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176 条记录 (耗时 0.017 秒)

    Catalytic process for preparing polymers of sulfur dioxide and olefin
    71.
    发明授权
    Catalytic process for preparing polymers of sulfur dioxide and olefin 失效
    用于制备二氧化硫和烯烃聚合物的催化方法

    公开(公告)号：US4808697A

    公开(公告)日：1989-02-28

    申请号：US164161

    申请日：1988-03-03

    申请人： Eit Drent

    发明人： Eit Drent

    IPC分类号： C08G67/00 ,  C08G75/00 ,  C08G75/22 ,  C08G75/18

    CPC分类号： C08G75/22 ,  C08G67/00

    摘要： The invention is a process for preparing linear alternating polymers of sulfur dioxide, ethylene, optionally at least one ethylenically unsaturated hydrocarbon other than ethylene and optionally carbon monoxide having the general formula ##STR1## wherein Z is at least one moiety selected from SO.sub.2 and CO, G is the moiety of at least one ethylenically unsaturated hydrocarbon of at least 2 carbon atoms polymerized through the ethylenic unsaturation, n is an integer of at least 1, and m is an integer of zero or greater, which process comprises contacting sulfur dioxide, ethylene, optionally carbon monoxide, and optionally at least one ethylenically unsaturated hydrocarbon of at least 2 carbon atoms, in the presence of a catalyst obtained from (1) a compound of a Group VIII metal selected from palladium, cobalt and nickel, (2) a bidentate ligand of phosphorus, arsenic, or antimony, and (3) an anion of a non-hydrohalogenic acid having a pKa of less than 6.

    摘要翻译： 本发明是一种制备二氧化硫，乙烯，任选至少一种除乙烯以外的至少一种烯属不饱和烃和任选一种具有通式“IMAGE”的一氧化碳的线性交替聚合物的方法，其中Z是至少一个选自SO 2和CO的部分， G是通过烯属不饱和键聚合的至少一个至少2个碳原子的烯属不饱和烃的部分，n是至少为1的整数，m是零或更大的整数，该方法包括使二氧化硫，乙烯 ，任选的一氧化碳，以及任选的至少一种具有至少2个碳原子的烯属不饱和烃，在（1）选自钯，钴和镍的Ⅷ族金属的化合物的存在下，（2） 磷，砷或锑的双齿配体，和（3）pKa小于6的非氢卤酸的阴离子。

    Positive radiation sensitive resist terpolymer from omega alkynoic acid
    72.
    发明授权
    Positive radiation sensitive resist terpolymer from omega alkynoic acid 失效
    来自ω-炔酸的抗辐射敏感抗性三聚物

    公开(公告)号：US4405776A

    公开(公告)日：1983-09-20

    申请号：US396663

    申请日：1982-07-09

    申请人： Thomas R. Pampalone ,  Kurt B. Kilichowski

    发明人： Thomas R. Pampalone ,  Kurt B. Kilichowski

    IPC分类号： C08G75/22 ,  G03F7/039

    CPC分类号： G03F7/039 ,  C08G75/22

    摘要： This invention relates to novel terpolymers of 3-methylcyclopentene, an omega alkynoic acid and sulfur dioxide. Positive radiation sensitive films prepared from the subject terpolymers adhere well to the substrate, demonstrate resistance to cracking and erosion during development and possess excellent edge definition.

    摘要翻译： 本发明涉及3-甲基环戊烯，ω-炔酸和二氧化硫的新型三元共聚物。 从主题三聚体制备的正性辐射敏感膜很好地粘附到基材上，在显影过程中表现出抗裂纹和侵蚀性，并且具有优异的边界定义。

    Positive radiation sensitive resist terpolymers
    73.
    发明授权
    Positive radiation sensitive resist terpolymers 失效
    正辐射敏感抗蚀剂三元共聚物

    公开(公告)号：US4355094A

    公开(公告)日：1982-10-19

    申请号：US244104

    申请日：1981-03-16

    申请人： Thomas R. Pampalone ,  Kurt B. Kilichowski

    发明人： Thomas R. Pampalone ,  Kurt B. Kilichowski

    IPC分类号： C08G75/22 ,  G03F7/039 ,  G03C1/00 ,  B05D3/06 ,  C23F1/00

    CPC分类号： C08G75/22 ,  G03F7/039

    摘要： This invention relates to novel terpolymers of 3-methylcyclopentene, an omega alkynoic acid and sulfur dioxide. Positive radiation sensitive films prepared from the subject terpolymers adhere well to the substrate, demonstrate resistance to cracking and erosion during development and possess excellent edge definition.

