公开(公告)号：US07468333B2

公开(公告)日：2008-12-23

申请号：US10339971

申请日：2003-01-10

申请人： Wiliam C. Kimbrell, Jr. ,  Xinggao Fang ,  Yunzhang Wang ,  Dominick J. Valenti ,  Daniel T. McBride

发明人： Wiliam C. Kimbrell, Jr. ,  Xinggao Fang ,  Yunzhang Wang ,  Dominick J. Valenti ,  Daniel T. McBride

IPC分类号： B32B27/12 ,  B32B27/02 ,  D06C11/00

CPC分类号： D06M15/277 ,  D06M15/256 ,  D06M15/576 ,  D06M15/653 ,  D06M15/657 ,  D06M2101/32 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T442/2279 ,  Y10T442/2861

摘要： The present invention relates generally to substrates that exhibit useful, auto adaptable surface energy properties that depend on the environment of the substrate. Such surface energy properties provide relatively high advancing and receding contact angles for liquids when in contact with the target substrate surface. The substrates exhibit low surface energy quantities of at most about 20 millijoules per square meter (mJ/m2) at a temperature of about 25 degrees C. and a surface energy greater than about 20 mJ/m2 at, or with exposure to, a temperature of about 40 degrees C. More specifically, encompassed within the present invention are textile substrates having this highly desirable unique surface energy modification property and which exhibit wash durable oil and water repellency and stain release features. Novel compositions and formulations that impart such surface energy modifications to substrates are also encompassed within this invention, as well as methods for producing such treated substrates.

摘要翻译： 本发明一般涉及依赖于衬底环境的有用的，自动适应的表面能特性的衬底。 当与目标基板表面接触时，这种表面能量特性为液体提供相对高的前进和后退接触角。 这些基材在约25℃的温度下表现出低至多约20毫焦耳/平方米（mJ / m 2）的低表面能量，并且在暴露于温度时表面能大于约20mJ / m 2 更具体地，本发明中包括具有这种非常理想的独特表面能改性性能的织物基材，并且具有洗涤耐久的防油和防水性和脱色特性。 赋予基质的这种表面能改变的新型组合物和制剂也包括在本发明内，以及生产这种处理过的基材的方法。

公开(公告)号：US07217760B2

公开(公告)日：2007-05-15

申请号：US10471179

申请日：2002-03-06

申请人： Takuya Yoshioka ,  Masato Kashiwagi

发明人： Takuya Yoshioka ,  Masato Kashiwagi

IPC分类号： D06M15/277 ,  C08L27/12

CPC分类号： D06M15/277 ,  C08F212/14 ,  C08F214/18 ,  C08F214/182 ,  C08F220/22 ,  C08F220/24 ,  C09K3/18 ,  D06M15/227 ,  D06M15/248 ,  D06M15/263 ,  D06M15/576 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T428/2967 ,  C08F2/24 ,  C08F2/32

摘要： A fluoropolymer-based water-and-oil repellant composition which comprises a copolymer comprising units derived from (a) an ethylenic monomer having a perfluoroalkyl group, (b) an ethylenic monomer having a group comprising an aromatic ring and a halogen atom or halogenomethyl group bonded thereto, and (c) an ethylenic monomer copolymerizable with these. The composition imparts excellent water and oil repellency through cold cure.

摘要翻译： 一种含氟聚合物类防水斥油剂组合物，其包含共聚物，所述共聚物包含衍生自（a）具有全氟烷基的烯属单体的单元，（b）具有包含芳环和卤素原子的基团的烯属单体或卤代甲基 和（c）可与其共聚的乙烯类单体。 该组合物通过冷固化赋予优异的拒水拒油性。

公开(公告)号：US07105465B2

公开(公告)日：2006-09-12

申请号：US10887661

申请日：2004-07-09

申请人： Sanjay Patel ,  Michael David Draper

发明人： Sanjay Patel ,  Michael David Draper

IPC分类号： B32B5/02 ,  B32B27/04 ,  B32B27/12

CPC分类号： D06M14/00 ,  D06M15/53 ,  D06M15/568 ,  D06M15/576 ,  D21F1/30 ,  Y10T442/2221 ,  Y10T442/2238 ,  Y10T442/2279 ,  Y10T442/2287 ,  Y10T442/2311 ,  Y10T442/232 ,  Y10T442/2328 ,  Y10T442/3976 ,  Y10T442/696

摘要： An industrial textile including a polymeric substrate and a resin system grafted onto the polymeric substrate by way of a primer. The resin system includes a water-borne thermoplastic, a polyhydroxyether resin and/or an analogue of a polyhydroxyether resin, and at least one co-resin.

