公开(公告)号：US08703020B2

公开(公告)日：2014-04-22

申请号：US13501596

申请日：2009-10-12

申请人： Mingjie Zhou ,  Wenbo Ma ,  Zhaopu Shi

发明人： Mingjie Zhou ,  Wenbo Ma ,  Zhaopu Shi

IPC分类号： C09K11/78 ,  C09K11/77

CPC分类号： C09K11/7775 ,  C09K11/7793

摘要： Bismuth ion sensitized rare earth germanate luminescence materials and preparation methods are disclosed. The luminescence materials are the compounds of the following general formula (Y1-x-y-zAxBiyLnz)2GeO5. The preparation methods comprise: using oxides, carbonates, oxalates, acetates, nitrates or halides of Y, A, Bi, Ln and Ge as raw materials, wherein A is one of Gd, Lu, Sc and La, and Ln is at least one of Tm, Ho, Sm, Tb, Eu and Dy, homogeneously grinding the raw materials, sintering at 1300-1500° C. for 6-24 h, and then cooling them to room temperature to obtain the bismuth ion sensitized rare earth germanate luminescence materials.

摘要翻译： 公开了铋离子敏化稀土锗酸盐发光材料及制备方法。 发光材料是以下通式（Y1-x-y-zAxBiyLnz）2GeO5的化合物。 制备方法包括：以Y，A，Bi，Ln和Ge为原料的氧化物，碳酸盐，草酸盐，乙酸盐，硝酸盐或卤化物为原料，其中A为Gd，Lu，Sc和La之一，Ln为至少一种 的Tm，Ho，Sm，Tb，Eu和Dy，对原材料进行均匀研磨，在1300-1500℃下烧结6〜24h，然后冷却至室温，得到铋离子增感稀土锗酸盐发光 材料

公开(公告)号：US08696934B2

公开(公告)日：2014-04-15

申请号：US13254860

申请日：2009-03-06

申请人： Mingjie Zhou ,  Wenbo Ma ,  Zhaopu Shi

发明人： Mingjie Zhou ,  Wenbo Ma ,  Zhaopu Shi

IPC分类号： C09K11/02 ,  C09K11/08

CPC分类号： C09K11/7767

摘要： The present invention relates to oxide luminescent materials activated by trivalent thulium and their preparations. The luminescent materials are the compounds with the following general formula: (RE1-xTmx)2O3, wherein a range of x is 0

摘要翻译： 本发明涉及三价铯活化的氧化物发光材料及其制备方法。 发光材料是具有以下通式的化合物：（RE1-xTmx）2O3，其中x的范围为0

公开(公告)号：US08592333B2

公开(公告)日：2013-11-26

申请号：US13257314

申请日：2009-03-25

申请人： Mingjie Zhou ,  Wenbo Ma ,  Zhaopu Shi ,  Yanbo Qiao ,  Qingtao Li

发明人： Mingjie Zhou ,  Wenbo Ma ,  Zhaopu Shi ,  Yanbo Qiao ,  Qingtao Li

IPC分类号： C03C3/095 ,  C03C4/12 ,  C03B25/00 ,  C09K11/78 ,  C09K11/79

CPC分类号： C09K11/7774 ,  C03C3/095 ,  C03C4/12

摘要： A green light-emitting glass and the method of preparing the same are provided. The components with parts by mole of the green light-emitting glass are alkali oxide 25-40, Y2O3 0.01-15, SiO2 40-70, Tb2O3 0.01-15. The method of preparing the glass includes mixing alkali salt with Y2O3, SiO2 and Tb4O7, firing the mixture at 1200° C.-1500° C. for 1-5 hours, cooling the precursor to the room temperature and annealing the precursor in a reducing atmosphere at 600° C.-1200° C. for 1-20 hours. A green light-emitting glass with good transparence, high uniformity, easily being made into big bulk and high stability is provided. The process of capsulation of parts by using the glass is simple. And a method of preparing the glass with simple process and low cost is provided.

