Optoelectronic device comprising perovskites

    公开(公告)号:US11908962B2

    公开(公告)日:2024-02-20

    申请号:US17653795

    申请日:2022-03-07

    摘要: The invention provides an optoelectronic device comprising a porous material, which porous material comprises a semiconductor comprising a perovskite. The porous material may comprise a porous perovskite. Thus, the porous material may be a perovskite material which is itself porous. Additionally or alternatively, the porous material may comprise a porous dielectric scaffold material, such as alumina, and a coating disposed on a surface thereof, which coating comprises the semiconductor comprising the perovskite. Thus, in some embodiments the porosity arises from the dielectric scaffold rather than from the perovskite itself. The porous material is usually infiltrated by a charge transporting material such as a hole conductor, a liquid electrolyte, or an electron conductor. The invention further provides the use of the porous material as a semiconductor in an optoelectronic device. Further provided is the use of the porous material as a photosensitizing, semiconducting material in an optoelectronic device. The invention additionally provides the use of a layer comprising the porous material as a photoactive layer in an optoelectronic device. Further provided is a photoactive layer for an optoelectronic device, which photoactive layer comprises the porous material.

    Microstructured Crystalline Device In Confined Space, A Dye-Sensitized Solar Cell, and Method of Preparation Thereof
    53.
    发明申请
    Microstructured Crystalline Device In Confined Space, A Dye-Sensitized Solar Cell, and Method of Preparation Thereof 有权
    密闭空间中的微结构晶体装置,染料敏化太阳能电池及其制备方法

    公开(公告)号:US20160351341A1

    公开(公告)日:2016-12-01

    申请号:US15235153

    申请日:2016-08-12

    IPC分类号: H01G9/20 C01B33/02 C01G9/02

    摘要: A method of forming an ordered nanorods array in a confined space is used to form a high surface area device where an ensemble of parallel trenches has micrometer dimensions for the width and depth of the trenches, which are decorated with crystalline nanowires radiating from the sidewalls and bases of the trenches. The high surface area device is formed by depositing a conformal crystalline seed coating in the trenches, forming microchannels from these trenches by placing a barrier layer on the open surface of the trenches, contacting the conformal coating with a crystal precursor solution that is caused to flow through the microchannels. In an embodiment, a very high surface area electrode is constructed with ZnO nanowires radiating from the sidewalls and base of trenches formed on a silicon substrate. The device can be a dye-sensitized solar cell.

    摘要翻译: 在密闭空间中形成有序纳米棒阵列的方法用于形成高表面积装置,其中平行沟槽的整体具有用于沟槽宽度和深度的微米尺寸,其用从侧壁辐射的晶体纳米线进行装饰, 壕沟的基地。 高表面积装置是通过在沟槽中沉积保形结晶种子涂层而形成的,通过在沟槽的开放表面上放置一个阻挡层,使该保形涂层与导致流动的晶体前体溶液接触,从这些沟槽中形成微通道 通过微通道。 在一个实施例中,非常高的表面积电极由从形成在硅衬底上的沟槽的侧壁和基底辐射的ZnO纳米线构成。 该装置可以是染料敏化太阳能电池。

    Method for forming a solar cell with tree-like nanostructure
    56.
    发明授权
    Method for forming a solar cell with tree-like nanostructure 有权
    形成具有树状纳米结构的太阳能电池的方法

    公开(公告)号:US09269840B2

    公开(公告)日:2016-02-23

    申请号:US13462911

    申请日:2012-05-03

    摘要: The present invention discloses a solar cell having a multi-layered structure that is used to generate, transport, and collect electric charges. The multi-layered nanostructure comprises a cathode, a conducting metal layer, a photo-active layer, a hole-transport layer, and an anode. The photo-active layer comprises a tree-like nanostructure array and a conjugate polymer filler. The tree-like nanostructure array is used as an electron acceptor while the conjugate polymer filler is as an electron donor. The tree-like nanostructure array comprises a trunk part and a branch part. The trunk part is formed in-situ on the surface of the conducting metal layer and is used to provide a long straight transport pathway to transport electrons. The large contact area between the branch part and the conjugate polymer filler provides electron-hole separation.