摘要翻译： 一种工业织物，其包括聚合物基材和通过底漆接枝到聚合物基材上的树脂体系。 树脂体系包括水性热塑性塑料，聚羟基醚树脂和/或聚羟基醚树脂的类似物，以及至少一种共树脂。

公开(公告)号：US07078454B2

公开(公告)日：2006-07-18

申请号：US10124523

申请日：2002-04-17

申请人： Malcolm B. Burleigh ,  David P. Cheatham ,  John C. Clark ,  A. Dale Otteson

发明人： Malcolm B. Burleigh ,  David P. Cheatham ,  John C. Clark ,  A. Dale Otteson

IPC分类号： C08J3/00 ,  C08K3/20 ,  C08L75/00 ,  B05D3/02 ,  B32B27/00

CPC分类号： C08F214/186 ,  C08G18/2885 ,  D06M15/27 ,  D06M15/277 ,  D06M15/576 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T428/31551

摘要： This invention provides compositions for treating fibrous substrates to render those substrates durably repellent to water and oil and durably resistant to dry soil comprising a 1) fluorochemical urethane formed by reacting a tri- or higher order isocyanate with a fluorochemical monofunctional compound and optionally a non-fluorinated aliphatic monofunctional compound; and 2) a fluorochemical polymeric surfactant.The present invention also provides a method of treating fibrous substrates to render those substrates durably repellent to water and oil and durably resistant to dry soil comprising application of the aforementioned composition to a fibrous substrate with optionally one or more stainblocker compounds such as acrylic and methacrylic acid polymers and copolymers, sulfonated phenol-formaldehyde resins, and styrene-maleic anhydride polymers and copolymers, said application of the composition taking place either coincident with or following application of the hydrophilic anti-staining compound or compounds to the substrate. Fibrous substrates treated according to this method and fibrous substrates treated with the aforementioned compositions are also disclosed.

摘要翻译： 本发明提供了用于处理纤维基材以使这些基材耐久地驱除水和油并且耐受干土的耐久性的组合物，其包含1）通过使三价或更高级异氰酸酯与含氟单官能化合物和任选的非官能化合物反应形成的含氟氨基甲酸酯， 氟化脂肪族单官能化合物; 和2）含氟聚合物表面活性剂。 本发明还提供了一种处理纤维基材以使这些基材耐久地驱除水和油并且耐久干燥的土壤的方法，其包括将上述组合物施用到纤维基材中，任选地包含一种或多种着色剂化合物如丙烯酸和甲基丙烯酸 聚合物和共聚物，磺化酚醛树脂和苯乙烯 - 马来酸酐聚合物和共聚物，所述组合物的应用与亲水性抗染色化合物或化合物一起施加或者应用于底物。 还公开了根据该方法处理的纤维基材和用上述组合物处理的纤维基材。

公开(公告)号：US20060110997A1

公开(公告)日：2006-05-25

申请号：US10996850

申请日：2004-11-24

申请人： Hue Snowden

发明人： Hue Snowden

IPC分类号： B32B27/04 ,  B32B5/02 ,  B32B27/12 ,  C11D3/00

CPC分类号： A61L15/225 ,  A61L15/52 ,  D06M15/267 ,  D06M15/277 ,  D06M15/576 ,  D06M15/657 ,  D06M2101/20 ,  D06M2200/00 ,  D06M2200/10 ,  Y10T442/2164 ,  Y10T442/2279 ,  Y10T442/2418

摘要： The present invention provides a method of treating a nonwoven fabric to provide the fabric with repellency to fluids while minimizing impact to the hydrostatic head properties of the fabric. Generally, the process includes contacting a nonwoven fabric with an aqueous treatment solution that includes a fluoropolymer and a polymeric antistatic agent.

