公开(公告)号：US20090312568A1

公开(公告)日：2009-12-17

申请号：US12545101

申请日：2009-08-21

申请人： Teddy M. Keller ,  Manoj K. Kolel-Veetil

发明人： Teddy M. Keller ,  Manoj K. Kolel-Veetil

IPC分类号： C07F7/02

CPC分类号： C08F283/00 ,  C08F283/12 ,  C08G77/04 ,  C08G77/12 ,  C08G77/20 ,  C08G77/50 ,  C08G77/56 ,  C08L83/14

摘要： A thermoset and method of making such by crosslinking a mixture of a polyhedral oligomeric silsesquioxane having pendent siloxane groups or unsaturated carbon bonds and a siloxylcarborane compound having unsaturated carbon bonds.

摘要翻译： 一种热固性材料和通过交联具有侧基硅氧烷基团或不饱和碳键的多面体低聚倍半硅氧烷与具有不饱和碳键的硅氧烷基碳化硼化合物的混合物来制备的方法。

公开(公告)号：US20090082490A1

公开(公告)日：2009-03-26

申请号：US12163004

申请日：2008-06-27

申请人： Teddy M. Keller

发明人： Teddy M. Keller

IPC分类号： C03C25/28 ,  C08G77/56

CPC分类号： C08G77/56 ,  C08G77/50 ,  C08G79/08 ,  Y10T428/2962

摘要： A linear polymer comprising carborane, siloxane, and acetylene units, which may be cross-linked to a cured polymer and/or pyrolyzed to a ceramic.

摘要翻译： 包含碳硼烷，硅氧烷和乙炔单元的线性聚合物，其可以与固化的聚合物交联和/或热解成陶瓷。

公开(公告)号：US20090018273A1

公开(公告)日：2009-01-15

申请号：US11834741

申请日：2007-08-07

申请人： Teddy M. Keller ,  Manoj K. Kolel-Veetil

发明人： Teddy M. Keller ,  Manoj K. Kolel-Veetil

IPC分类号： C08F283/12

CPC分类号： C08F283/00 ,  C08F283/12 ,  C08G77/04 ,  C08G77/12 ,  C08G77/20 ,  C08G77/50 ,  C08G77/56 ,  C08L83/14

摘要： A thermoset and method of making such by crosslinking a mixture of a polyhedral oligomeric silsesquioxane having pendent siloxane groups or unsaturated carbon bonds and a siloxylcarborane compound having unsaturated carbon bonds.

摘要翻译： 一种热固性材料和通过交联具有侧基硅氧烷基团或不饱和碳键的多面体低聚倍半硅氧烷与具有不饱和碳键的硅氧烷基碳化硼化合物的混合物来制备的方法。

公开(公告)号：US20080255287A1

公开(公告)日：2008-10-16

申请号：US11851411

申请日：2007-09-07

申请人： Matthew Laskoski ,  Teddy M. Keller

发明人： Matthew Laskoski ,  Teddy M. Keller

IPC分类号： C08G79/04 ,  C07F9/53 ,  C08K3/04 ,  C08K3/22

CPC分类号： C08G79/04 ,  C07F9/5325 ,  C08G65/40 ,  C08G65/48 ,  C08K5/5397

摘要： Compounds having the formulas below. Each R1 is an aromatic-containing group. Each R2 is methyl, phenyl, alkyl, perfluoroalkyl, and trifluoromethyl. M is an alkali metal, and n is a positive integer. A thermoset made by curing a mixture comprising a curing agent and the below phthalonitrile monomer. A method of: reacting a bis(fluorophenyl)phenylphosphine oxide with an excess of an aromatic diol in the presence of an alkali metal carbonate to form the oligomer below.

摘要翻译： 具有下式的化合物。 每个R 1是含芳基的基团。 每个R 2是甲基，苯基，烷基，全氟烷基和三氟甲基。 M是碱金属，n是正整数。 通过固化包含固化剂和下述邻苯二甲腈单体的混合物制成的热固性材料。 一种在碱金属碳酸盐存在下使双（氟苯基）苯基氧化膦与过量的芳族二醇反应以在下面形成低聚物的方法。