摘要翻译： 提供绿色发光玻璃及其制备方法。 具有摩尔比的绿色发光玻璃的组分是碱金属氧化物25-40，Y2O3 0.01-15，SiO2 40-70，Tb2O3 0.01-15。 制备玻璃的方法包括将碱金属盐与Y 2 O 3，SiO 2和Tb 4 O 7混合，将混合物在1200℃-1500℃下烧制1-5小时，将前体冷却至室温，并在还原 气氛在600℃-1200℃下保持1-20小时。 提供透明性好，均匀性好，容易制成大体积，高稳定性的绿色发光玻璃。 通过使用玻璃来封装部件的过程很简单。 并提供了一种以简单的工艺和低成本制备玻璃的方法。

公开(公告)号：US20130119313A1

公开(公告)日：2013-05-16

申请号：US13811859

申请日：2010-07-28

申请人： Mingjie Zhou ,  Wenbo Ma ,  Yanbo Qiao

发明人： Mingjie Zhou ,  Wenbo Ma ,  Yanbo Qiao

IPC分类号： C09K11/77

CPC分类号： C09K11/7774 ,  C09K11/873

摘要： A silicate fluorescent material is provided. The general chemical formula of the luminescent material is Ln2SiO5:Tb, M, wherein Ln represents at least one of the elements selected from Y, Gd, La or Lu, M represents at least one of the nanoparticles selected from Ag, Au, Os, Ir, Pt, Ru, Rh or Pd, the mole ratio of Tb to Ln is greater than 0 but not greater than 0.25. The porous glass containing metal nanoparticles is prepared by introducing metal nano ions into the porous glass and extracting the uniformly dispersed metal nanoparticles from the porous glass via a chemical reduction method. A silicate fluorescent material with enhanced luminescence is obtained by substituting SiO2 which is the raw material in the process for preparing the silicate fluorescent material via the conventional high temperature solid phase sintering with the porous glass containing metal nanoparticles. The performance of the silicate fluorescent material is better and the light emitting efficiency of the silicate fluorescent material is higher compared with the conventional silicate fluorescent material.

摘要翻译： 提供硅酸盐荧光材料。 发光材料的一般化学式为Ln2SiO5：Tb，M，其中Ln表示选自Y，Gd，La或Lu中的至少一种元素，M表示选自Ag，Au，Os， Ir，Pt，Ru，Rh或Pd，Tb与Ln的摩尔比大于0但不大于0.25。 通过将金属纳米离子引入多孔玻璃中并通过化学还原法从多孔玻璃中提取均匀分散的金属纳米粒子来制备含金属纳米颗粒的多孔玻璃。 通过用含有金属纳米颗粒的多孔玻璃的常规高温固相烧结来代替通过常规高温固相烧结制备硅酸盐荧光材料的方法中的原料SiO 2来获得具有增强发光的硅酸盐荧光材料。 与传统的硅酸盐荧光材料相比，硅酸盐荧光材料的性能更好，硅酸盐荧光材料的发光效率更高。

公开(公告)号：US20130082208A1

公开(公告)日：2013-04-04

申请号：US13702134

申请日：2010-06-17

申请人： Mingjie Zhou ,  Jun Liui ,  Wenbo Ma

发明人： Mingjie Zhou ,  Jun Liui ,  Wenbo Ma

IPC分类号： C09K11/87 ,  C09K11/77

CPC分类号： C09K11/873 ,  B82Y40/00 ,  C09K11/7718 ,  C09K11/87 ,  Y10S977/773 ,  Y10S977/896

摘要： Disclosed is a strontium cerate luminescent material having a chemical formula of Sr2CeO4:xM and comprising the luminescent material Sr2CeO4 and metal nanoparticle M, and the preparation method thereof, where M is at least one of Ag, Au, Pt and Pd, and x is a molar ratio of M to the luminescent material Sr2CeO4 and 0

摘要翻译： 公开了具有化学式Sr2CeO4：xM并且包含发光材料Sr2CeO4和金属纳米颗粒M的锶铈化物发光材料及其制备方法，其中M是Ag，Au，Pt和Pd中的至少一种，x是 M与发光材料Sr2CeO4的摩尔比为0

公开(公告)号：US20130075656A1

公开(公告)日：2013-03-28

申请号：US13702151

申请日：2010-06-09

申请人： Mingjie Zhou ,  Xiaofang Liang ,  Wenbo Ma

发明人： Mingjie Zhou ,  Xiaofang Liang ,  Wenbo Ma

IPC分类号： C09K11/77

CPC分类号： C09K11/7787

摘要： A luminescent material and a preparation method thereof are provided. The said luminescent material is represented by the following chemical formula: Ln2−EuxSn2O7, wherein Ln is selected from one of Gd, Y and La, 0.1≦x≦1.5. The said luminescent material has good electrical performance, anti-electron bombardment and stable luminescent property. It is appropriate to be used in field emission light-emitting devices. The said preparation method has simple technique, no pollution, manageable process conditions, low preparation temperature and low equipment requirement, and is beneficial to industry production.

