摘要:
New sealing adhesive bed compositions for glazing are form retaining and comprise elastomeric material initially mixed with plasticizers of low volatility and finely divided solids which either are of fibrous form or produce thixotropic mixtures with the plasticizers. A ratio range of from 3/4 to 21/2 parts non-volatile plasticizers to one part elastomeric material, and from 0.3 to 21/2 parts such finely divided solids to one part elastomeric material is present. Other kinds of finely divided solids and other ingredients may be present. The glazing strand is formed by extrusion, and the formed strand is not cured after extrusion. The tapes permanently deform under pressure when the glass is installed, have low spring back and exhibit little or no creep or cold flow in service.
摘要:
An adhesive composition comprises chlorobutyl rubber, an unsaturated ethylene-alpha olefin polymer of high molecular weight (as defined), carbon black, a liquid isobutene polymer, an ethylene alpha-olefin copolymer of low molecular weight (as defined), a tackifying resin and a sulphur vulcanisation system, each component being present in specified proportions. The adhesive composition is particularly useful in the preparation of an article of manufacture comprising at least two sheets of vulcanised EPDM rubber compositions, the edge portion of the sheets being adhered together at the interface by means of the adhesive composition which has been vulcanised after bringing said edges together.
摘要:
Process for bonding (1) vulcanizable composition comprising lowunsaturation ethylene/higher alpha-olefin/unconjugated diolefin terpolymer, a vulcanizing agent therefor and carbon black with (2) vulcanizable composition comprising natural rubber, a vulcanizing agent therefor and carbon black, this process comprising interposing between layers of compositions (1) and (2) a layer of (3) vulcanizable composition comprising a brominated copolymer of isobutene with about 0.5 - 5 percent by weight of isoprene, a vulcanizable agent therefor and carbon black, the carbon black in composition (3) having a lower activity than the carbon black in layers (1) and (2), contacting the three layers under pressure, and then heating at a temperature of 130* - 210* C to thereby covulcanize the three layers and obtain a high degree of adhesion therebetween.
摘要:
PROCESS FOR BONDING (1) VULCANIZABLE COMPOSITION COMPRISING LOW-UNSATURATION ETHYLENE/HIGHER ALPHA-OLEFIN/UNCONJUGATED DIOLEFIN TERPOLYMER, A VULCANIZING AGENT THEREFOR AND CARBON BLACK WITH (2) VULCANIZABLE COMPOSITION COMPRISING NATURAL RUBBER, A VULCANIZING AGENT THEREFOR AND CARBON BLACK, THIS PROCESS COMPRISING INTERPOSING BETWEEN LAYERS OF COMPOSITIONS (1) AND (2) A LAYER OF (3) VULCANIZABLE COMPOSITION COMPRISING A BROMINATED COPOLYMER OF ISOBUTENE WITH ABOUT 0.5-5% BY WEIGHT OF ISOPRENE, A VULCANIZING AGENT THEREFOR AND CARBON BLACK, THE CARBON BLACK IN COMPOSITION (3) HAVING A LOWER ACTIVITY THAN THE CARBON BLACK IN LAYERS (1) AND (2), CONTACTING THE THREE LAYERS UNDER PRESSURE, AND THEN HEATING AT A TEMPERATURE OF 130-210*C. TO THEREBY COVULCANIZE THE THREE LAYERS AND OBTAIN A HIGH DEGREE OF ADHESION THEREBETWEEN.
