公开(公告)号：US20060216445A1

公开(公告)日：2006-09-28

申请号：US11442321

申请日：2006-05-30

申请人： Cynthia Ebner ,  Andrew Matthews ,  Terry Millwood

发明人： Cynthia Ebner ,  Andrew Matthews ,  Terry Millwood

IPC分类号： B32B27/10

CPC分类号： B32B27/18 ,  A23L3/3436 ,  B32B2307/74 ,  B32B2439/70 ,  C08G63/20 ,  C08G63/553 ,  C08K5/098 ,  C08K2201/012 ,  C08L67/06 ,  C09K15/04 ,  C09K15/32 ,  Y10T428/13 ,  Y10T428/1303 ,  Y10T428/1352 ,  Y10T428/31504 ,  Y10T428/31678 ,  Y10T428/31993 ,  C08L67/02 ,  C08L2666/02

摘要： An oxygen scavenger composition includes mer units that have at least one cycloalkenyl group or functionality and, further, has mer units derived from isophthalic acid or terephthalic acid or certain derivatives thereof. The oxygen scavenger composition has been found to act as an oxygen scavenger under both ambient and refrigeration conditions, to be compatible with conventional film forming packaging materials, to inhibit undesirable oligomer formation and oxidation by-product formation, and to be readily formable and processable using conventional film forming equipment. A film and laminated product having said oxygen scavenger composition are also disclosed.

摘要翻译： 除氧剂组合物包含具有至少一个环烯基或官能团的mer单元，并且还具有源自间苯二甲酸或对苯二甲酸或其某些衍生物的聚合单元。 已经发现氧气清除剂组合物在环境和制冷条件下用作除氧剂，以与常规的成膜包装材料相容，以抑制不期望的低聚物形成和氧化副产物形成，并且易于形成和可加工使用 常规成膜设备。 还公开了具有所述除氧剂组合物的薄膜和层压产品。

公开(公告)号：US20050261126A1

公开(公告)日：2005-11-24

申请号：US11130961

申请日：2005-05-17

申请人： Gianluca Ferrari ,  Edwin Sisson ,  Ricardo Knudsen

发明人： Gianluca Ferrari ,  Edwin Sisson ,  Ricardo Knudsen

IPC分类号： B01J23/00 ,  B29B9/12 ,  B29B13/02 ,  B32B33/00 ,  C08J3/00 ,  C08J3/12 ,  C08K5/00 ,  C08K5/098

CPC分类号： C08K5/098 ,  B29B9/12 ,  B29B13/021 ,  B29K2067/00 ,  C08J3/005 ,  C08J3/12 ,  C08J2323/06 ,  C08K2201/012 ,  C08L9/00 ,  C08L13/00 ,  C08L67/02 ,  C08L77/00 ,  Y10T428/2982 ,  Y10T428/2989 ,  Y10T428/2991 ,  Y10T428/2998 ,  Y10T428/31736 ,  C08L2666/04 ,  C08L2666/20

摘要： This invention discloses a process and a necessary article to simultaneously thermally treat at least two thermoplastics. The process utilizes the necessary compartmentalized or zoned pellet construction wherein the major amount of each thermoplastic component is located within individual compartments or zones of the pellet such that the components of the reaction during thermal processing and/or reactions with compounds in the atmosphere such as oxygen are less than the reaction if the thermoplastics were homogeneously dispersed in the pellet. This invention allows the components of the multi-component pellets to be thermally treated together without significant degradation and/or stored in air or in the presence of oxygen without significant degradation.

摘要翻译： 本发明公开了一种同时热处理至少两种热塑性塑料的方法和必要制品。 该方法利用必要的划分或分区的颗粒结构，其中每个热塑性组分的主要量位于颗粒的单独隔室或区域内，使得在热处理期间的反应成分和/或与大气中的化合物如氧气反应 如果热塑性塑料均匀地分散在颗粒中，则小于反应。 本发明允许多组分颗粒的组分在一起被热处理，而不会显着降解和/或储存在空气中或在存在氧的情况下而不会显着降解。

