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    Triarylmethane color formers
    22.
    发明授权
    Triarylmethane color formers 失效
    三芳基甲烷成色剂

    公开(公告)号：US5233048A

    公开(公告)日：1993-08-03

    申请号：US942112

    申请日：1992-09-08

    申请人： Udo Eckstein ,  Roderich Raue

    发明人： Udo Eckstein ,  Roderich Raue

    IPC分类号： B41M5/136 ,  B41M5/323 ,  C07D249/08 ,  C09B11/10 ,  C09B11/26

    CPC分类号： C09B11/26 ,  B41M5/1366 ,  B41M5/323 ,  C09B11/10

    摘要： Color formers of the general formula ##STR1## in which --independently of one another-- R.sup.1 and R.sup.2 are hydrogen, halogen, alkyl, aralkyl etc.,Y.sup.1 and Y.sup.2 are alkyl, aryl, cycloalkyl or aralkyl,X.sup.1 is alkyl, alkenyl, cycloalkyl, aralkyl etc.,X.sup.2 is H, alkyl, alkenyl, cycloalkyl etc.X.sup.1 with X.sup.2 with the inclusion of the nitrogen atom carrying them can form a saturated or unsaturated 5- or 6-membered heterocyclic ring, andfurther isocyclic or heterocyclic rings can be fused with the rings A, B and C, upon incorporation in recording materials based on acid developers, show a particularly advantageous migration behaviour. Deep blue, green-blue, green, violet or red shades which have excellent sublimation and light fastness are obtained.

    摘要翻译： 通式（Ⅰ）所示的成色剂 - 其中R 1和R 2彼此独立地为氢，卤素，烷基，芳烷基等，Y 1和Y 2为烷基，芳基，环烷基或芳烷基，X 1为烷基， 烯基，环烷基，芳烷基等，X 2是H，烷基，烯基，环烷基等。具有包含含有氮原子的X 2的X 1可以形成饱和或不饱和的5-或6-元杂环，并且还可以是环或 当结合到基于酸显影剂的记录材料中时，杂环可以与环A，B和C稠合，显示出特别有利的迁移行为。 获得了具有极好升华和耐光牢度的深蓝色，绿色 - 蓝色，绿色，紫色或红色色调。

    Triarylmethane color-forming agents
    23.
    发明授权
    Triarylmethane color-forming agents 失效
    三色甲醛成色剂

    公开(公告)号：US5094688A

    公开(公告)日：1992-03-10

    申请号：US231796

    申请日：1988-08-12

    申请人： Udo Eckstein ,  Hubertus Psaar ,  Gert Jabs

    发明人： Udo Eckstein ,  Hubertus Psaar ,  Gert Jabs

    IPC分类号： C09B11/00 ,  B41M5/136 ,  B41M5/323 ,  C09B11/26

    CPC分类号： C09B11/26 ,  B41M5/1366 ,  B41M5/323

    摘要： Color-forming agents of the present formula ##STR1## wherein X denotes hydroxyl, alkoxy, alkenyloxy, aralkoxy, cycloalkoxy, aryloxy, acyloxy, alkylamino, dialkylamino, acylamino, aralkylamino or arylamino,R denotes alkyl, alkenyl or aralkyl,R.sub.1 denotes hydrogen, halogen or alkyl,R.sub.2 denotes alkoxy, aralkoxy, aryloxy or a radical of the formula ##STR2## Y.sub.1 and Y.sub.2 independently of one another denote alkyl, aryl, cycloalkyl or aralkyl or R.sub.2, with A in the o-position, forms a heterocyclic ring,a benzene ring can be fused onto the ring A, in the o-/m-position relative to R.sub.2, and the ring A and its fused-on rings and the cyclic and acyclic radicals can carry further non-ionic substitutents customary in dyestuffs chemistry,are used in thermoreactive papers and pressure-sensitive recording materials and for the preparation of highly concentrated solutions in organic solvents.

