公开(公告)号：US20120259078A1

公开(公告)日：2012-10-11

申请号：US13517038

申请日：2010-12-17

Applicant: Diego Brita ,  Gianni Collina ,  Daniele Evangelisti ,  Anna Fait ,  Benedetta Gaddi ,  Giampiero Morini ,  Pietro Baita ,  Lorella Marturano ,  Harry Mavridis

Inventor： Diego Brita ,  Gianni Collina ,  Daniele Evangelisti ,  Anna Fait ,  Benedetta Gaddi ,  Giampiero Morini ,  Pietro Baita ,  Lorella Marturano ,  Harry Mavridis

IPC: C08F4/76 ,  C08F4/646 ,  C08F4/649 ,  C08F110/02

CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F2410/03 ,  C08F4/6543 ,  C08F4/6545 ,  C08F4/6494 ,  C08F2/001 ,  C08F2500/07 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/14 ,  C08F2500/18 ,  C08F2500/11

Abstract: Catalyst component comprising Mg, Ti, and halogen atoms, and is characterized in that (a) the Ti atoms are present in an amount higher than 4% based on the total weight of the said catalyst component, (b) the amount of Mg and Ti atoms is such that the Mg/Ti molar ratio is higher than 2 and (c) by a X-ray diffraction spectrum, in which, in the range of 2θ diffraction angles between 47° and 52°, at least two diffraction lines are present at diffraction angles 2θ of 48.3±0.2°, and 50.0±0.2°, the most intense diffraction lines being the one at 2θ of 50.0±0.2°, the intensity of the other diffraction line being equal to or lower than the intensity of the most intense diffraction line.

Abstract translation: 包含Mg，Ti和卤素原子的催化剂组分，其特征在于（a）Ti原子以基于所述催化剂组分的总重量高于4％的量存在，（b）Mg和 Ti原子使得Mg / Ti摩尔比高于2，（c）通过X射线衍射光谱，其中在2θ的范围内; 衍射角在47°和52°之间，至少两条衍射线存在于衍射角2°处; 分别为48.3±0.2°和50.0±0.2°，最强烈的衍射线为2°; 为50.0±0.2°，其他衍射线的强度等于或低于最强衍射线的强度。

公开(公告)号：US07560521B2

公开(公告)日：2009-07-14

申请号：US11200618

申请日：2005-08-05

Applicant: Gianni Collina ,  Ofelia Fusco ,  Diego Brita

Inventor： Gianni Collina ,  Ofelia Fusco ,  Diego Brita

IPC: C08F4/44 ,  C08F210/00

CPC classification number: C08F10/00 ,  C08F4/651 ,  C08F4/6543

Abstract: A catalyst component for the polymerization of olefins comprising a titanium compound, a Mg-dihalide, a difunctional electron donor compound (ED) selected from diesters, diketones, diamines or diethers, and a monofunctional electron donor compound (MD) selected from ethers, esters, amines or ketones, wherein a molar ratio ED/MD is higher than 10.

Abstract translation: 用于烯烃聚合的催化剂组分，包括钛化合物，二卤化镁，选自二酯，二酮或二醚的双官能电子给体化合物（ED）和选自醚，酯的单官能电子给体化合物（MD） ，胺或酮，其中ED / MD的摩尔比高于10。

公开(公告)号：US10155825B2

公开(公告)日：2018-12-18

申请号：US13818626

申请日：2011-08-10

Applicant: Joachim T. M. Pater ,  Dario Liguori ,  Gianni Vitale ,  Gianni Collina ,  Diego Brita ,  Tiziano Dall'Occo ,  Giampiero Morini

Inventor： Joachim T. M. Pater ,  Dario Liguori ,  Gianni Vitale ,  Gianni Collina ,  Diego Brita ,  Tiziano Dall'Occo ,  Giampiero Morini

IPC: C08F4/649 ,  C08F10/00 ,  C08F4/46 ,  C08F210/16

Abstract: A solid catalyst component for olefin polymerization, and in particular for the preparation of LLDPE, comprising Mg, Ti, halogen and an electron donor compound (ID) belonging to cyclic ethers having 3-6 carbon atoms, characterized by having the molar ratio Mg/Ti higher than 5, the molar ratio Mg/ID lower than 3, and by a specific X-ray diffraction spectrum.