    摘要翻译: 本发明公开了一种具有多层结构的太阳能电池,其用于产生,运送和收集电荷。 多层纳米结构包括阴极,导电金属层,光活性层,空穴传输层和阳极。 光活性层包括树状纳米结构阵列和共轭聚合物填料。 树状纳米结构阵列用作电子受体,而共轭聚合​​物填料是电子给体。 树状纳米结构阵列包括树干部分和分支部分。 主体部分在导电金属层的表面上原地形成,并且用于提供长的输送电子的直线输送路径。 分支部分和共轭聚合物填料之间的大的接触面积提供电子 - 空穴分离。

    ASSEMBLIES AND METHODS OF STABILIZATION
    57.
    发明申请
    ASSEMBLIES AND METHODS OF STABILIZATION 审中-公开
    装配和稳定方法

    公开(公告)号:US20150294796A1

    公开(公告)日:2015-10-15

    申请号:US14646047

    申请日:2013-11-21

    IPC分类号: H01G9/20 C25B1/00

    摘要: Some embodiments of the present invention provide an assembly for harvesting light comprising a first molecule joined to a metal oxide surface through a surface linking group and a second molecule joined to the metal oxide surface. Such assemblies can harvest light to do useful chemistry, such as in a dye-sensitized photoelectrochemical cell, or a molecular catalyst-solar cell system. In other embodiments, the harvested light can be converted into electricity, such as in a dye-sensitized solar cell. Other embodiments of the present invention provide methods for stabilizing a chromophore or a catalyst on a surface. These methods are applicable, for example, to dye-sensitized photoelectrochemical cells where the surface-bound chromophores are known to be unstable under aqueous conditions.

    摘要翻译: 本发明的一些实施方案提供了一种用于收获光的组件,包括通过表面连接基团连接到金属氧化物表面的第一分子和连接到金属氧化物表面的第二分子。 这样的组件可以收获光以进行有用的化学,例如在染料敏化的光电化学电池中,或分子催化剂 - 太阳能电池系统中。 在其它实施方案中,所收获的光可以转化为电,例如在染料敏化太阳能电池中。 本发明的其它实施方案提供了在表面上稳定发色团或催化剂的方法。 这些方法适用于染料敏化的光电化学电池,其中表面结合的发色团已知在水性条件下是不稳定的。

    Photoelectric conversion device and electronic equipment
    58.
    发明授权
    Photoelectric conversion device and electronic equipment 有权
    光电转换装置及电子设备

    公开(公告)号:US09117594B2

    公开(公告)日:2015-08-25

    申请号:US14162394

    申请日:2014-01-23

    IPC分类号: H01L27/142 H01G9/20

    摘要: A photoelectric conversion device provided with an electron transport layer having an excellent electron transport ability and having an excellent photoelectric conversion efficiency, and electronic equipment provided with such a photoelectric conversion device and having a high reliability are provided. A solar cell, to which the photoelectric conversion device is applied, has a first electrode provided on a substrate, a second electrode arranged opposite to the first electrode and retained on a facing substrate, an electron transport layer provided between these electrodes and positioned on the side of the first electrode, a dye layer being in contact with the electron transport layer, and an electrolyte layer provided between the electron transport layer and the second electrode and being in contact with the dye layer. The electron transport layer includes particles of sodium trititanate.

    摘要翻译: 提供具有电子传输能力优异并且具有优异的光电转换效率的电子传输层的光电转换装置和具有这种光电转换装置并具有高可靠性的电子设备。 设置有光电转换装置的太阳能电池具有设置在基板上的第一电极,与第一电极相对设置并保持在面对基板上的第二电极,设置在这些电极之间并位于其上的电子传输层 第一电极的侧面,与电子传输层接触的染料层,以及设置在电子传输层和第二电极之间并与染料层接触的电解质层。 电子传输层包括三钛酸钠的颗粒。

    DYE-SENSITIZED SOLAR CELL AND METHOD FOR MANUFACTURING SAME
    60.
    发明申请
    DYE-SENSITIZED SOLAR CELL AND METHOD FOR MANUFACTURING SAME 有权
    透明的太阳能电池及其制造方法

    公开(公告)号:US20150090332A1

    公开(公告)日:2015-04-02

    申请号:US14398646

    申请日:2013-05-08

    发明人: Tae-Sik Kang

    IPC分类号: H01G9/20

    摘要: The present invention relates to a dye-sensitized solar cell and a fabrication method thereof. The dye-sensitized solar cell according to the present invention comprises: a transparent substrate; a porous semiconductor layer provided on the transparent substrate and comprising a dye sensitizer; a current collecting electrode provided on the porous semiconductor layer and deposited such that a structure having at least one through-hole on the porous semiconductor layer is formed; a catalyst electrode; and an electrolyte material provided between the transparent substrate and the catalyst electrode.

    摘要翻译: 染料敏化太阳能电池及其制造方法技术领域本发明涉及染料敏化太阳能电池及其制造方法。 根据本发明的染料敏化太阳能电池包括:透明基板; 设置在所述透明基板上并包含染料敏化剂的多孔半导体层; 设置在所述多孔半导体层上并沉积的集流电极,以形成在所述多孔半导体层上具有至少一个通孔的结构; 催化剂电极; 以及设置在透明基板和催化剂电极之间的电解质材料。