公开(公告)号：US08569388B2

公开(公告)日：2013-10-29

申请号：US13807349

申请日：2011-06-23

Applicant: Michiel Johannes Franciscus Maria Verhaak

Inventor： Michiel Johannes Franciscus Maria Verhaak

IPC: C07C27/00

CPC classification number: C07C1/02 ,  B01J23/34 ,  B01J23/8892 ,  B01J29/076 ,  B01J29/26 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/035 ,  C07C1/0435 ,  C07C1/0445 ,  C07C11/02

Abstract: The invention relates to a process for preparing olefins from synthesis gas, wherein the synthesis gas is contacted with a catalyst which contains cobalt, manganese and a third element selected from the group consisting of aluminium, gallium, indium, thallium, tin, lead and bismuth. Further, the invention relates to a process for preparing such catalyst, and to the catalyst so obtained.

Abstract translation: 本发明涉及从合成气制备烯烃的方法，其中合成气与含有钴，锰的催化剂和选自铝，镓，铟，铊，锡，铅和铋的第三元素接触 。 此外，本发明涉及制备这种催化剂的方法，以及如此得到的催化剂。

公开(公告)号：US08557878B2

公开(公告)日：2013-10-15

申请号：US13094438

申请日：2011-04-26

Applicant: Alkis S. Rappas ,  Robert A. Spitz

Inventor： Alkis S. Rappas ,  Robert A. Spitz

IPC: C07C27/00

CPC classification number: C10J3/00 ,  C10J2300/0943 ,  C10J2300/0966 ,  C10J2300/0973 ,  C10J2300/0986 ,  C10J2300/1807 ,  C10J2300/1823 ,  C10L3/08 ,  C22B7/00 ,  C22B34/22 ,  C22B34/225 ,  Y02P10/23

Abstract: The present invention relates to processes and apparatuses for hydromethanating a vanadium-containing carbonaceous feedstock while recovering at least a portion of the vanadium content originally present in the carbonaceous feedstock.

Abstract translation: 本发明涉及用于在含钒原料中初始存在的至少一部分钒含量的同时含钒含碳原料进行氢化反应的方法和装置。

公开(公告)号：US08552073B2

公开(公告)日：2013-10-08

申请号：US12526822

申请日：2008-02-08

Applicant: Jan Hendrik Duvenhage Boshoff ,  Isabella Lodewina Greeff ,  Andre Peter Steynberg

Inventor： Jan Hendrik Duvenhage Boshoff ,  Isabella Lodewina Greeff ,  Andre Peter Steynberg

IPC: C07C27/00

CPC classification number: C10J3/00 ,  C10G2/32 ,  C10J3/86 ,  C10J2300/093 ,  C10J2300/0956 ,  C10J2300/0959 ,  C10J2300/0973 ,  C10J2300/1606 ,  C10J2300/165 ,  C10J2300/1659 ,  C10J2300/1675 ,  C10J2300/1807 ,  C10K1/004 ,  C10K1/005 ,  C10K1/101 ,  C10K1/103 ,  C10K1/143 ,  C10K1/165 ,  C10K3/04 ,  Y02E20/18 ,  Y02P20/129

Abstract: A process (10) for co-producing power and hydrocarbons includes gasifying (16, 70) coal to produce a synthesis gas (36) and a combustion gas (86) both comprising at least CO1H2 and CO2 and being at elevated pressure, separating CO2 (18, 48) from the synthesis gas, and synthesizing (20, 22) hydrocarbons from the synthesis gas. Power (1 14) is generated from the combustion gas, including by combusting (78) the combustion gas in the presence of oxygen and in the presence of at least a portion of the separated CO2 as moderating agent to produce a hot combusted gas (106) which includes CO2. The CO2 is recycled (1 12) or recovered from the combusted gas. In certain embodiments, the process (10) produces a CO2 exhaust stream (134) for sequestration or capturing for further use.