摘要翻译： 本发明提供了一种处理无纺布以提供织物对流体排斥性同时最小化对织物的静水压头性能的影响的方法。 通常，该方法包括使非织造织物与包含含氟聚合物和聚合抗静电剂的水性处理溶液接触。

公开(公告)号：US07037440B2

公开(公告)日：2006-05-02

申请号：US10479549

申请日：2002-05-23

申请人： Harald Chrobaczek ,  Ralf Goretzki

发明人： Harald Chrobaczek ,  Ralf Goretzki

IPC分类号： C08L83/04 ,  D06M15/643

CPC分类号： D06M15/277 ,  C08G77/14 ,  C08G77/20 ,  C08G77/70 ,  C08L83/04 ,  D06M15/507 ,  D06M15/564 ,  D06M15/576 ,  D06M15/643 ,  C08L83/00

摘要： Aqueous dispersions comprising polyorganosiloxanes having relatively long alkyl groups and having aromatic groups and also polymers having perfluoroalkyl groups or fluorine-free polyurethanes are useful for treating textile fabrics.

摘要翻译： 包含具有较长烷基和芳族基团的聚有机硅氧烷的水性分散体以及具有全氟烷基或无氟聚氨酯的聚合物可用于处理纺织品。

公开(公告)号：US20050211945A1

公开(公告)日：2005-09-29

申请号：US10808902

申请日：2004-03-25

申请人： Dirk Coppens ,  Dean Moren

发明人： Dirk Coppens ,  Dean Moren

IPC分类号： D06M13/192 ,  D06M13/207 ,  D06M13/224 ,  D06M15/277 ,  D06M15/576 ,  C14C9/00

CPC分类号： D06M13/207 ,  D06M13/224 ,  D06M15/277 ,  D06M15/576

摘要： The present invention provides an aqueous composition comprising (i) a fluorochemical compound and (ii) an ester derivative of an alpha-hydroxy acid, the ester derivative having a melting point of not more than 35° C. and a water solubility of not more than 10% by weight at 25° C. The fluorochemical compound is typically dispersed or emulsified in the aqueous composition. The aqueous compositions may provide such advantages as providing good oil- and/or water repellency properties to a substrate upon application at ambient conditions, without the need for a heat treatment. Thus, the aqueous compositions may be used to provide oil- and/or water repellency properties to a substrate such as for example a fibrous substrate, e.g., leather or textile. In particular, repellency properties comparable to those achieved with a heat treatment step may be achieved.

摘要翻译： 本发明提供一种水性组合物，其包含（i）含氟化合物和（ii）α-羟基酸的酯衍生物，所述酯衍生物的熔点不超过35℃，水溶性不大于 在25℃下为10重量％以下。含氟化合物通常在水性组合物中分散或乳化。 含水组合物可以提供这样的优点，例如在环境条件下施用时向基材提供良好的油和/或拒水性质，而不需要热处理。 因此，水性组合物可用于向基材例如纤维基材例如皮革或纺织品提供油和/或拒水性能。 特别地，可以实现与通过热处理步骤实现的排斥性能相当的排斥性能。

公开(公告)号：US20050022313A1

公开(公告)日：2005-02-03

申请号：US10887034

申请日：2004-07-08

申请人： Karl Scheidler

发明人： Karl Scheidler

IPC分类号： C14C9/00 ,  D06M13/00 ,  D06M13/35 ,  D06M13/358 ,  D06M15/277 ,  D06M15/576 ,  D06M15/643 ,  D06M23/06 ,  D06M10/00

CPC分类号： D06M15/643 ,  C14C9/00 ,  D06M13/005 ,  D06M13/35 ,  D06M13/358 ,  D06M15/277 ,  D06M15/576 ,  D06M23/06 ,  D06M2200/25

摘要： One method includes applying to a post-manufactured textile material a liquid composition resulting from a combination of ingredients. The ingredients include one or more anti-fading compounds, one or more anti-soiling compounds, one or more silicon-based compounds, and one or more carrying media. One composition is a liquid composition resulting from a combination of ingredients, with the ingredients including a benzotriazole, a fluorocarbon, an organosiloxane, and odorless mineral spirits.