摘要:
An aqueous composition comprising 100 parts by weight of a halogenated butyl rubber and from 2 to 60 parts of a phenol-aldehyde resin is used to coat fibrous material. The butyl rubber copolymer comprises 85 to 99.5 weight per cent of an iso-olefine of 4 to 8 carbon atoms, e.g. isobutylene and 0.5 to 15 weight per cent of a multiolefine of 4 to 10 carbon atoms, e.g. butadiene, dimethyl butadiene, piperylene or isoprene and the halogen content is 0.5 weight per cent of combined halogen and not more than one combined atom of chlorine or three combined atoms of bromine per double bond in the copolymer. The phenol-aldehyde resins may be derived from compounds such as phenols, cresols, phloroglucinol, xylenol, tri-methyl, mono- or dichlorodiamyl or diisopropyl, p-tert. butyl and p-phenyl phenols, hydroquinone and resorcinol and aldehydes such as formaldehyde paraformaldehyde, acetaldehyde and furfural. The compositions may be prepared by dissolving the halogenated rubber in a hydrocarbon solvent e.g. hexane, and emulsifying with water containing from between 0.5 and 20 weight per cent of emulsifier, and non-ionic, anionic and cationic types are listed. The solvent is removed by stripping. The rubber latex may be mixed with an aqueous solution containing the phenol and aldehyde, and the pH of the mixture adjusted, for example by caustic soda to between 7.5 and 9, and the mixture is then allowed to stand until condensation takes place. A phenol dialcohol, in an amount of, from 1 to 35 parts by weight may also be added to the dispersion. Cord, filament or layers of fabric dipped in the composition, dried, and embedded in rubber which is then vulcanized with the usual agents, show improved adhesion to the rubber, and are suitable for use as tyres and reinforced laminated structures such as conveyer belts.ALSO:A fibrous material, e.g. of cotton, rayon, silk or nylon, is coated with an aqueous composition comprising 100 parts by weight of a halogenated butyl rubber and 2-60 parts of a phenol-aldehyde resin, whereby its adhesion to butyl rubber, after vulcanization at from 250-400 DEG F., is improved. The fibres may be in the form of a cord or a single layer of fabric, which may be coated on one or both sides with the composition. The butyl rubber copolymer comprises 85-99.5 weight per cent of an isoolefine of 4-8 carbon atoms, e.g. isobutylene, and 0.5-15 weight per cent of a multiolefine of 4-10 carbon atoms, e.g. butadiene, dimethyl butadiene, piperylene or isoprene, and the halogen content is 0.5 weight per cent, not more than one combined atom of chlorine or three combined atoms of bromine being present per double bond in the copolymer. The phenolaldehyde resins may be derived from compounds such as phenols, cresols, phloroglucinol, xylenol, trimethyl-, mono- or dichloro-, diamyl-, diisopropyl-, p-tert. butyl- and p-phenyl-phenols, hydroquinone and resorcinol, and aldehydes such as formaldehyde, paraformaldehyde, acetaldehyde and furfural. Emulsifiers, and a phenol dialcohol in an amount of 1-35 parts by weight, may also be present in the dispersion.
摘要:
An adhesive composition is described comprising a tackifier and at least one grafted isobutylene copolymer. The grafted isobutylene copolymer has the formula: R1—(R2—Z) wherein R1 represents an isobutylene copolymer, R2 is a covalent bond or multivalent alkylene or arylene, and Z is a grafted polymer. Z is typically a homopolymer of copolymer comprising alkene repeat units, aralkylene repeat units, or a combination thereof. Also described are adhesive coated articles, methods of making adhesive coated articles, and grafted isobutylene polymers.
摘要:
A pressure-sensitive adhesive composition containing a pressure-sensitive adhesive that contains from 40 to 95% by mass of a rubber-based resin not containing a styrene-derived constituent unit, and a photochromic dye of a dithienylethene-based compound, wherein the content of the photochromic dye is from 0.40 to 8.00 parts by mass relative to 100 parts by mass of the pressure-sensitive adhesive, and a pressure-sensitive adhesive sheet having a pressure-sensitive adhesive layer formed of the pressure-sensitive adhesive composition have excellent weather resistance that can withstand long-term use, a relatively rapid rate of color change from colored to colorless, and excellent peelability to release sheets.
摘要:
A pressure-sensitive adhesive polymeric composition comprising: a butyl rubber; a polyurethane; an olefinic polymer component; and a filler that includes titanium dioxide, wherein said adhesive polymeric composition is pressure-sensitive, and where pressure-sensitive adhesive polymeric composition is a solids composition wherein said butyl rubber forms a matrix.