摘要翻译： 提供发光材料及其制备方法。 所述发光材料由以下化学式表示：Ln2-EuxSn2O7，其中Ln选自Gd，Y和La中的一种，0.1＆nlE; x＆amp; ll; 1.5。 所述发光材料具有良好的电性能，抗电子轰击和稳定的发光性能。 适用于场发射发光装置。 所述制备方法技术简单，无污染，工艺条件可控，制备温度低，设备要求低，有利于工业生产。

公开(公告)号：US20130028824A1

公开(公告)日：2013-01-31

申请号：US13640353

申请日：2010-04-27

申请人： Mingjie Zhou ,  Shuxin Lu ,  Wenbo Ma

发明人： Mingjie Zhou ,  Shuxin Lu ,  Wenbo Ma

IPC分类号： C01B33/20

CPC分类号： C09K11/595

摘要： A preparation method of zinc manganese silicate is provided. The method includes the following steps: step 1, preparing silicon dioxide sol with distilled water, anhydrous ethanol and tetraethyl orthosilicate; step 2, preparing a mixture solution of a zinc salt and a manganese salt; step 3, adjusting the silicon dioxide sol to be neutral or acidic; step 4, adding the mixture solution of the zinc salt and the manganese salt into the silicon dioxide sol to form a gelatin; step 5, drying the gelatin, keeping the temperature, grinding, reducing with keeping the temperature in a reductive atmosphere to obtain zinc manganese silicate. The preparation method has simple technique and low equipment requirement. The particles of the zinc manganese silicate phosphor prepared by the method have a regular size, uniform shape and good luminescent performance.

摘要翻译： 提供了一种硅酸锌的制备方法。 该方法包括以下步骤：步骤1，用蒸馏水，无水乙醇和原硅酸四乙酯制备二氧化硅溶胶; 步骤2，制备锌盐和锰盐的混合溶液; 步骤3，调节二氧化硅溶胶为中性或酸性; 步骤4，将锌盐和锰盐的混合溶液加入到二氧化硅溶胶中以形成明胶; 步骤5，干燥明胶，保持温度，研磨，还原，保持温度在还原气氛中，得到硅酸锌锰。 制备方法技术简单，设备要求低。 通过该方法制备的硅酸锌锰粉末的颗粒具有规则的尺寸，均匀的形状和良好的发光性能。

公开(公告)号：US20130001444A1

公开(公告)日：2013-01-03

申请号：US13514959

申请日：2009-12-31

申请人： Mingjie Zhou ,  Wenbo Ma ,  Yanbo Qiao ,  Zhaopu Shi ,  Qingtao Li

发明人： Mingjie Zhou ,  Wenbo Ma ,  Yanbo Qiao ,  Zhaopu Shi ,  Qingtao Li

IPC分类号： F21V9/16 ,  G21K5/00

CPC分类号： C09K11/7734 ,  C03C14/006 ,  C03C17/22 ,  C03C2214/16 ,  F21V3/061 ,  F21V3/12 ,  F21V9/30 ,  F21Y2115/10 ,  H01L25/0753 ,  H01L33/507 ,  H01L2924/0002 ,  Y02B20/181 ,  H01L2924/00

摘要： The present invention relates to a white light luminescent device based on purple light LED. The white light luminescent device includes a housing, a support plate, at least one purple light LED semiconductor light source, and a piece of high silica luminescent glass. The support plate is received in the housing. The at least one purple light LED semiconductor light source is positioned on the support plate. The piece of high silica luminescent glass doped with Eu ions is opposite to the purple light LED semiconductor light source. One surface of the high silica luminescent glass away from the purple light LED semiconductor light source is coated with a phosphor layer formed with a selection from a mixture of yellow phosphor and red phosphor, a mixture of green phosphor and red phosphor, and yellow phosphor.