公开(公告)号：US20050148680A1

公开(公告)日：2005-07-07

申请号：US10746626

申请日：2003-12-24

申请人： Drew Speer

发明人： Drew Speer

IPC分类号： A23L3/3436 ,  B32B27/18 ,  B65D81/26 ,  C08K5/00 ,  C09K15/14 ,  C09K15/32 ,  B32B9/04 ,  C08G2/00

CPC分类号： B32B27/18 ,  A23L3/3436 ,  B32B27/08 ,  B32B2305/72 ,  B32B2307/514 ,  B32B2307/736 ,  B32B2307/74 ,  B32B2439/70 ,  B32B2439/80 ,  C08K5/0008 ,  C08K2201/012 ,  C09K15/32 ,  Y10T428/31504

摘要： An oxygen scavenger composition includes an organic oxygen scavenger, a transition metal catalyst, and a blend of at least two photoinitiators selected from 1,3,5-tris(4-benzoylphenyl)benzene, thioxanthone derivative, acyl phenylphosphineoxide derivative, and diphenyl sulfide derivative. A film includes at least one layer including an organic oxygen scavenger, a transition metal catalyst, and a blend of at least two photoinitiators selected from 1,3,5-tris(4-benzoylphenyl)benzene, thioxanthone derivative, acyl phenylphosphineoxide derivative, and diphenyl sulfide derivative. A method of triggering an oxygen scavenger composition includes providing an oxygen scavenger composition including an organic oxygen scavenger, a transition metal catalyst, and a blend of at least two of 1,3,5-tris(4-benzoylphenyl)benzene, thioxanthone derivative, acyl phenylphosphineoxide derivative, and diphenyl sulfide derivative; and subjecting the oxygen scavenger composition to a dosage of actinic radiation effective to trigger the oxygen scavenger composition.

摘要翻译： 除氧剂组合物包括有机氧清除剂，过渡金属催化剂和至少两种选自1,3,5-三（4-苯甲酰基苯基）苯，噻吨酮衍生物，酰基苯基膦氧化物衍生物和二苯硫醚衍生物的光引发剂的共混物 。 膜包括至少一层，包括有机氧清除剂，过渡金属催化剂和至少两种选自1,3,5-三（4-苯甲酰基苯基）苯，噻吨酮衍生物，酰基苯基膦氧化物衍生物和光催化剂的光引发剂的共混物， 二苯硫醚衍生物。 触发除氧剂组合物的方法包括提供包含有机氧清除剂，过渡金属催化剂和1,3,5-三（4-苯甲酰基苯基）苯，噻吨酮衍生物中的至少两种的共混物的除氧剂组合物， 酰基苯基膦氧化物衍生物和二苯硫醚衍生物; 并且使所述除氧剂组合物经受有效触发除氧剂组合物的光化辐射剂量。

公开(公告)号：US06878774B2

公开(公告)日：2005-04-12

申请号：US10003228

申请日：2001-12-06

申请人： Atsushi Kikuchi ,  Ikuo Komatsu ,  Toshiki Yamada ,  Yoshihiro Kitano ,  Go Saito

发明人： Atsushi Kikuchi ,  Ikuo Komatsu ,  Toshiki Yamada ,  Yoshihiro Kitano ,  Go Saito

IPC分类号： C08K5/56 ,  B32B27/08 ,  B32B27/18 ,  B32B27/36 ,  C08F279/00 ,  C08F279/02 ,  C08K5/098 ,  C08L23/08 ,  C08L51/04 ,  C08L77/00

CPC分类号： B32B27/08 ,  B32B27/18 ,  B32B27/306 ,  B32B27/34 ,  B32B27/36 ,  B32B2307/7244 ,  B32B2439/40 ,  C08F279/00 ,  C08F279/02 ,  C08K5/098 ,  C08K2201/008 ,  C08K2201/012 ,  C08L23/0861 ,  C08L51/04 ,  C08L2312/00 ,  C08L2666/24 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/04

摘要： A resin composition obtained by blending a thermoplastic resin that can be melt-extruded at a solubility parameter of not smaller than 9.5 with an organic oxidizing component and with a transition metal catalyst, the organic oxidizing component being a polyene having a functional group on a side chain or at a terminal thereof. The resin composition has excellent moldability and gas shut-off property. A multi-layer container having an oxygen-absorbing layer of this resin composition exhibits excellent gas-barrier property and is capable of favorably preserving the content.

