Acetylene compound, liquid crystal composition and liquid crystal element
    11.
    发明授权
    Acetylene compound, liquid crystal composition and liquid crystal element 有权
    乙炔化合物,液晶组合物和液晶元素

    公开(公告)号:US06217793B1

    公开(公告)日:2001-04-17

    申请号:US09312698

    申请日:1999-05-17

    IPC分类号: C09K1932

    CPC分类号: C09K19/2007 C09K19/32

    摘要: Provided are novel acetylene compounds which are useful as a component for a liquid crystal composition used for a liquid crystal element, a liquid crystal composition containing said compounds and a liquid crystal element using said liquid crystal composition. The acetylene compound is represented by Formula (1): n-CmH2m+1—C≡C—A—Z1—B—Y1—R1  (1) wherein m represents an integer of 2 to 24; R1 represents a linear or branched alkyl group, a linear or branched alkoxyalkyl group, a linear or branched alkenyl group, or a linear or branched alkenyloxyalkyl group each of which may be substituted with a halogen atom; R1 may have an asymmetric carbon atom, and the asymmetric carbon atom may be optically active; A and B represents a cyclic group such as a phenylene group, a biphenylene group, a naphthylene group and the like each of which may be substituted with a halogen atom.

    摘要翻译: 提供了可用作用于液晶元件的液晶组合物的组分,含有所述化合物的液晶组合物和使用所述液晶组合物的液晶元件的新型乙炔化合物。 乙炔化合物由式(1)表示:其中m表示2〜24的整数; R1表示直链或支链烷基,直链或支链烷氧基烷基,直链或支链烯基,或每个可被卤素原子取代的直链或支链烯氧基烷基; R1可以具有不对称碳原子,并且不对称碳原子可以是光学活性的; A和B表示可以被卤素原子取代的亚苯基,亚联苯基,亚萘基等环状基团。

    Fluorinated cyclopenta[a]naphthalenes and their use in liquid-crystal mixtures
    13.
    发明授权
    Fluorinated cyclopenta[a]naphthalenes and their use in liquid-crystal mixtures 有权
    氟化环戊二烯[a]萘及其在液晶混合物中的应用

    公开(公告)号:US06737125B2

    公开(公告)日:2004-05-18

    申请号:US10242128

    申请日:2002-09-12

    IPC分类号: C09K1932

    摘要: Compounds of the formula (I), liquid-crystal mixtures comprising these compounds, and their use in liquid-crystal displays: in which R1 is H, F, CF3, OCF3, OCF2H, OCFH2, an alkyl radical or alkyloxy radical or an alkenyl radical or alkenyloxy radical; R2 is H, an alkyl radical or alkyloxy radical or an alkenyl radical or alkenyloxy radical M1 is —C(═O)O—, —OC(═O)—, —CH2O—, —OCH2—, —OCF2—, —CF2O—, —C≡C—, —CH2CH2—, —CF2CF2—, —CF═CFC(═O)O— or a single bond M2 is —C(═O)O—, —OC(═O)—, —CH2O—, —OCH2—, —CH2CH2—, —CF2CF2— or a single bond; A1 and A2 are &agr;-1,4-diyl, unsubstituted or mono- or disubstituted by F; where &agr; is: phenylene, cyclohexane, 1-cyclohexene or 1,3-dioxane-2,5-diyl; m and n are zero or 1; m+n=0 or 1 L1, L2, L3, L4 and L5 are H or F.

    摘要翻译: 式(I)化合物,包含这些化合物的液晶混合物及其在液晶显示器中的用途:其中R 1是H,F,CF 3,OCF 3,OCF 2 H,OCF 2 H,烷基或烷氧基或其 烯基或烯氧基; R 2是H,烷基或烷氧基或链烯基或烯氧基自由基M 1是-C(= O)O-,-OC(= O) - , - CH 2 O - , - OCH 2 - , - OCF 2 - , - CF 2 O-,-C = C - , - CH 2 CH 2 - , - CF 2 CF 2 - , - CF = CFC(= O)O-或单键M 2是-C O)O-,-OC(= O) - , - CH 2 O - , - OCH 2 - , - CH 2 CH 2 - , - CF 2 CF 2 - 或单键; A 1和A 2是α-1,4-二 F未取代或单取代或二取代; 其中α是:亚苯基,环己烷,1-环己烯或1,3-二恶烷-2,5-二基; m和n是0或1; m + n = 0或1L 1,L 2,L 3,L 4和L 5为H或F.