摘要翻译： 本发明涉及一种基于紫光LED的白光发光装置。 白光发光装置包括壳体，支撑板，至少一个紫色LED半导体光源和高二氧化硅发光玻璃片。 支撑板被容纳在壳体中。 至少一个紫光LED半导体光源位于支撑板上。 掺有Eu离子的高二氧化硅发光玻璃与紫光LED半导体光源相反。 远离紫色LED半导体光源的高二氧化硅发光玻璃的一个表面涂覆有由黄色荧光体和红色荧光体的混合物，绿色荧光体和红色荧光体的混合物以及黄色荧光体形成的荧光体层。

公开(公告)号：US20120270056A1

公开(公告)日：2012-10-25

申请号：US13497817

申请日：2009-09-25

申请人： Mingjie Zhou ,  Wenbo Ma

发明人： Mingjie Zhou ,  Wenbo Ma

IPC分类号： C09K11/00 ,  B05D5/06 ,  B05D1/02 ,  B32B17/06

CPC分类号： C03C27/06 ,  C03C14/006 ,  C03C17/008 ,  C03C2217/475 ,  C03C2217/48 ,  C09K11/025 ,  C09K11/7774

摘要： A luminescent glass comprises glass matrix. Said glass matrix comprises a glass part and a complex part of glass and fluorescent powder, which is embedded in said glass part. Said complex part of glass and fluorescent powder comprises glass material and fluorescent powder dispersed in said glass material. Said fluorescent powder is long after-glow fluorescent powder. A method for producing the luminescent glass and a luminescent device comprising the luminescent glass are also provided. The luminescent glass and the luminescent device have good luminescence reliability, high luminescence stability and long service life. The method can be carried out at a relatively low temperature.

摘要翻译： 发光玻璃包括玻璃基体。 所述玻璃基体包括玻璃部分和嵌入所述玻璃部分中的玻璃和荧光粉末的复合部分。 玻璃和荧光粉的所述复合部分包括分散在所述玻璃材料中的玻璃材料和荧光粉。 所述荧光粉是长辉光荧光粉。 还提供了制造发光玻璃的方法和包括发光玻璃的发光装置。 发光玻璃和发光装置具有良好的发光可靠性，高发光稳定性和长使用寿命。 该方法可以在相对较低的温度下进行。

公开(公告)号：US20120175661A1

公开(公告)日：2012-07-12

申请号：US13497921

申请日：2009-09-25

申请人： Mingjie Zhou ,  Wenbo Ma ,  Guitang Chen ,  Chaopu Shi ,  Yanbo Qiao ,  Xi Luo

发明人： Mingjie Zhou ,  Wenbo Ma ,  Guitang Chen ,  Chaopu Shi ,  Yanbo Qiao ,  Xi Luo

IPC分类号： H01L33/44 ,  H01L33/52

CPC分类号： H01L33/507 ,  H01L33/501 ,  H01L33/54 ,  H01L2224/48091 ,  H01L2924/00014

摘要： A semiconductor light emitting package includes a substrate, an encapsulating material, a semiconductor light emitting chip disposed on the substrate, wires; and an integrated glass-fluorescent powder compound light-emitting structure. The encapsulating material and the integrated glass-fluorescent powder compound light-emitting structure are packaged on the semiconductor light emitting chip, the integrated glass-fluorescent powder compound light-emitting structure is coated on the encapsulating material. The semiconductor light-emitting package has a large light-emitting area, high uniformity which can effectively avoid “halo” phenomenon, and long working life. The present invention also relates to a method for manufacturing semiconductor light emitting package, which can be implemented at low temperature and improve the reliability and the stability of the light-emitting property of the compound light-emitting structure.

摘要翻译： 半导体发光封装包括基板，封装材料，设置在基板上的半导体发光芯片，导线; 和集成的玻璃 - 荧光粉末化合物发光结构。 封装材料和集成的玻璃 - 荧光粉末化合物发光结构被封装在半导体发光芯片上，将集成的玻璃 - 荧光粉末化合物发光结构涂覆在封装材料上。 半导体发光封装具有发光面积大，均匀性高，可以有效地避免“晕”现象，使用寿命长。 本发明还涉及可以在低温下实现的半导体发光封装的制造方法，提高复合发光结构的发光特性的可靠性和稳定性。