摘要翻译： 将可溶性参数为9.5以上的可熔融挤出的热塑性树脂与有机氧化成分和过渡金属催化剂混合而获得的树脂组合物，有机氧化成分为侧面具有官能团的多烯 链或其末端。 树脂组合物具有优异的成型性和气体切断性。 具有该树脂组合物的氧吸收层的多层容器具有优异的阻气性，能够有利地保持该含量。

公开(公告)号：US20040176536A1

公开(公告)日：2004-09-09

申请号：US10802718

申请日：2004-03-18

申请人： TOYO SEIKAN KAISHA, LTD.

发明人： Atsushi Kikuchi ,  Ikuo Komatsu ,  Toshiki Yamada ,  Yoshihiro Kitano ,  Go Saito

IPC分类号： C08G081/00

CPC分类号： B32B27/08 ,  B32B27/18 ,  B32B27/306 ,  B32B27/34 ,  B32B27/36 ,  B32B2307/7244 ,  B32B2439/40 ,  C08F279/00 ,  C08F279/02 ,  C08K5/098 ,  C08K2201/008 ,  C08K2201/012 ,  C08L23/0861 ,  C08L51/04 ,  C08L2312/00 ,  C08L2666/24 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/04

摘要： A resin composition obtained by blending a thermoplastic resin that can be melt-extruded at a solubility parameter of not smaller than 9.5 with an organic oxidizing component and with a transition metal catalyst, the organic oxidizing component being a polyene having a functional group on a side chain or at a terminal thereof. The resin composition has excellent moldability and gas shut-off property. A multi-layer container having an oxygen-absorbing layer of this resin composition exhibits excellent gas-barrier property and is capable of favorably preserving the content.

摘要翻译： 将可溶性参数为9.5以上的可熔融挤出的热塑性树脂与有机氧化成分和过渡金属催化剂混合而获得的树脂组合物，有机氧化成分为侧面具有官能团的多烯 链或其末端。 树脂组合物具有优异的成型性和气体切断性。 具有该树脂组合物的氧吸收层的多层容器具有优异的阻气性，能够有利地保持该含量。

公开(公告)号：US20040081584A1

公开(公告)日：2004-04-29

申请号：US10683103

申请日：2003-10-10

发明人： Richard Dayrit ,  Scott W. Beckwith ,  Brian L. Butler ,  Ronald L. Cotterman ,  Drew V. Speer ,  Thomas D. Kennedy

IPC分类号： B32B005/02

CPC分类号： B32B27/08 ,  A23L3/3436 ,  B32B1/08 ,  B32B7/12 ,  B32B15/04 ,  B32B27/304 ,  B32B27/306 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B27/40 ,  B32B29/002 ,  B32B2307/7244 ,  B32B2311/00 ,  B32B2317/12 ,  B32B2323/043 ,  B32B2323/046 ,  B32B2323/10 ,  B32B2327/06 ,  B32B2329/04 ,  B32B2367/00 ,  B32B2375/00 ,  B32B2377/00 ,  B32B2439/40 ,  B32B2439/70 ,  B65B25/067 ,  B65B25/068 ,  B65B31/00 ,  B65B55/16 ,  B65B55/19 ,  B65D81/267 ,  C01B13/0281 ,  C08K5/0008 ,  C08K2201/012 ,  Y02E60/324

摘要： A method includes triggering an oxygen scavenger; and storing the scavenger in a container configured such that the oxygen scavenger exhibits no substantial oxygen scavenging activity while inside the container. The triggered oxygen scavenger can later be removed from the container, and used in packaging oxygen sensitive products. A stored oxygen scavenger, triggered, is also disclosed. A method of distributing an oxygen scavenger film includes providing a tubular film at a first location, the film having oxygen barrier and oxygen scavenger layers; triggering the oxygen scavenger; collapsing the film; rolling up the film; transporting the film to a second location; and triggering the oxygen scavenger. Another method of distributing an oxygen scavenger film includes providing an oxygen scavenger film at a first location; transporting the film to a second location; triggering the oxygen scavenger; storing the oxygen scavenger film in a container; and transporting the film to a third location.