    摘要翻译： 本发明的成色剂（I）其中X表示羟基，烷氧基，烯氧基，芳烷氧基，环烷氧基，芳氧基，酰氧基，烷基氨基，二烷基氨基，酰氨基，芳烷基氨基或芳基氨基，R表示烷基，烯基或芳烷基 表示氢，卤素或烷基，R 2表示烷氧基，芳烷氧基，芳氧基或式Y 1和Y 2基团彼此独立地表示烷基，芳基，环烷基或芳烷基或R 2，其中位于O位的A形成 一个杂环，一个苯环可以相对于R2在o- / m-位上的A环上融合，并且环A及其稠合的环和环状和非环状的基团可以携带更多的非离子取代基 常用于染料化学，用于热反应纸和压敏记录材料以及在有机溶剂中制备高浓度溶液。

    Triphenyl methane derivatives and method of quantitatively measuring an oxidative substance
    24.
    发明授权
    Triphenyl methane derivatives and method of quantitatively measuring an oxidative substance 失效
    三苯甲烷衍生物和定量测定氧化物质的方法

    公开(公告)号：US4613465A

    公开(公告)日：1986-09-23

    申请号：US649477

    申请日：1984-09-11

    申请人： Kazuhiko Yamanishi ,  Akinori Shintani ,  Satoru Okajima ,  Toshiro Hanada

    发明人： Kazuhiko Yamanishi ,  Akinori Shintani ,  Satoru Okajima ,  Toshiro Hanada

    IPC分类号： B41M5/136 ,  C09B11/00 ,  C09B11/12 ,  C09B11/14 ,  C12Q1/28 ,  C09B11/10

    CPC分类号： B41M5/1366 ,  C09B11/12 ,  C12Q1/28 ,  C12Q2326/40 ,  Y10S436/904 ,  Y10T436/206664

    摘要： Disclosed herein is a novel compound which is excellent in solubility to water around a neutral range, stable in an aqueous solution state for a long period of time, and high in coloring sensitivity with a stable coloring development, and is represented by the general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same as or different from one another, represent lower alkyl groups, and X.sub.1 and X.sub.2 both represent --O(CH.sub.2).sub.n SO.sub.3 M in which M is a hydrogen atom, an alkali metal ion or NH.sub.4.sup.+, and n is an integer of 2-4, or either of X.sub.1 and X.sub.2 represents --O(CH.sub.2).sub.n SO.sub.3 M in whch M and n are the same meanings as given above and the other represents a hydrogen atom. This reagent is hardly susceptible of the influence of the serum components such as hemoglobin, bilirubin and so on due to its color having absorption on a longer wavelength side. Disclosed is also a method of quantitatively measuring an oxidative substance, particularly, hydrogen peroxide, by using this color test reagent.

    摘要翻译： 本文公开了一种新颖的化合物，其在中性范围内对水的溶解性优异，在水溶液状态下长时间稳定，着色敏感性高，稳定的显色性，并且由通式（ I）：其中R 1，R 2，R 3和R 4可以相同或不同，表示低级烷基，X 1和X 2均表示-O（CH 2）n SO 3 M，其中M 是氢原子，碱金属离子或NH 4 +，n是2-4的整数，或者X 1和X 2中的任一个表示-O（CH 2）n SO 3 M，m和n与上述相同，而另一个 表示氢原子。 该试剂由于其在长波长侧具有吸收的颜色，几乎不受血清成分如血红蛋白，胆红素等的影响。 还公开了通过使用该颜色试验剂定量测定氧化物质，特别是过氧化氢的方法。

    Bis phenyl (2 carboxylic acid or ester indol-3-yl)methanes
    25.
    发明授权
    Bis phenyl (2 carboxylic acid or ester indol-3-yl)methanes 失效
    双苯基（2羧酸或酯吲哚-3-基）甲烷

    公开(公告)号：US4558137A

    公开(公告)日：1985-12-10

    申请号：US501309

    申请日：1983-06-06

    申请人： Paul J. Schmidt ,  William M. Hung

    发明人： Paul J. Schmidt ,  William M. Hung

    IPC分类号： B41M5/136 ,  C07D209/08 ,  C07D209/10 ,  C07D455/04 ,  C07D209/42

    CPC分类号： B41M5/1366 ,  C07D209/08 ,  C07D209/10 ,  C07D455/04

    摘要： The invention provides processes for the preparation of both known and novel [bis(substituted-aryl) (indolyl)]methanes and [(substituted-aryl) (heteryl) (indolyl)]methanes, useful as color formers, particularly in carbonless duplicating and thermal marking systems, which comprises the interaction of [bis(substituted-aryl) (phenylsulfonyl)]methanes and [(substituted-aryl) (heteryl) (phenylsulfonyl)]methanes with indoles in the presence of either an alkaline or an acidic catalyst.