    摘要翻译： 本发明涉及3-甲基环戊烯，ω-炔酸和二氧化硫的新型三元共聚物。 从主题三聚体制备的正性辐射敏感膜很好地粘附到基材上，在显影过程中表现出抗裂纹和侵蚀性，并且具有优异的边界定义。

    Oil-plasticized copolymers of SO.sub.2 and olefins
    74.
    发明授权
    Oil-plasticized copolymers of SO.sub.2 and olefins 失效
    SO {HD 2 {B和烯烃的油增塑共聚物

    公开(公告)号：US4100128A

    公开(公告)日：1978-07-11

    申请号：US787367

    申请日：1977-04-14

    申请人： Guido Sartori ,  Robert D. Lundberg

    发明人： Guido Sartori ,  Robert D. Lundberg

    IPC分类号： C08G75/22 ,  C08K5/01 ,  C08G75/18

    CPC分类号： C08G75/22 ,  C08K5/01

    摘要： The instant invention relates to compositions comprising a copolymer of sulfur dioxide and one or more olefins in combination with a hydrocarbon oil which is a mixture of paraffinic, aromatic and naphthenic hydrocarbons having a solubility parameter of about 7 to about 8.5. The olefins are alpha olefins, at least one having a carbon number of 20 or more, more preferably a carbon number of from 20 to 40. The copolymers useful in preparing the compositions of the instant invention are crystalline solids, which are combined with a sufficient amount, preferably from about 5 to 24 pph, of the hydrocarbon oil to yield flexible materials. The above compositions are useful as coatings.

    摘要翻译： 本发明涉及包含二氧化硫和一种或多种烯烃与烃油的共聚物的组合物，烃油是溶解度参数为约7至约8.5的链烷烃，芳族烃和环烷烃的混合物。 烯烃是α-烯烃，至少一种碳原子数为20以上，更优选碳原子数为20〜40。可用于制备本发明组合物的共聚物是结晶固体，它们与足够的 量，优选约5至24pph的烃油，以产生柔性材料。 上述组合物可用作涂层。

    Block copolymers containing olefin sulfur dioxide segments and process for their preparation
    76.
    发明授权
    Block copolymers containing olefin sulfur dioxide segments and process for their preparation 失效
    含有烯烃二氧化硫段的嵌段共聚物及其制备方法

    公开(公告)号：US3932369A

    公开(公告)日：1976-01-13

    申请号：US521454

    申请日：1974-11-06

    申请人： Guido Sartori ,  Robert D. Lundberg

    发明人： Guido Sartori ,  Robert D. Lundberg

    IPC分类号： C08F293/00 ,  C08G75/22 ,  C08F28/00

    CPC分类号： C08G75/22 ,  C08F293/00

    摘要： The instant invention relates to novel block copolymers containing olefin sulfur-dioxide segments and a process for their preparation. The olefin of choice is a "strained" olefin thus capable of reaction with SO.sub.2 in the presence of radicals at very high rates. Examples of strained olefins include cyclopropene, cyclobutene, norbornene, and the derivatives thereof. The novel block copolymers are prepared by contacting the olefin and the sulfur dioxide with a polymer under conditions of shearing degradation whereby said polymer is broken down into radical-containing segments which subsequently combine with the olefin and sulfur dioxide to form the novel copolymers described above. The polymer may be selected from the group consisting of polyisobutylene, poly(ethylene oxide), ethylene-propylene copolymers, poly(propylene oxide), polybutadiene, polyisoprene, etc. A novel block polymer formed by this preferred process shows improved properties as compared to physical mixtures of said polymer and olefin-sulfur dioxide copolymers. For example, the novel polymers formed by the preferred process of the instant invention show higher moduli and may be plasticized to higher levels while retaining good physical properties.

    摘要翻译： 本发明涉及含有烯烃二氧化硫段的新型嵌段共聚物及其制备方法。 所选择的烯烃是一种“应变”烯烃，因此能够在极性存在自由基的情况下与SO2反应。 应变烯烃的实例包括环丙烯，环丁烯，降冰片烯及其衍生物。 通过在剪切降解的条件下使烯烃和二氧化硫与聚合物接触来制备新的嵌段共聚物，其中所述聚合物被分解成含自由基的链段，其随后与烯烃和二氧化硫结合以形成上述新的共聚物。 聚合物可以选自聚异丁烯，聚（环氧乙烷），乙烯 - 丙烯共聚物，聚（环氧丙烷），聚丁二烯，聚异戊二烯等。通过该优选方法形成的新的嵌段聚合物显示出与 所述聚合物和烯烃 - 二氧化硫共聚物的物理混合物。 例如，通过本发明优选方法形成的新型聚合物显示更高的模量，并且可以塑化至更高的水平，同时保持良好的物理性能。

    Reactive alpha olefin polysulfones
    79.
    发明授权
    Reactive alpha olefin polysulfones 失效
    反应性ALPHA OLEFIN POLYSULFONES

    公开(公告)号：US3563961A

    公开(公告)日：1971-02-16

    申请号：US3563961D

    申请日：1969-08-04

    申请人： DOW CHEMICAL CO

    发明人： PICKLE WILLIAM S ,  LORETTE NICHOLAS B

    IPC分类号： C08G75/22 ,  D06M15/233 ,  C08F13/06

    CPC分类号： D06M15/233 ,  C08G75/22

    摘要： OLEFIN POLYSULFONES WHICH ARE THE REACTION PRODUCT OF SULFUR DIOXIDE, AT LEAST ONE ALPHA OLEFIN OF FROM 4 TO 40 CARBON ATOMS AND A MONOMER CHOSEN FROM MONOOLEFINICALLY UNSATURATED CARBOXYLIC ACID CHLORIDES OR MONOOLEFINICALLY UNSATURATED DICARBOXYLIC ANHYDRIDES ARE USEFUL TO COAT AND PROTECT VARIOUS SUBSTRATES. THEY ARE PARTICULARLY USEFUL TO RENDER NATURAL FABRICS SHRINK RESISTANT AND WATER REPELLANT.