摘要:
A polymer electrolyte membrane including a polysilsesquioxane group-containing copolymer and an ionic conductive polymer is provided. A method of preparing the polymer electrolyte membrane and a fuel cell including the polymer electrolyte membrane is also provided. The polymer electrolyte membrane has improved ion conductivity and an improved ability to suppress methanol crossover, and therefore can be used as an electrolyte membrane for a fuel cell, including a direct methanol fuel cell.
摘要:
A polymer electrolyte membrane including an ionic conducting polymer and a light-irradiated product of a photoacid generator (PAG), a method of manufacturing the same, and a fuel cell using the same. The polymer electrolyte membrane has excellent proton conductivity and homogeneity by radiating light such as UV light onto the PAG, thereby producing an acid radical which generates an acid. The polymer electrolyte membrane also suppresses methanol crossover well. The polymer electrolyte membrane can be used as an electrolyte membrane of a fuel cell, for example, a direct methanol fuel cell.
摘要:
An ion-conducting, sulfonated and crosslinked copolymer for use in a fuel cell is disclosed. The ion-conducting, sulfonated and crosslinked copolymer is made up of four monomers. The first monomer is an aromatic diol. The second monomer includes two groups, each group capable of reacting with the hydroxy groups of the first monomer, and each group independently selected from a nitro group and a halogen group. The third monomer is one of the first monomer or the second monomer, except that one of the hydrogen atoms attached to a benzene ring is substituted with —SO3Y, where Y is selected from hydrogen (H), lithium (Li), sodium (Na), potassium (K) and trialkyl ammonium of the form HNR3 where R is an alkyl group having from 1 to 5 carbon atoms. The fourth monomer includes at least three groups, each independently selected from a hydroxy group, a nitro group, and a halogen group.