摘要翻译： 一种方法包括向后制造的纺织品材料施加由成分组合产生的液体组合物。 这些成分包括一种或多种抗褪色化合物，一种或多种防污化合物，一种或多种硅基化合物和一种或多种载体介质。 一种组合物是由成分的组合产生的液体组合物，其成分包括苯并三唑，碳氟化合物，有机硅氧烷和无味的矿物油精。

公开(公告)号：US20050009963A1

公开(公告)日：2005-01-13

申请号：US10913914

申请日：2004-08-06

申请人： Patrick Fitzgerald ,  Andrew Liu ,  Peter Murphy ,  Charles Strickler

发明人： Patrick Fitzgerald ,  Andrew Liu ,  Peter Murphy ,  Charles Strickler

IPC分类号： C08K5/00 ,  C08G18/28 ,  C08G18/38 ,  C08G18/78 ,  C08G18/79 ,  C08L75/04 ,  D06M13/144 ,  D06M13/325 ,  D06M13/463 ,  D06M15/576 ,  D06M101/04 ,  D06M101/12 ,  D06M101/18 ,  D06M101/32 ,  D06M101/34 ,  C08K5/33 ,  C08K5/17

CPC分类号： C08G18/7831 ,  C08G18/2885 ,  D06M15/576 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T428/23986 ,  Y10T428/249991 ,  Y10T428/2938 ,  Y10T428/2967 ,  Y10T428/31551 ,  Y10T428/31562 ,  Y10T442/2189 ,  Y10T442/2197 ,  Y10T442/2238 ,  Y10T442/2246 ,  Y10T442/2893

摘要： Carpet protectants comprising an aqueous dispersion comprising A. a partially fluorinated urethane polymer having at least one urea linkage, which compound is the product of the reaction of: (1) at least one organic polyisocyanate containing at least three isocyanate groups; (2) at least one fluorochemical compound which contains per molecule (a) a single functional group having one or more Zerewitinoff hydrogen atoms and (b) at least two carbon atoms, each of which is attached to at least two fluorine atoms; and (3) water in an amount sufficient to react with from about 5% to about 60% of the isocyanate groups in said polyisocyanate; B. a non-fluorinated cationic surfactant; and C. a non-fluorinated nonionic surfactant are disclosed.

摘要翻译： 地毯保护剂包含水分散体，其包含A.具有至少一个脲键的部分氟化的聚氨酯聚合物，该化合物是以下物质的反应产物：（1）至少一种含有至少三个异氰酸酯基团的有机多异氰酸酯; （2）至少一种含氟化合物，其每分子含有（a）具有一个或多个Zerewitinoff氢原子的单官能团和（b）至少两个碳原子，每个碳原子连接至少两个氟原子; 和（3）足以与所述多异氰酸酯中的约5％至约60％的异氰酸酯基反应的水; B.非氟化阳离子表面活性剂; 和C.一种非氟化非离子表面活性剂。

公开(公告)号：US20040137814A1

公开(公告)日：2004-07-15

申请号：US10339971

申请日：2003-01-10

发明人： Wiliam C. Kimbrell JR. ,  Xinggao Fang ,  Yunzhang Wang ,  Dominick J. Valenti ,  Daniel T. McBride

IPC分类号： B32B005/02

CPC分类号： D06M15/277 ,  D06M15/256 ,  D06M15/576 ,  D06M15/653 ,  D06M15/657 ,  D06M2101/32 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T442/2279 ,  Y10T442/2861

摘要： The present invention relates generally to substrates that exhibit useful, auto adaptable surface energy properties that depend on the environment of the substrate. Such surface energy properties provide relatively high advancing and receding contact angles for liquids when in contact with the target substrate surface. The substrates exhibit low surface energy quantities of at most about 20 millijoules per square meter (mJ/m2) at a temperature of about 25 degrees C. and a surface energy greater than about 20 mJ/m2 at, or with exposure to, a temperature of about 40 degrees C. More specifically, encompassed within the present invention are textile substrates having this highly desirable unique surface energy modification property and which exhibit wash durable oil and water repellency and stain release features. Novel compositions and formulations that impart such surface energy modifications to substrates are also encompassed within this invention, as well as methods for producing such treated substrates.

摘要翻译： 本发明一般涉及依赖于衬底环境的有用的，自动适应的表面能特性的衬底。 当与目标基板表面接触时，这种表面能量特性为液体提供相对高的前进和后退接触角。 基材在约25℃的温度下表现出低至多约20毫焦耳/平方米（mJ / m 2）的表面能，而表面能大于约20mJ / m 2，或 暴露于约40℃的温度。更具体地，本发明中包括具有这种非常理想的独特表面能改性性能的织物基材，并且其具有耐洗涤耐油和防水性和脱色特性。 赋予基质的这种表面能改变的新型组合物和制剂也包括在本发明内，以及生产这种处理过的基材的方法。