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    METAL MODIFIED PD/NI CATALYSTS
    53.
    发明申请
    METAL MODIFIED PD/NI CATALYSTS 失效
    金属改性PD / NI催化剂

    公开(公告)号：US20050038295A1

    公开(公告)日：2005-02-17

    申请号：US10824952

    申请日：2004-04-15

    申请人： Hao Ding

    发明人： Hao Ding

    IPC分类号： B01J23/89 ,  B01J37/02 ,  C07B61/00 ,  C07C209/16 ,  C07C209/36 ,  C07C209/48 ,  C07C211/05 ,  C07C211/07 ,  C07C211/50 ,  C07C211/51 ,  C07C29/32

    CPC分类号： C07C209/48 ,  B01J23/892 ,  B01J23/8926 ,  B01J23/8953 ,  B01J37/0242 ,  C07C209/16 ,  C07C209/36 ,  C07C211/05 ,  C07C211/07 ,  C07C211/51

    摘要： This invention relates to improved catalytic compositions suited for use in hydrogenation processes and to an improved process for hydrogenating organic compounds as in amination of alcohols or hydrogenation of nitrile and nitro groups to the amine using the catalyst. The catalytic composition is more particularly an improvement in nickel catalysts promoted with palladium carried on a support. The improvement resides in including a promoting effect of a metal M and/or its oxide, selected from Zn, Cd, Cu, and Ag, typically from about 0.01 to 10% by weight of the support.

    摘要翻译： 本发明涉及适用于氢化方法的改进的催化剂组合物，以及用于氢化有机化合物的改进方法，如醇的胺化或使用催化剂将腈和硝基氢化为胺。 催化组合物更特别地是用载持在载体上的钯促进的镍催化剂的改进。 改进在于包括选自Zn，Cd，Cu和Ag的金属M和/或其氧化物的促进作用，通常为载体重量的约0.01至10％。

    Metal modified Pd/Ni catalysts
    54.
    发明申请
    Metal modified Pd/Ni catalysts 失效
    金属改性Pd / Ni催化剂

    公开(公告)号：US20040199017A1

    公开(公告)日：2004-10-07

    申请号：US10825027

    申请日：2004-04-15

    发明人： Hao Ding

    IPC分类号： C07C29/36

    CPC分类号： C07C209/48 ,  B01J23/892 ,  B01J23/8926 ,  B01J23/8953 ,  B01J37/0242 ,  C07C209/16 ,  C07C209/36 ,  C07C211/05 ,  C07C211/07 ,  C07C211/51

    摘要： This invention relates to improved catalytic compositions suited for use in hydrogenation processes and to an improved process for hydrogenating organic compounds as in amination of alcohols or hydrogenation of nitro groups to the amine using the catalyst. The catalytic composition is more particularly an improvement in nickel catalysts promoted with palladium carried on a support. The improvement resides in including a promoting effect of a metal M and/or its oxide, selected from Zn, Cd, Cu, and Ag, typically from about 0.01 to 10% by weight of the support.

    摘要翻译： 本发明涉及适用于氢化方法的改进的催化剂组合物以及用于氢化有机化合物的改进方法，如醇的胺化或使用催化剂将硝基氢化为胺。 催化组合物更特别地是用载持在载体上的钯促进的镍催化剂的改进。 改进在于包括选自Zn，Cd，Cu和Ag的金属M和/或其氧化物的促进作用，通常为载体重量的约0.01至10％。

    Method for the production of amines from epoxidised olefins
    56.
    发明申请
    Method for the production of amines from epoxidised olefins 有权
    从环氧化烯烃生产胺的方法

    公开(公告)号：US20030028053A1

    公开(公告)日：2003-02-06

    申请号：US10182895

    申请日：2002-08-02

    发明人： Christian Ott ,  Marco Bergemann

    IPC分类号： C07C213/04

    CPC分类号： C07C231/02 ,  C07C209/16 ,  C07C213/04 ,  C07C211/09 ,  C07C237/06

    摘要： A process for preparing amines comprises reacting an epoxide of the formula (I) 1 where R1, R2, R3 and R4 are each, independently of one another, hydrogen or a linear or branched, saturated or unsaturated C2-C200-hydrocarbon radical, with ammonia and hydrogen in the presence of a catalyst, where the molar ratio of ammonia:epoxide is from 5:1 to 500:1 and the hydrogen pressure is from 10 bar to 500 bar.

