: C09B62/09

    摘要: Reactive dyes of the formulaX.sub.1 --NH--CH.sub.2).sub.0-1 A--N.dbd.N--M--N.dbd.N--B--CH.sub.2).sub.0-1 NH--X.sub.2 (1)in which M is twice-coupled 1-amino-8-hydroxynaphthalene-3,6-disulfonic acid, 1-amino-8-hydroxynaphthalene-4,6-disulfonic acid, 1-amino-8-hydroxynaphthalene-4-sulfonic acid or 2-amino-5-hydroxynaphthalene-7-sulfonic acid, A and B, independently of each other, are each unsubstituted or substituted phenylene or naphthylene, and X.sub.1 and X.sub.2, independently of each other, are each unsubstituted or substituted amino-fluoro-1,3,5-triazinyl, excluding the reactive dyes of German Offenlegungsschrift 2,738,823, are suitable in particular for dyeing and printing cellulose-containing fibre materials and produce, combined with a high dyeing yield, dyeings and prints having good fastness properties.

    摘要翻译: 式X1-NH-CH2)0-1A-N = NMN = NB-CH2)的反应性染料0-1NH-X2(1)其中M是2-氨基-8-羟基萘-3,6-二 二磺酸,1-氨基-8-羟基萘-4,6-二磺酸,1-氨基-8-羟基萘-4-磺酸或2-氨基-5-羟基萘-7-磺酸A和B,独立地 彼此独立地为未取代或取代的亚苯基或亚萘基,X1和X2彼此独立地为未取代或取代的氨基 - 氟-1,3,5-三嗪基,不包括德国Offenlegungsschrift 2,738,823的活性染料是合适的 特别是用于染色和印刷含纤维素的纤维材料并且产生高染色性,染色和具有良好牢度性能的印花。

    Fibre-reactive azo dyes containing vinylsulfonyl groups and further
aliphatic fibre-reactive radicals

    公开(公告)号:US4908436A

    公开(公告)日:1990-03-13

    申请号:US921849

    申请日:1986-10-23

    申请人: Peter Scheibli

    发明人: Peter Scheibli

    CPC分类号: C09B62/4411

    摘要: A reactive dye of the formula ##STR1## or of the formula ##STR2## or of the formula ##STR3## in which D, D.sub.1 and D.sub.2 are each phenylene or naphthylene unsubstituted or substituted by alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, carboxylic acylamino having 1 to 8 carbon atoms, amino, alkylamino having 1 to 4 carbon atoms, phenylamino, N,N-di-.beta.-hydroxyethylamino, N,N-di-.beta.-sulfatoethylamino, sulfobenzylamino, N,N-disulfobenzylamino, alkoxycarbonyl having 1 to 4 carbon atoms in the alkoxy radical, alkylsulfonyl having 1 to 4 carbon atoms, trifluoromethyl, nitro, cyano, halogen, carbamoyl, N-alkylcarbamoyl having 1 to 4 carbon atoms in the alkyl radical, sulfamoyl N-alkylsulfamoyl having 1 to 4 carbon atoms, N-(.beta.-hydroxyethyl)-sulfamoyl, N,N-di-(.beta.-hydroxyethyl)-sulfamoyl, N-phenylsulfamoyl, ureido hydroxyl, carboxyl, sulfomethyl, or sulfo, R.sub.1 is hydrogen or C.sub.1-4 -alkyl unsubstituted or substituted by halogen, hydroxyl, cyano, C.sub.1-4 -alkoxy, methoxycarbonyl, ethoxycarbonyl, sulfamoyl, sulfato, carboxyl or sulfo, R.sub.2 is (1) hydrogen, (2) alkyl unsubstituted or substituted by halogen, hydroxy, cyano, alkoxy, methoxycarbonyl, ethoxycarbonyl, sulfamoyl, sulferto, carboxy or sulfo, (3) cyclohexyl, (4) phenyl unsubstituted or substituted by methyl, ethyl, methoxy, ethoxy, chlorine, bromine, carboxyl, sulfo or sulfomethyl, or (5) a radical of the formula --alk--SO.sub.2 --Z, E--NH.sub.2, --CH.sub.3, --NH--CO--NH.sub.2, --NH--CO--CH.sub.3 or --NH--CO--CH.sub.2 --OH, wherein alk is C.sub.2-6 --alkylene, Y is --SO.sub.2 --Z, --SO.sub.2 --N(R.sub.1)--Z, --N--(R.sub.1)--SO.sub.2 --Z, --N(R.sub.1)--CO--(CH.sub.2).sub.3-5 SO.sub.2 --Z, --SO.sub.2 --F, --SO.sub.2 CH.sub.2 --CH.dbd.CH.sub.2, --N(R.sub.1)--CO--CBr.dbd.CH.sub.2, --N(R.sub.1)--CO--CHBr--CH.sub.2 Br, --N(R.sub.1)--CO--CCl.dbd.CH.sub.2, --N(R.sub.1)--CO--CHCl--CH.sub.2 Cl, --N(R.sub.1)--CO--CH.sub.2 Cl or --N(R.sub.1)--CO--CH.dbd.CH.sub.2, Z is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 --A, A is --OSO.sub.3 H, --SSO.sub.3 H, --OCOCH.sub.3, --OPO.sub.3 H.sub.2, --Cl, --Br or --F, and X is fluorine, chlorine or hydroxyl.