Abstract translation: 用于共同生产动力和烃的方法（10）包括气化（16,70）煤以产生合成气（36）和至少包括CO 1 H 2和CO 2并处于升高压力的燃烧气体（86），分离CO 2 （18,48），并从合成气中合成（20,22）烃。 燃烧气体产生动力（114），包括在氧的存在下燃烧（78）燃烧气体，并在至少一部分分离的CO 2存在下作为调节剂产生热燃气（106 ），其中包括CO2。 二氧化碳被回收（112）或从燃烧的气体中回收。 在某些实施方案中，方法（10）产生用于进一步使用的用于封存或捕获的CO 2排气流（134）。

公开(公告)号：US20130255803A1

公开(公告)日：2013-10-03

申请号：US13435852

申请日：2012-03-30

Applicant: Surinder Prabhjot Singh ,  John Brian McDermott ,  Lingzhi Zhang

Inventor： Surinder Prabhjot Singh ,  John Brian McDermott ,  Lingzhi Zhang

IPC: C07C27/00

CPC classification number: C10G2/34 ,  B01J19/245 ,  B01J2219/00103 ,  B01J2219/24 ,  C01B3/36 ,  C01B3/382 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/062 ,  C01B2203/1241 ,  C10G2/32 ,  Y10T137/8593

Abstract: A system and method of converting natural gases to liquids is provided. The system includes a catalytic partial oxidation (CPO) system with natural gas, air and steam input, a Fischer-Tropsch (F-T) system taking syngas from the CPO system, and supplying product gases to a power engine (PE), after separation of the product liquids. An F-T steam output line is in fluid communication with the CPO-steam input line. The energy output from the PE is supplied to the compressors and condensers, to provide self-sustainability in energy, for the gas-to-liquid separation system.

公开(公告)号：US08536360B2

公开(公告)日：2013-09-17

申请号：US13089708

申请日：2011-04-19

Applicant: Hyunwoo Kim ,  James Lincoln Leighton

Inventor： Hyunwoo Kim ,  James Lincoln Leighton

IPC: C07F7/00 ,  C07C27/00

CPC classification number: C07F7/12 ,  C07B2200/07 ,  C07C29/38 ,  C07F7/10 ,  C07C33/30

Abstract: Compositions and methods for practical, stereoselective allylation and crotylation for aldehyde substrates are described. The compositions and methods comprise reagents for allylation and/or crotylation and acids. In some embodiments, the reagents and acids are pre-mixed.

Abstract translation: 描述了用于醛底物的实际的立体选择性烯丙基化和胡萝卜素化的组合物和方法。 组合物和方法包括用于烯丙基化和/或脱蛋白化和酸的试剂。 在一些实施方案中，将试剂和酸预混合。

公开(公告)号：US08513313B2

公开(公告)日：2013-08-20

申请号：US12672985

申请日：2008-08-05

Applicant: Johannes Jacobus Huyser ,  Matthys Josephus Janse Van Vuuren

Inventor： Johannes Jacobus Huyser ,  Matthys Josephus Janse Van Vuuren

IPC: C07C27/00 ,  B01J20/34

CPC classification number: B01J23/78 ,  B01J23/745 ,  B01J37/18 ,  C10G2/332 ,  C10G2300/703

Abstract: This invention relates to a hydrocarbon synthesis process. More particularly, but not exclusively, this invention relates to a Fischer Tropsch Process employing an activated catalyst and to the use of such an activated catalyst, wherein the Fischer Tropsch Process conditions favor the attainment of a low acid selectivity. More particularly the invention relates to a three-phase low temperature Fischer Tropsch (LTFT) process wherein a feed of H2 and CO are converted to hydrocarbons and possible oxygenates thereof by contacting the H2 and CO in the presence of an iron-based Fischer Tropsch catalyst in a reaction zone, wherein the molar ratio of H2:CO in the feed is from 0.5 and less than 1.0 and wherein the iron-based Fischer Tropsch catalyst is activated according to the steps of: (a) providing an iron-based catalyst including iron in a positive oxidation state; and (b) contacting the iron-based catalyst in a reactor with a reducing gas selected from CO and a combination of H2 and CO; at a reduction temperature of at least 245° C. and below 280° C.; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total reducing gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.