公开(公告)号：US09127095B2

公开(公告)日：2015-09-08

申请号：US13517038

申请日：2010-12-17

Applicant: Diego Brita ,  Gianni Collina ,  Daniele Evangelisti ,  Anna Fait ,  Benedetta Gaddi ,  Giampiero Morini ,  Pietro Baita ,  Lorella Marturano ,  Harry Mavridis

Inventor： Diego Brita ,  Gianni Collina ,  Daniele Evangelisti ,  Anna Fait ,  Benedetta Gaddi ,  Giampiero Morini ,  Pietro Baita ,  Lorella Marturano ,  Harry Mavridis

IPC: C08F4/76 ,  C08F4/646 ,  C08F4/649 ,  C08F110/02 ,  C08F10/00

CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F2410/03 ,  C08F4/6543 ,  C08F4/6545 ,  C08F4/6494 ,  C08F2/001 ,  C08F2500/07 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/14 ,  C08F2500/18 ,  C08F2500/11

Abstract: Catalyst component comprising Mg, Ti, and halogen atoms, and is characterized in that (a) the Ti atoms are present in an amount higher than 4% based on the total weight of the said catalyst component, (b) the amount of Mg and Ti atoms is such that the Mg/Ti molar ratio is higher than 2 and (c) by a X-ray diffraction spectrum, in which, in the range of 2θ diffraction angles between 47° and 52°, at least two diffraction lines are present at diffraction angles 2θ of 48.3±0.2°, and 50.0±0.2°, the most intense diffraction lines being the one at 2θ of 50.0±0.2°, the intensity of the other diffraction line being equal to or lower than the intensity of the most intense diffraction line.

Abstract translation: 包含Mg，Ti和卤素原子的催化剂组分，其特征在于（a）Ti原子以基于所述催化剂组分的总重量高于4％的量存在，（b）Mg和 Ti原子使得Mg / Ti摩尔比高于2，（c）通过X射线衍射光谱，其中在2θ的范围内; 衍射角在47°和52°之间，至少两条衍射线存在于衍射角2°处; 分别为48.3±0.2°和50.0±0.2°，最强烈的衍射线为2°; 为50.0±0.2°，其他衍射线的强度等于或低于最强衍射线的强度。

公开(公告)号：US20130158214A1

公开(公告)日：2013-06-20

申请号：US13818626

申请日：2011-08-10

Applicant: Joachim T.M. Pater ,  Dario Liguori ,  Gianni Vitale ,  Gianni Collina ,  Diego Brita ,  Tiziano Dall'Occo ,  Giampiero Morini

Inventor： Joachim T.M. Pater ,  Dario Liguori ,  Gianni Vitale ,  Gianni Collina ,  Diego Brita ,  Tiziano Dall'Occo ,  Giampiero Morini

IPC: C08F4/46

CPC classification number: C08F4/46 ,  C08F4/6494 ,  C08F10/00 ,  C08F210/16 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/651 ,  C08F4/6543

Abstract: A solid catalyst component for olefin polymerization, and in particular for the preparation of LLDPE, comprising Mg, Ti, halogen and an electron donor compound (ID) belonging to cyclic ethers having 3-6 carbon atoms, characterized by having the molar ratio Mg/Ti higher than 5, the molar ratio Mg/ID lower than 3, and by a specific X-ray diffraction spectrum.

Abstract translation: 用于烯烃聚合的固体催化剂组分，特别是制备包含Mg，Ti，卤素和属于3-6个碳原子的环醚的电子给体化合物（ID）的LLDPE的固体催化剂组分，其特征在于具有摩尔比Mg / Ti高于5，摩尔比Mg / ID低于3，并通过特定的X射线衍射光谱。

公开(公告)号：US20110152482A1

公开(公告)日：2011-06-23

申请号：US12737742

申请日：2009-08-13

Applicant: Diego Brita ,  Gianni Collina

Inventor： Diego Brita ,  Gianni Collina

IPC: C08F4/649 ,  B01J31/38

CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/18

Abstract: A solid catalyst component comprising Ti, Mg, halogen and a couple of monofunctional electron donor compounds MD1 and MD2 selected from esters and ethers, said donors being present in amounts such that the molar ratio MD1/MD2 ranges from 20 to 800. The so obtained catalyst component when converted into a catalyst is able to produce ethylene polymers with good morphological properties even under drastic polymerization conditions.