    Chiral swallow-tailed liquid crystals and its fabrication method
    16.
    发明授权
    Chiral swallow-tailed liquid crystals and its fabrication method 有权
    手性燕尾液晶及其制作方法

    公开(公告)号:US06245256B1

    公开(公告)日:2001-06-12

    申请号:US09411866

    申请日:1999-10-04

    IPC分类号: C09K1932

    摘要: Novel chiral swallow-tailed liquid crystals synthesized from chiral material comprised of alkyl(s)-2-{6-[4-(4′-alkyloxyphenyl)benzoyloxy]-2-naphthyl}propionates having a rigid core, a chiral center directly linked to the rigid core, a chiral tail, and a swallow-tailed group linked to the chiral tail. The chiral center and the swallow-tailed group are arranged at the same side in the molecular structure of the chiral material. These structural characteristics enable the chiral material to have same property of threadholdless antiferroelectricity, and the advantage of simple manufacturing process. The chiral material shows an optimum application effect in liquid crystal displays.

    摘要翻译: 由具有刚性芯的烷基(s)-2- {6- [4-(4'-烷氧基苯基)苯甲酰氧基] -2-萘基}丙酸酯的手性材料合成的新型手性燕尾液晶,手性中心直接连接 到刚性核心,手性尾巴和连接到手性尾巴的燕尾组。 手性中心和燕尾组在手性材料的分子结构的同一侧排列。 这些结构特征使得手性材料具有相同的螺纹保持性反铁电性能,以及简单制造工艺的优点。 手性材料在液晶显示器中显示出最佳的应用效果。

    Liquid crystal alkenyl bicyclo[2.2.2]octanes and mixtures and devices containing such compounds
    17.
    发明授权
    Liquid crystal alkenyl bicyclo[2.2.2]octanes and mixtures and devices containing such compounds 有权
    液晶烯基双环[2.2.2]辛烷和含有这些化合物的混合物和装置

    公开(公告)号:US06187393B1

    公开(公告)日:2001-02-13

    申请号:US09269110

    申请日:1999-03-19

    IPC分类号: C09K1932

    摘要: Compounds of formula (I) are provided which are particularly useful in super twisted nematic devices, where n may be 0-5; m may be 0-5; p may be 1-9; q may be 1, 1, or 2; A1, A2 are independently chosen from 1-4, -disubstituted benzene, 2,5-disubstituted pyrimidine, or 2,5-disubstituted pyridine, trans- 1,4-disubstituted cyclohexane, trans- 2,5-disubstitued dioxane. The aromatic rings may be laterally substituted with F, Cl, Br or CN; Z1 may be O, COO, OOC; Z2, Z3 are independent chosen from a direct bond, COO, OOC, C2H4, CH2O, OCH2, or -c≡c-, provided that when Z1 is O and m is 1, 3 or 5 the carbon—carbon double bond configuration is E; provided that when Z1 is O and m is 2 or 4 the carbon—carbon double bond configuration is Z; provided that when Z1 is COO or OOC and m is 0, 2 or 4 the carbon—carbon double bond configuration is E; and provided that when Z1 is COO or OOC and m is 1, 3 or 5 the carbon—carbon double bond configuration is Z.

    摘要翻译: 提供式(I)化合物,其特别适用于超扭曲向列装置,其中n可为0-5; m可以是0-5; p可以是1-9; q可以是1,1或2; A1,A2独立地选自1-4, - 二取代的苯,2,5-二取代的嘧啶或2,5-二取代的吡啶,反式-1,4-二取代的环己烷,反式-2,5-二取代的二恶烷。 芳环可以被F,Cl,Br或CN横向取代; Z1可以是O,COO,OOC; Z2,Z3独立地选自直接键,COO,OOC,C2H4,CH2O,OCH2或-c = c-,条件是当Z1为O且m为1,3或5时,碳 - 碳双键构型为 E; 条件是当Z1为O且m为2或4时,碳 - 碳双键构型为Z; 条件是当Z1为COO或OOC且m为0或2时,碳 - 碳双键构型为E; 并且当Z1为COO或OOC且m为1,3或5时,碳 - 碳双键构型为Z。