公开(公告)号：US07273509B1

公开(公告)日：2007-09-25

申请号：US10875806

申请日：2004-06-24

申请人： Teddy M. Keller ,  Syed B. Qadri

发明人： Teddy M. Keller ,  Syed B. Qadri

IPC分类号： B22F9/24

CPC分类号： B22F9/24

摘要： A process of making metal nanoparticles comprising the steps of: providing a precursor composition comprising at least one metallic compound and at least one organic compound; wherein the organic compound is selected from the group consisting of an ethynyl compound, a metal-ethynyl complex, and combinations thereof; wherein the precursor composition is a liquid or a solid at room temperature; and heating the precursor composition under conditions effective to produce metal nanoparticles. A metal nanoparticle composition comprising metal nanoparticles dispersed homogenously in a matrix selected from the group consisting of ethynyl polymer, crosslinked ethynyl polymer, amorphous carbon, carbon nanotubes, carbon nanoparticles, graphite, and combinations thereof.

摘要翻译： 制备金属纳米颗粒的方法包括以下步骤：提供包含至少一种金属化合物和至少一种有机化合物的前体组合物; 其中所述有机化合物选自乙炔基化合物，金属 - 乙炔基络合物及其组合; 其中所述前体组合物在室温下为液体或固体; 并在有效产生金属纳米颗粒的条件下加热前体组合物。 包含均匀分散在选自乙炔基聚合物，交联乙炔基聚合物，无定形碳，碳纳米管，碳纳米颗粒，石墨及其组合的基质中的金属纳米颗粒组合物。

公开(公告)号：US07198771B2

公开(公告)日：2007-04-03

申请号：US10652082

申请日：2003-08-28

申请人： Teddy M. Keller ,  Joseph Perrin ,  Syed B. Qadri

发明人： Teddy M. Keller ,  Joseph Perrin ,  Syed B. Qadri

IPC分类号： C07F17/02

CPC分类号： B82Y30/00 ,  D01F9/127 ,  Y10S977/773 ,  Y10S977/775 ,  Y10S977/777 ,  Y10S977/788 ,  Y10S977/896 ,  Y10S977/897

摘要： The invention comprises a chemical composition with the structure shown below. The composition can be polymerized or pyrolyzed, forming transition metal nanoparticles homogeneously dispersed in a thermoset or carbon composition. The size of the nanoparticles can be controlled by manipulating the number and arrangement of functional groups in the composition and by changing the conditions of the polymerization or pyrolysis. The resulting thermosets and carbon compositions have useful magnetic, electric, mechanical, catalytic and/or optical properties. wherein A is selected from the group consisting of H, wherein M is a metal selected independently from the group consisting of Fe, Mn, Ru, Co, Ni, Cr and V; wherein Rx is independently selected from the group consisting of an aromatic, a substituted aromatic group and combinations thereof; wherein Ry is independently selected from the group consisting of an aromatic, a substituted aromatic group and combinations thereof; wherein m is ≧0; wherein s is ≧0; wherein z is ≧0; and wherein m and s are independently determined in each repeating unit.

摘要翻译： 本发明包括具有如下结构的化学组合物。 组合物可以聚合或热解，形成均匀分散在热固性或碳组合物中的过渡金属纳米颗粒。 可以通过操纵组合物中官能团的数目和排列以及通过改变聚合或热解的条件来控制纳米颗粒的尺寸。 所得的热固性和碳组合物具有有用的磁性，电学，机械，催化和/或光学性质。

公开(公告)号：US06673953B2

公开(公告)日：2004-01-06

申请号：US10006226

申请日：2001-12-10

申请人： Teddy M. Keller ,  Joseph Perrin ,  Syed B. Qadri

发明人： Teddy M. Keller ,  Joseph Perrin ,  Syed B. Qadri

IPC分类号： C07F1702

CPC分类号： B82Y30/00 ,  D01F9/127 ,  Y10S977/773 ,  Y10S977/775 ,  Y10S977/777 ,  Y10S977/788 ,  Y10S977/896 ,  Y10S977/897

摘要： The invention comprises a chemical composition with the structure shown below. The composition can be polymerized or pyrolyzed, forming transition metal nanoparticles homogeneously dispersed in a thermoset or carbon composition. The size of the nanoparticles can be controlled by manipulating the number and arrangement of functional groups in the composition and by changing the conditions of the polymerization or pyrolysis. The resulting thermosets and carbon compositions have useful magnetic, electric, mechanical, catalytic and/or optical properties. wherein A is selected from the group consisting of H, wherein M is a metal selected independently from the group consisting of Fe, Mn, Ru, Co, Ni, Cr and V; wherein Rx is independently selected from the group consisting of an aromatic, a substituted aromatic group and combinations thereof; wherein Ry is independently selected from the group consisting of an aromatic, a substituted aromatic group and combinations thereof; wherein m is ≧0; wherein s is ≧0; wherein z is ≧0; and wherein m and s are independently determined in each repeating unit.