摘要翻译： 一种方法包括触发除氧剂; 并将所述清除剂储存在容器中，所述容器被构造成使得所述除氧剂在所述容器内部不显示显着的氧清除活性。 触发的氧气清除剂可以稍后从容器中取出，并用于包装氧气敏感产品。 还公开了一种被触发的储存除氧剂。 分配除氧剂膜的方法包括在第一位置提供管状膜，所述膜具有氧气阻挡层和除氧剂层; 触发除氧剂 崩溃的电影 卷起电影; 将影片运送到第二位置; 并引发氧气清除剂。 分配除氧剂膜的另一种方法包括在第一位置提供氧清除膜; 将影片运送到第二位置; 触发除氧剂 将除氧剂膜储存在容器中; 并将影片运送到第三位置。

公开(公告)号：US20030144145A1

公开(公告)日：2003-07-31

申请号：US10024835

申请日：2001-12-19

发明人： Hu Yang ,  Ta Yen Ching ,  Peter Kwan

IPC分类号： B32B027/06

CPC分类号： C01B13/0262 ,  B01J20/26 ,  B32B27/06 ,  C01B13/0281 ,  C08K5/0008 ,  C08K5/098 ,  C08K2201/012 ,  Y10T428/1303 ,  Y10T428/1352 ,  Y10T428/1355 ,  Y10T428/1379 ,  Y10T428/31551 ,  Y10T428/31554 ,  Y10T428/31565 ,  Y10T428/31573 ,  Y10T428/31576 ,  Y10T428/3158 ,  Y10T428/31583 ,  Y10T428/31587 ,  Y10T428/31591 ,  Y10T428/31605 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31728 ,  Y10T428/31736 ,  Y10T428/3175 ,  Y10T428/31757 ,  Y10T428/31779 ,  Y10T428/31786 ,  Y10T428/3179 ,  Y10T428/31797 ,  C08L67/02

摘要： Herein is disclosed an oxygen scavenging composition, comprising (i) an oxygen scavenging polymer comprising units having structure I: 1 wherein R1 and R2 are independently selected from the group consisting of nullOnull, nullNCOnull, and nullNRnull, wherein R is selected from the group consisting of nullH and nullC1-C6 alkyls; (ii) a transition metal oxidation catalyst; and (iii) an energy-absorbing compound selected from the group consisting of microwave reactive materials and photoinitiators having a wavelength of maximum absorption of electromagnetic radiation from about 200 nm to about 750 nm. The oxygen scavenging composition can be used to form an oxygen scavenging packaging article.

摘要翻译： 本文公开了一种除氧组合物，其包含（i）含氧清除聚合物，其包含具有结构I的单元：其中R 1和R 2独立地选自-O - ， - NCO-和-NR-，其中R为 选自-H和-C 1 -C 6烷基; （ii）过渡金属氧化催化剂; 和（iii）选自微波反应物质和具有约200nm至约750nm的电磁辐射的最大吸收波长的光引发剂的能量吸收化合物。 除氧组合物可用于形成除氧包装制品。

公开(公告)号：US20020177635A1

公开(公告)日：2002-11-28

申请号：US10151358

申请日：2002-05-20

发明人： Philip H. Cook JR. ,  Melania M. Craddock ,  William A. Feehley ,  Nathanael R. Miranda ,  Drew V. Speer ,  Jeffrey Thomas

IPC分类号： C08K003/00 ,  A61L002/00

CPC分类号： B65B55/08 ,  A23L3/26 ,  A23L3/28 ,  A23L3/3436 ,  C08J3/28 ,  C08K5/0008 ,  C08K5/098 ,  C08K2201/012

摘要： A method for triggering an oxygen scavenging composition for use in packaging an oxygen sensitive article includes the steps of providing an oxygen scavenging composition comprising an oxidizable organic compound and, optionally, a transition metal catalyst, and exposing the composition to a source of pulsed light wherein each pulse has a duration of between 1 microsecond and 1 millisecond, a frequency of between 0.1 to 100 Hertz, and a total intensity of at least 350 mW/cm2 so that each pulse provides the composition with a dose of light of at least 0.1 J/cm2 so as to provide a triggered composition. The triggered composition can be applied to an article so as to provide an oxygen scavenging package. An apparatus and packaging system are also disclosed.