Abstract translation: 包含Ti，Mg，卤素和选自酯和醚的一对单官能电子给体化合物MD1和MD2的固体催化剂组分，所述供体以使得MD1 / MD2的摩尔比为20至800的量存在。如此获得 当转化为催化剂时催化剂组分即使在剧烈聚合条件下也能够生产具有良好形态特性的乙烯聚合物。

公开(公告)号：US20100168350A1

公开(公告)日：2010-07-01

申请号：US12224008

申请日：2007-02-09

Applicant: Diego Brita ,  Gianni Collina

Inventor： Diego Brita ,  Gianni Collina

IPC: C08F4/64 ,  C08F4/609 ,  C08F4/602

CPC classification number: C08F10/00 ,  C08F210/16 ,  C08F4/651 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/17

Abstract: The present invention relates to catalysts component for the polymerization of ethylene and its mixtures with olefins CH2═CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising Ti, Mg, halogen, and electron donor belonging to 1,2-diethers as internal electron donor compound. The catalyst of the invention is suitably used in (co)polymerization processes of ethylene to prepare (co)polymers having narrow Molecular Weight Distribution (MWD) and high bulk density.

Abstract translation: 本发明涉及用于乙烯及其与烯烃CH 2 = CHR的混合物的聚合的催化剂组分，其中R是具有1-12个碳原子的烷基，环烷基或芳基，包括Ti，Mg，卤素和属于 1,2-二醚作为内电子给体化合物。 本发明的催化剂适用于乙烯的（共）聚合方法，以制备具有窄分子量分布（MWD）和高堆积密度的（共）聚合物。

公开(公告)号：US20090143549A1

公开(公告)日：2009-06-04

申请号：US11886112

申请日：2006-02-21

Applicant: Diego Brita

Inventor： Diego Brita

IPC: C08F2/00 ,  C08F4/54

CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/651 ,  C08F2500/07 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/18

Abstract: The present invention relates to catalysts component for the polymerization of ethylene and its mixtures with olefins CH2═CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising Ti, Mg, halogen, and 1,2-dimethoxyethane as internal electron donor compound. The catalyst of the invention is suitably used in (co)polymerization processes of ethylene to prepare (co)polymers having narrow Molecular Weight Distribution (MWD) and high bulk density.

Abstract translation: 本发明涉及用于乙烯及其与烯烃CH 2 -CHR的混合物的聚合的催化剂组分，其中R是具有1-12个碳原子的烷基，环烷基或芳基，包括Ti，Mg，卤素和1,2- 二甲氧基乙烷作为内电子给体化合物。 本发明的催化剂适用于乙烯的（共）聚合方法，以制备具有窄分子量分布（MWD）和高堆积密度的（共）聚合物。

公开(公告)号：US07427653B2

公开(公告)日：2008-09-23

申请号：US10537077

申请日：2003-11-25

Applicant: Diego Brita ,  Gianni Collina ,  Giampiero Morini ,  Gianni Vitale

Inventor： Diego Brita ,  Gianni Collina ,  Giampiero Morini ,  Gianni Vitale

IPC: C08F4/42

CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  Y02P20/52 ,  C08F2500/18 ,  C08F4/6565 ,  C08F4/651 ,  C08F4/6555 ,  C08F4/6494 ,  C08F4/6543 ,  C08F210/14 ,  C08F2500/12

Abstract: A catalyst component for olefin (co)polymerization, and in particular for the preparation of LLDPE, comprising Mg, Ti, halogen and an electron donor compound (ED) belonging to ethers, esters, amines, ketones, or nitriles, characterized in that the molar ratio Mg/Ti is higher than 5, and the molar ratio ED/Ti is higher than 3.5. The said catalyst components display a homogeneous distribution of the comonomer in and among the copolymer chains.

Abstract translation: 烯烃（共）聚合，特别是用于制备LLDPE的催化剂组分，其包含Mg，Ti，卤素和属于醚，酯，胺，酮或腈的电子给体化合物（ED），其特征在于， 摩尔比Mg / Ti高于5，ED / Ti摩尔比高于3.5。 所述催化剂组分显示共聚物链中和共聚物链中共聚单体的均匀分布。