Abstract translation: 本发明涉及烃合成方法。 更具体地但非排他地，本发明涉及使用活化催化剂的费 - 托法和这种活化催化剂的用途，其中费托法条件有利于获得低酸选择性。 更具体地说，本发明涉及一种三相低温费托（LTFT）方法，其中通过在铁基费托催化剂存在下使H 2和CO接触将H 2和CO的进料转化为烃和可能的含氧化合物 在反应区中，其中进料中H 2 :CO的摩尔比为0.5至小于1.0，其中铁基费托催化剂根据以下步骤活化：（a）提供一种铁基催化剂，其包括 正铁氧化态; 和（b）使反应器中的铁基催化剂与选自CO和H2与CO的组合的还原气体接触; 在至少245℃和280℃以下的还原温度下进行。 在0.5MPa以上且2.2MPa以下的还原气体压力下， 并且在进料到反应器的总还原气体的GHSV为至少6000ml（N）/ g cat / h，从而减少催化剂中正氧化步骤中的铁。

公开(公告)号：US08461217B2

公开(公告)日：2013-06-11

申请号：US12755957

申请日：2010-04-07

Applicant: George A. Olah ,  G. K. Surya Prakash

Inventor： George A. Olah ,  G. K. Surya Prakash

IPC: C07C27/00

CPC classification number: C10L1/02 ,  C07C29/151 ,  C07C41/09 ,  Y02P20/582 ,  Y02P30/42 ,  C07C31/04 ,  C07C43/043

Abstract: The invention provides a method for rendering natural gas as an environmentally essentially carbon dioxide-neutral fuel. Carbon dioxide produced from natural gas combustion or from natural gas wells is captured, purified, combined with natural gas or methane or with hydrogen, and reacted under reaction conditions sufficient to form methanol and/or dimethyl ether, which can be used as fuel or feedstock for derived synthetic hydrocarbons and products.

Abstract translation: 本发明提供了一种使天然气作为环境基本上是二氧化碳中性燃料的方法。 从天然气燃烧或天然气井产生的二氧化碳被捕获，纯化，与天然气或甲烷或氢气结合，并在足以形成甲醇和/或二甲醚的反应条件下反应，可用作燃料或原料 用于衍生合成碳氢化合物和产物。

公开(公告)号：US08415512B2

公开(公告)日：2013-04-09

申请号：US12904030

申请日：2010-10-13

Applicant: Jeffrey H. Sherman ,  Eric W. McFarland ,  Michael J. Weiss ,  Ivan Marc Lorkovic ,  Leroy E. Laverman ,  Shouli Sun ,  Dieter J. Schaefer ,  Galen D. Stucky ,  Peter C. Ford ,  Philip Grosso ,  Ashley W. Rreed ,  Michael F. Doherty

Inventor： Jeffrey H. Sherman ,  Eric W. McFarland ,  Michael J. Weiss ,  Ivan Marc Lorkovic ,  Leroy E. Laverman ,  Shouli Sun ,  Dieter J. Schaefer ,  Galen D. Stucky ,  Peter C. Ford ,  Philip Grosso ,  Ashley W. Rreed ,  Michael F. Doherty

IPC: C07C27/00 ,  C07C27/10

CPC classification number: C07C1/30 ,  C07C17/10 ,  C07C29/124 ,  C07C29/58 ,  C07C45/27 ,  C07C2521/02 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/42 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/80 ,  C07C2527/128 ,  C07C2527/133 ,  C07D301/26 ,  Y02P20/582 ,  C07C19/075 ,  C07C19/043 ,  C07C19/07 ,  C07C47/06 ,  C07C41/01 ,  C07C43/04 ,  C07C31/02

Abstract: Improvements in previously disclosed methods of and apparatuses for converting alkanes, alkenes, and aromatics to olefins, alcohols, ethers, and aldehydes includes: safety improvements, use of alternative feedstocks, process simplification, improvements to the halogenation step, improvements to the reproportionation step, improvements to the solid oxide reaction, improvements to solid oxide regeneration, improvements in separations, maintenance, start-up, shut-down, and materials of construction.