摘要翻译： 用于触发用于包装氧敏感物品的除氧组合物的方法包括提供包含可氧化有机化合物和任选的过渡金属催化剂的氧清除组合物并将组合物暴露于脉冲光源的步骤，其中 每个脉冲具有1微秒和1毫秒之间的持续时间，0.1至100赫兹之间的频率和至少350mW / cm2的总强度，使得每个脉冲为组合物提供至少0.1J的光的剂量 / cm2，以提供触发组合物。 可以将触发的组合物施用于制品以提供除氧包装。 还公开了一种装置和包装系统。

公开(公告)号：US5529833A

公开(公告)日：1996-06-25

申请号：US276125

申请日：1994-07-15

申请人： Drew V. Speer ,  Charles R. Morgan ,  William P. Roberts ,  Andrew W. VanPutte

发明人： Drew V. Speer ,  Charles R. Morgan ,  William P. Roberts ,  Andrew W. VanPutte

IPC分类号： C09K3/00 ,  A23L3/3436 ,  B01J20/26 ,  B32B27/08 ,  B32B27/18 ,  B65B55/00 ,  B65B55/19 ,  B65D81/24 ,  C01B13/02 ,  C08K5/098 ,  B29D22/00

CPC分类号： C08K5/098 ,  A23L3/3436 ,  B32B27/18 ,  C08K2201/012 ,  Y10S428/921 ,  Y10T428/1334 ,  Y10T428/1355 ,  Y10T428/1359 ,  Y10T428/24967 ,  Y10T428/25 ,  Y10T428/2826 ,  Y10T428/31913

摘要： Products and film structures using the oxygen scavengers, are disclosed. Such products demonstrate enhanced shelf stability of foodstuffs and reduced sensitivity to humidity and temperature changes.

摘要翻译： 公开了使用除氧剂的产品和膜结构。 这些产品表现出增强的食品储存稳定性，降低对湿度和温度变化的敏感性。

公开(公告)号：US5211875A

公开(公告)日：1993-05-18

申请号：US722067

申请日：1991-06-27

申请人： Drew V. Speer ,  William P. Roberts ,  Charles R. Morgan

发明人： Drew V. Speer ,  William P. Roberts ,  Charles R. Morgan

IPC分类号： C09K15/04 ,  A22C13/00 ,  B01D53/14 ,  B01J20/30 ,  B29C35/08 ,  B29C71/04 ,  B32B27/18 ,  B65D81/24 ,  B65D81/26 ,  C08F2/50 ,  C08J9/00 ,  C08K5/00 ,  C08K5/04 ,  C08K5/098 ,  C08L9/00 ,  C08L23/06 ,  C08L23/08 ,  C09K15/06

CPC分类号： B32B27/18 ,  A22C13/0013 ,  B29C71/04 ,  B65D81/267 ,  C08K5/0008 ,  C08K5/098 ,  C08L9/00 ,  B29C2035/0833 ,  B29C2035/0877 ,  B29K2023/06 ,  B29K2023/083 ,  B29K2096/00 ,  B29K2105/0085 ,  B29K2105/0088 ,  C08K2201/012 ,  C08L23/06 ,  C08L23/0853 ,  C08L23/30 ,  Y02P20/52 ,  Y10T428/1334 ,  Y10T428/1341 ,  Y10T428/1352 ,  Y10T428/1355 ,  Y10T428/1359

摘要： A method of initiating oxygen scavenging by compositions which comprise oxidizable organic compounds and transition metal catalysts is disclosed. The method comprises initiating scavenging by exposing the composition, etc., to radiation. The radiation exposure is preferably electron beam or ultraviolet light and is preferably used on oxygen scavenging compositions which comprise a substituted or unsubstituted ethylenically unsaturated hydrocarbon and a transition metal catalyst. Inclusion of a photoinitiator or antioxidant in the scavenging composition is also preferred to facilitate and/or control the composition's scavenging properties. The method can be used for initiating scavenging in packaging layers or articles for oxygen sensitive products such as food and beverage.