摘要:
A frameless bipolar cell stack architecture with either internal manifolds of circulation of electrolyte solutions “in parallel” through all respective cell compartments or internal ducting adapted to provide for “serial” flow paths of the electrolyte solutions in succession through all respective cell compartments of the stack, does not employ any plastic frame and employs substantially planar bipolar electrical interconnects (I) of substantially homogeneous electrical conductivity with a perimeter that super-imposes to the perimeter of any other element of the stack. Whenever useful for the particular application, the planar interconnects may have a protruding “lug portion” that projects beyond the outer perimeter side of the other stacked elements, providing an externally contactable area sufficiently large for the power (current rating) of an electrical tap, at an intermediate voltage relative to the voltage difference between the end terminals of the stack, connectable to an external circuit.
摘要:
A fuel cell membrane electrode assembly (MEA) comprising first and second gas diffusion layers and an ion exchange membrane disposed between the diffusion layers. Each diffusion layer includes an inner surface facing the membrane, an outer surface opposite the inner surface, and a side surface defining a perimeter of the diffusion layers. An outboard region extends about the diffusion layers at the perimeter. The outboard region surrounds an inboard region. The outboard region has a low density region proximate to the side surface and a high density region between the low density region and the inboard portion. A seal is mounted at the low density region. The high density region prevents portions of the seal from entering the inboard region thereby damaging the MEA. The seal includes a first rim having a smaller radius than a second rim. The smaller radius allows the seal to fit between adjacent support plates and increases the durability of the seal.
摘要:
A membrane electrode assembly including an electrolyte membrane; a catalyst layer on the electrolyte membrane; a gas diffusion layer attached to the catalyst layer; and an adhesive layer between the electrolyte membrane and the gas diffusion layer around an outer edge of the catalyst layer, and a fuel cell stack including a plurality of unit cells, each including one of the membrane electrode assemblies.
摘要:
A membrane electrode assembly having a peripheral edge region and a central region. The membrane electrode assembly comprises an ion-conducting membrane, first and second electrocatalyst layers disposed either side of the ion-conducting membrane, and first and second gas diffusion layers disposed either side of the first and second electrocatalyst layers respectively. The membrane electrode assembly further comprises an edge protection member, the edge protection member comprising a film layer, a bonding layer, and one or more additives selected from the group consisting of free radical decomposition catalyst, self regenerating antioxidant, hydrogen donors (H-donor) primary antioxidant, free radical scavenger secondary antioxidant, oxygen absorbers (oxygen scavenger) and elemental palladium. The edge protection member is positioned between the membrane and the first and/or second gas diffusion layer at the peripheral edge region of the membrane electrode assembly, and the edge protection member overlaps the first and/or second electrocatalyst layers.
摘要:
A system for fabricating a radiation-cured structure is provided. The system includes a radiation-sensitive material configured to at least one of initiate, polymerize, crosslink and dissociate with exposure to radiation. At least one radiation source is configured to project a radiation beam toward the radiation-sensitive material. A smart glass device is disposed between the radiation-sensitive material and the at least one radiation source. The smart glass device includes at least one switchable layer selectively operable from an active state to an inactive state. The smart glass device is configured to expose the radiation-sensitive material to a desired exposure pattern when in one of the active state and the inactive state. A method for fabricating the radiation-cured structure is also provided.
摘要:
The invention relates to the field of electrochemical cells and fuel cells, more specifically to polymer-electrolyte-membrane fuel cells (PEMFC) and direct methanol fuel cells (DMFC). A multi-layer membrane-electrode-assembly (ML-MEA) comprising two electrically conductive bipolar plates and a membrane-electrode-assembly (MEA) bonded together by means of an electrically insulating adhesive material is disclosed. The adhesive material, preferably a polyurethane-based system, is in direct contact with the protective film layers attached to front side and the back side of the MEA, thus contamination of the ionomer membrane and/or the electrode layers with adhesive components is avoided. Multi-layer MEAs with improved long term stability and life time are obtained. The products are used for the manufacture of low temperature PEMFC and DMFC stacks.
摘要:
A seal arrangement in a fuel cell device seals against leaks in a mechanical joint between two components which convey a liquid and/or a gaseous process medium 3 in a media chamber of the fuel cell device. The seal arrangement has a first sealing member which extends around the media chamber in an installed state, and is in active connection with the components. A second, surrounding sealing member is arranged facing away from the media relative to the first sealing member and is formed of a different material from the first sealing member and/or has a different geometry.
摘要:
A composite seal having a multilayer elastomeric construction and method for constructing the same is provided. More specifically, the present invention provides a composite seal comprised of a low-durometer elastomer compliant layer coated with, or alternatively encapsulated by, a thin protective layer for securely sealing a bipolar plate and a membrane electrode assembly of a fuel cell. The elastomer compliant layer is preferably a silicone constituent and the thin coat protective layer is preferably a fluoroelastomer or fluoropolymer constituent suitable for bonding to the elastomer compliant layer. The foregoing layers constructing the composite seal are preferably deposited directly onto the aforementioned fuel cell components along a predetermined periphery. The resulting composite seal is thin in construction, resistive to undesired chemical and thermal reactions and provides the necessary compressive compliance without undue stress on the fuel cell assembly.
摘要:
In a solid polyelectrolyte fuel cell, with a frame including a frame body main part placed along a peripheral edge portion of a membrane, a plurality of first retaining portions which are arrayed so as to protrude from an inner edge of the frame body main part and which retain the front surface side of the membrane, and a plurality of second retaining portions which are arrayed so as to protrude from the inner edge of the frame body main part and which retain the back surface side of the membrane, the first retaining portions and the second retaining portions are so arrayed that retaining positions of the membrane by the first retaining portions and retaining positions of the membrane by the second retaining portions are alternately placed. A plurality of front-surface side elastic members are placed on the front surface of the membrane between neighboring ones of the first retaining portions while a plurality of back-surface side elastic members are placed on the back surface of the membrane between neighboring ones of the second retaining portions.
摘要:
A first separator to which a resin film is joined beforehand is set in a cavity formed between a lower die and an upper die of an injection molding machine. At the time of die locking by moving the upper die toward the lower die, in the case where the total thickness of the resin film and the first separator is larger than a predetermined dimension, the resin film is pressed by the lower die or the upper die, and thus, the resin film is deformed by compression within its elastic deformation range.