Abstract translation: 将烷烃，烯烃和芳族化合物转化为烯烃，醇，醚和醛的先前公开的方法和装置的改进包括：安全性改进，替代原料的使用，工艺简化，改进卤化步骤，改善重复步骤， 固体氧化物反应的改进，固体氧化物再生的改进，分离改进，维护，启动，停机和施工材料。

公开(公告)号：US08410183B2

公开(公告)日：2013-04-02

申请号：US13410330

申请日：2012-03-02

Applicant: Randy D. Cortright ,  James A. Dumesic

Inventor： Randy D. Cortright ,  James A. Dumesic

IPC: C07C27/00

CPC classification number: C10G2/332 ,  C01B3/326 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/06 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/0811 ,  C01B2203/0838 ,  C01B2203/0866 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1217 ,  C10G2/32 ,  C10G2/333 ,  C10G2300/1011 ,  Y02E50/13 ,  Y02E50/32 ,  Y02P20/52 ,  Y02P30/20

Abstract: A low-temperature catalytic process for converting biomass (preferably glycerol recovered from the fabrication of bio-diesel) to synthesis gas (i.e., H2/CO gas mixture) in an endothermic gasification reaction is described. The synthesis gas is used in exothermic carbon-carbon bond-forming reactions, such as Fischer-Tropsch, methanol, or dimethylether syntheses. The heat from the exothermic carbon-carbon bond-forming reaction is integrated with the endothermic gasification reaction, thus providing an energy-efficient route for producing fuels and chemicals from renewable biomass resources.

Abstract translation: 描述了在吸热气化反应中将生物质（优选从制备生物柴油回收的甘油）转化为合成气（即H 2 / CO气体混合物）的低温催化方法。 合成气用于放热碳 - 碳键形成反应，如费 - 托，甲醇或二甲醚合成。 来自放热碳 - 碳键形成反应的热量与吸热气化反应相结合，从而为从可再生生物质资源生产燃料和化学物质提供了节能途径。

公开(公告)号：US20130065974A1

公开(公告)日：2013-03-14

申请号：US13228042

申请日：2011-09-08

Applicant: Steve KRESNYAK

Inventor： Steve KRESNYAK

IPC: C07C27/00

CPC classification number: C01B3/38 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0405 ,  C01B2203/0435 ,  C01B2203/0475 ,  C01B2203/062 ,  C01B2203/0844 ,  C01B2203/0872 ,  C01B2203/1241 ,  C01B2203/1258 ,  C01B2203/142 ,  C01B2203/143 ,  C01B2203/145 ,  C01B2203/147 ,  C10G2/30

Abstract: An enhanced Fischer-Tropsch process for the synthesis of sulfur free, clean burning, hydrocarbon fuels, examples of which include syndiesel and aviation fuel. Naphtha is destroyed in a syngas generator and recycled as feedstock to an Fischer-Tropsch (FT) reactor in order to enhance the production of syndiesel from the reactor. The process enhancement results is the maximum production of formulated syndiesel without the formation of low value by-products.

Abstract translation: 一种用于合成无硫，清洁燃烧，碳氢化合物燃料的增强的费 - 托方法，其实例包括集料和航空燃料。 石脑油在合成气发生器中被破坏，并作为原料再循环到费 - 托（FT）反应器，以增强反应堆中的混合物的产生。 过程增强的结果是在不形成低价值副产物的情况下最大限度地生产配方的混合物。