    摘要翻译： 本发明提供用于制备已知和新颖的[双（取代 - 芳基）（吲哚基）]甲烷和[（取代的 - 芳基）（杂芳基）（吲哚基）]甲烷的方法，可用作成色剂，特别是在无碳复制和 包括在碱性或酸性催化剂存在下，[双（取代 - 芳基）（苯基磺酰基）]甲烷和[（取代的 - 芳基）（杂芳基）（苯基磺酰基）]甲烷与吲哚的相互作用的热标记系统。

    Pressure sensitive recording unit
    29.
    发明授权
    Pressure sensitive recording unit 失效
    压敏记录单元

    公开(公告)号：US4398753A

    公开(公告)日：1983-08-16

    申请号：US330325

    申请日：1981-12-14

    申请人： Makoto Asano ,  Kiyoharu Hasegawa ,  Hiroyuki Akahori ,  Michihiro Tsujimoto

    发明人： Makoto Asano ,  Kiyoharu Hasegawa ,  Hiroyuki Akahori ,  Michihiro Tsujimoto

    IPC分类号： B41M5/124 ,  B41M5/136 ,  B41L1/20

    CPC分类号： B41M5/136 ,  B41M5/1366 ,  Y10S428/914

    摘要： Disclosed is a pressure sensitive recording unit which comprises a single base web sheet and a methine-type dyestuff and an organic oxidizing compound both supported on the single base web sheet, or a combination of first and second base web sheets and the methine-type dyestuff and organic oxidizing compound supported individually on the first and second base web sheets. Such a recording unit includes for example a pressure sensitive recording unit formed in combination of (a) a back-coated topsheet (CB-sheet) making use of microscopic capsules containing a solution obtained by dissolving a methine-type dyestuff in a solvent having a high boiling point and (b) a front-coated undersheet (CF-sheet) carrying an organic oxidizing compound coated thereon. Also disclosed is a pressure sensitive recording unit which includes a base web sheet carrying thereon such a methine-type dyestuff together with a metal ion sequestering agent and/or alkanol amine.

    摘要翻译： 公开了一种压敏记录单元，其包括单个基网网片和次甲基型染料和有机氧化剂，两者均支撑在单个基网幅材上，或第一和第二基网幅片与次甲基型染料 和在第一和第二基底幅片上分别支撑的有机氧化剂。 这样的记录单元包括例如压敏记录单元，其组合使用（a）使用含有通过将次甲基型染料溶解在溶剂中而得到的溶液的微观胶囊的背面涂布的顶片（CB片） 高沸点和（b）在其上涂覆有有机氧化剂的前涂底片（CF-片）。 还公开了一种压敏记录单元，其包括其上承载有次甲基型染料的基础网片与金属离子螯合剂和/或链烷醇胺。

    Associated dye salts and method of forming colored indicia therewith
    30.
    再颁专利
    Associated dye salts and method of forming colored indicia therewith 失效
    相关染料盐及其形成有色标记的方法

    公开(公告)号：USRE30797E

    公开(公告)日：1981-11-17

    申请号：US850027

    申请日：1977-11-09

    申请人： Chester Davis

    发明人： Chester Davis

    IPC分类号： B41M5/136

    CPC分类号： B41M5/1366

    摘要： .Iadd.Described herein are methods of printing which comprise applying to an unfired silicate surface characterized by high ionizing power a substantially colorless associated salt of an arylmethane dye base characterized by a logarithmic dissociation constant below 7 and an organic sulfinic acid whereby physical contact of the associated compound and the silicate dissociates the compound to the intensely colored cation of the dye and produces color on the silicate surface. .Iaddend. .Iadd.