    摘要翻译： 一种制备胺的方法包括使式（I）的环氧化物，其中R 1，R 2，R 3和R 4各自彼此独立地是氢或直链或支链，饱和或不饱和的C 2 -C 200烃基与氨 和催化剂存在下的氢气，其中氨：环氧化物的摩尔比为5:1至500:1，氢气压力为10巴至500巴。

    Catalyst and process for producing amines
    59.
    发明授权
    Catalyst and process for producing amines 失效
    催化剂和生产胺的方法

    公开(公告)号：US5817593A

    公开(公告)日：1998-10-06

    申请号：US459892

    申请日：1995-06-02

    申请人： Dane Chang ,  Fred A. Sherrod

    发明人： Dane Chang ,  Fred A. Sherrod

    IPC分类号： B01J23/889 ,  B01J23/89 ,  C07C209/02 ,  C07C209/16 ,  C07C211/10 ,  B01J21/02

    CPC分类号： C07C209/16 ,  B01J23/8896 ,  B01J23/8986 ,  Y02P20/582

    摘要： This invention includes catalysts comprising rhenium (atomic number 75), nickel, cobalt, boron and copper and/or ruthenium impregnated on a support material and a process for preparing said catalyst, said process comprising (i) impregnating a mixture of metals comprising rhenium, cobalt, copper and/or ruthenium, boron and nickel on a support material selected from the group consisting of alpha-alumina, silica, silica-alumina, kieselguhrs or diatomaceous earths, and silica-titanias; and (ii) activating said catalyst by heating the catalyst in the presence of hydrogen at an effective temperature preferably in the range of about 150.degree. C. to about 500.degree. C. for a sufficient period preferably of from about 30 minutes to about 6 hours. A further feature of the present invention is a method for producing amine products by the catalytic amination of alkane or arylalkane derivatives including epoxides, monols, diols, polyethers, polyols, alcoholamines, ketones, imino compounds iminoalcohols, ether alcohols, and mixtures thereof, said process comprising contacting said lower alkane or arylalkane derivatives with ammonia and/or reactant amine at an effective temperature preferably from 150.degree. C. to about 500.degree. C. and in the presence of hydrogen and the nickel-rhenium-cobalt-boron-copper and/or ruthenium catalyst as described hereinabove.

    摘要翻译： 本发明包括包含浸渍在载体材料上的铼（原子序号75），镍，钴，硼和铜和/或钌的催化剂和所述催化剂的制备方法，所述方法包括（i）浸渍包含铼， 钴，铜和/或钌，硼和镍在选自α-氧化铝，二氧化硅，二氧化硅 - 氧化铝，硅藻土或硅藻土的支撑材料上，以及二氧化硅 - 钛合金; 和（ii）通过在优选约150℃至约500℃的有效温度下在氢气存在下加热催化剂来活化所述催化剂足够的时间，优选约30分钟至约6小时 。 本发明的另一个特征是通过烷烃或芳基烷烃衍生物的催化胺化产生胺产物的方法，包括环氧化物，单醇，二醇，聚醚，多元醇，醇胺，酮，亚氨基化合物亚氨基醇，醚醇及其混合物。 方法包括使所述低级烷烃或芳基烷烃衍生物与氨和/或反应物胺在有效温度，优选150℃至约500℃，在氢气和镍 - 铼 - 钴 - 硼 - 铜和 /或如上所述的钌催化剂。

    Production of methylamines
    60.
    发明授权
    Production of methylamines 失效
    生产甲胺

    公开(公告)号：US5688854A

    公开(公告)日：1997-11-18

    申请号：US712886

    申请日：1996-09-12

    申请人： Takeyuki Fujita ,  Kiyonobu Niwa ,  Kazumoto Ogura ,  Michio Fukatsu

    发明人： Takeyuki Fujita ,  Kiyonobu Niwa ,  Kazumoto Ogura ,  Michio Fukatsu

    IPC分类号： C07C209/16 ,  C07C211/04

    CPC分类号： C07C209/16 ,  Y02P20/582

    摘要： Disclosed is an improvement in a process for catalytic production of methylamines from methanol and NH.sub.3, or methanol, a mixture of methylamines and NH.sub.3, or a mixture of methylamines and NH.sub.3, in a gaseous phase, over a bed of a zeolite catalyst, where the improvement is that the catalyst bed is divided into two or more sub-beds, and the difference between the inlet and outlet temperatures of each catalyst sub-bed is kept in the range of approximately 5.degree. C. to approximately 70.degree. C. while the reaction is carried out.

    摘要翻译： 公开了在沸石催化剂床上在气相中从甲醇和NH 3或甲醇，甲胺和甲胺，甲胺和NH 3的混合物或甲胺和NH 3的混合物催化制备甲胺的方法的改进，其中 改进之处在于催化剂床分为两个或更多个床层，每个催化剂床层的入口和出口温度之间的差别保持在约5℃至约70℃的范围内，而 进行反应。