摘要翻译： 本发明包括具有如下结构的化学组合物。 组合物可以聚合或热解，形成均匀分散在热固性或碳组合物中的过渡金属纳米颗粒。 可以通过操纵组合物中官能团的数目和排列以及通过改变聚合或热解的条件来控制纳米颗粒的尺寸。 所得的热固性和碳组合物具有有用的磁，电，机械，催化和/或光学性质，其中A选自H，其中M是选自Fe，Mn，Ru， Co，Ni，Cr和V;其中Rx独立地选自芳族，取代的芳族基团及其组合;其中R y独立地选自芳族，取代的芳族基团及其组合; 其中m是> = 0;其中s是> = 0;其中z是> = 0; 并且其中m和s在每个重复单元中独立地确定。

公开(公告)号：US06579955B2

公开(公告)日：2003-06-17

申请号：US10046296

申请日：2002-01-16

申请人： Teddy M. Keller ,  Craig Homrighausen

发明人： Teddy M. Keller ,  Craig Homrighausen

IPC分类号： C08G7744

CPC分类号： C08L83/14 ,  C08G77/50

摘要： A linear polymer has repeating units represented by the formula wherein (a) n is an integer greater than or equal to 0, (b) x is an integer greater than or equal to 1, and  represents an unconjugated acetylenic group when x is equal to 1 or conjugated acetylenic groups when x is greater than 1; (c) Ar is an aromatic group, and (c) R1, R2, R3, R4, R5, R6, R7 and R8 are independently selected from the group consisting of alkyl, aryl, alkylaryl, haloalkyl, haloaryl and mixtures thereof. The linear polymer may be thermally cured to form a crosslinked polymer.

公开(公告)号：US5780569A

公开(公告)日：1998-07-14

申请号：US337012

申请日：1994-11-07

申请人： Teddy M. Keller ,  David Y. Son

发明人： Teddy M. Keller ,  David Y. Son

IPC分类号： C08G77/56 ,  C08G77/60

CPC分类号： C08G77/56 ,  C08G77/60

摘要： A novel organoboron polymer and its method of preparation is claimed. The organoboron polymer has a backbone having a repeating unit comprising at least one carboranyl group, at least two acetylenic groups, and one or more silyl or siloxanyl groups.

摘要翻译： 要求保护新颖的有机硼聚合物及其制备方法。 有机硼聚合物具有主链，其具有包含至少一个碳硼烷基，至少两个炔基和一个或多个甲硅烷基或硅氧烷基的重复单元。

公开(公告)号：US5681870A

公开(公告)日：1997-10-28

申请号：US687699

申请日：1996-07-26

申请人： Teddy M. Keller ,  Raj A. Sundar

发明人： Teddy M. Keller ,  Raj A. Sundar

IPC分类号： C04B35/563 ,  C04B35/571 ,  C08F2/48 ,  C08G77/56 ,  C08G79/08 ,  C08F299/08

CPC分类号： C08G77/56 ,  C04B35/563 ,  C04B35/571 ,  C08G79/08

摘要： Novel class of organoboron thermosetting polymer and ceramics that are fod from an organoboron polymer having a backbone with a repeating of at least one alkynyl group, at least one silyl group, at least one boranyl group, optionally at least one siloxyl group, and optionally an aryldisilyl group. The boron containing units in and the silicon containing units can be arranged in either random occurrences between each other or in the form of interdispersed block-type structures of each unit. The thermosetting polymers are useful as high temperature, oxidatively stable thermosetting plastics and for microelectronic applications.

摘要翻译： 由具有重复至少一个炔基的主链的有机硼聚合物，至少一个甲硅烷基，至少一个硼烷基，任选至少一个硅氧烷基，以及任选的 芳基二甲硅烷基。 含硼单元和含硅单元可以以彼此之间的随机出现或以每个单元的分散间隔型结构的形式布置。 热固性聚合物可用作高温，氧化稳定的热固性塑料和微电子应用。