摘要:
A method and apparatus for producing hydrogen using an aluminum-based water-split reaction, in which water is reacted with metallic aluminum, at least one-soluble inorganic salt catalyst that causes progressive pitting of the metallic aluminum, and at least one metal oxide initiator that increases temperature upon exposure to water. The solid reactant materials are differentially distributed in a matrix relative to at least one inlet for introducing water to the matrix. The differential distribution affects at least one characteristic of the reaction, such as the rate, temperature, pressure and products of the reaction, the latter comprising one or more of hydrogen, heat and steam. The water-soluble inorganic salt catalyst may be sodium chloride, potassium chloride and combinations thereof, and the metal oxide initiator may be magnesium oxide, calcium oxide and combinations thereof. The solid reactant materials may be differentially distributed by concentrating at least one of the solid reactant materials in at least one area of the matrix relative to the inlet. One or more of the solid reactant materials may be concentrated proximate the inlet so as to achieve a rapid initial reaction upon introduction of water, or may be concentrated in defined packets at spaced apart locations within the matrix to achieve a more moderated action. The solid reactant materials may be positioned in layers arranged concentrically or spirally about the water inlet. The layers may be formed of a water permeable substrate, such as a fiber wool or mat material having the reactant materials deposited thereon. The substrate including the reactant materials may be stored in a disposable container, to which water is introduced via the inlet at the time of use.
摘要:
This invention relates to hydrogen production using combined heat pumps and a thermochemical cycle. Low grade waste heat can be upgraded to higher temperatures via salt/ammonia and/or MgO/vapor chemical heat pumps, which release heat at successively higher temperatures through exothermic reactions, or vapor compression heat pumps that upgrade thermal energy with phase change fluids. Using this new approach, low grade heat or waste heat from nuclear or other industrial sources can be transformed to a useful energy supply for thermochemical hydrogen production.
摘要:
A fuel for splitting water into hydrogen and an oxide component comprises a substantially solid pellet formed from a solid-like mixture of a solid-state source material capable of oxidizing in water to form hydrogen and a passivation surface layer of the oxide component, and a passivation preventing agent that is substantially inert to water in an effective amount to prevent passivation of the solid-state material during oxidation. The pellets are brought into contact with an alloy of the passivation preventing agent having a melting point temperature below that of the solid-like mixture to initiate the hydrogen-producing reaction at a lower temperature.
摘要:
Embodiments of the invention relate to a fuel source including a chemical hydride and at least one reactive metal source selected from the group consisting of a reactive metal, a reactive metalloid and a combination thereof.
摘要:
A fuel for splitting water into hydrogen and an oxide component comprises a substantially solid pellet formed from a solid-like mixture of a solid-state source material capable of oxidizing in water to form hydrogen and a passivation surface layer of the oxide component, and a passivation preventing agent that is substantially inert to water in an effective amount to prevent passivation of the solid-state material during oxidation. The pellets may be introduced into water or other suitable oxidizer in a controlled rate to control the rate of reaction of the source material with the oxidizer, and thereby control the rate of formation of hydrogen. Methods are described for producing the solid-like mixture in varying weight percent of source material to passivation preventing agent.
摘要:
The methods and systems for producing hydrogen on demand use aluminum, a heat source and an electrical source, such as, but not limited to, solar power. The heat source and electrical source is used to produce chemical intermediates from sodium chloride via electrolysis. The chemical intermediates from the sodium chloride may be reacted with aluminum to produce hydrogen. The on-demand hydrogen systems can generate a continuous stream of hydrogen that can power a home or business. Alternatively, or in addition, the on-demand hydrogen system can be incorporated into a vehicle to power the vehicle.
摘要:
A method for producing hydrogen gas is provided and comprises reducing a metal oxide in a reduction reaction between a carbon-based fuel and a metal oxide to provide a reduced metal or metal oxide having a lower oxidation state, and oxidizing the reduced metal or metal oxide to produce hydrogen and a metal oxide having a higher oxidation state. The metal or metal oxide is provided in the form of a porous composite of a ceramic material containing the metal or metal oxide. The porous composite may comprise either a monolith, pellets, or particles.
摘要:
A method for producing hydrogen by using different metals includes: providing a metal of lower reduction potential as an anode metal and a metal of higher reduction potential as a cathode metal, then immerse the anode metal and the cathode metal in an electrolyte, while the anode metal and the cathode metal can be combined with appropriate steps before or after being immersed in the electrolyte, whereby hydrogen and side-products generated from a reaction of electrochemistry caused by reduction potential difference between the different metals, that is, the method for producing hydrogen is through spontaneous chemical reaction without extra energy consumption.
摘要:
The present invention relates to the production of hydrogen gas. More particularly, the present invention relates to: (1) a composition and process for the displacement of hydrogen from water under standard temperature and pressure conditions; (2) a hydrogen fuel system; (3) a method for using the hydrogen fuel system in conjunction with a feedstock composition to produce hydrogen gas (e.g., onboard a vehicle); and (4) a method of using the hydrogen fuel system at a reduced cost (e.g., by providing a consumer rebate in exchange for the return of byproduct(s) collected after using the hydrogen fuel system). The composition (e.g., a feedstock composition) comprises finely divided metal powders (e.g., magnesium, or magnesium and aluminum) and can also contain a chloride salt (e.g., sodium chloride or potassium chloride). The process of the present invention comprises adding a composition of the present invention to water (either water that already contains chloride ions—such as seawater—or, alternatively, with compositions that contain a chloride salt, either fresh water or seawater), at standard temperature and pressure conditions, in order to create hydrogen gas from the displacement of hydrogen from the water The methods of the present invention also comprises contacting the feedstock composition of the present invention with water (either water that already contains chloride ions—such as seawater—or, alternatively, with compositions that contain a chloride salt, either fresh water or seawater), at standard temperature and pressure conditions, in order to create hydrogen gas from the displacement of hydrogen from the water.
摘要:
An ultrasound system is disclosed that includes a tub, a reaction chamber, an ultrasound probe positioned within the reaction chamber, and a cooling jacket surrounding the tub for exchanging heat with the tub.