摘要:
Ferrous iron bearing acid waste waters such as hydrochloric acid waste waters or sulfuric acid waste waters or a combination of the two with or without a small amount of hydrofluoric acid, are treated with lime or sodium hydroxide and partially oxidized to produce hydrated ferroso-ferric oxide or hydrated magnetite. The process is conducted at ambient temperatures in a batch-type or a continuous operation.
摘要:
In a process for the production of a gas containing sulfur dioxide from a dilute aqueous sulfuric acid stream containing iron (II) sulfate and approximately 10-40% by weight H2SO4, e.g. pickle liquor or waste H2SO4 from TiO2 production, comprising concentrating the acid in an evaporation stage, and reductively cracking the concentrating acid in a cracking stage at temperatures of between 850* and 1,100* C. to a hot cracked gas containing SO2 and metallic oxides, THE IMPROVEMENT COMPRISING EVAPORATING THE 10-40% STRENGTH SULFURIC ACID TO 55-70% STRENGTH SULFURIC ACID BY DIRECT HEAT EXCHANGE WITH THE HOT CRACKED GAS; SIMULTANEOUSLY FORMING PRECIPITATE CONTAINING IRON (II) sulfate; and passing resultant evaporated sulfuric acid to the cracking stage. The resultant cracked gas containing metallic oxides, aluminum and magnesium oxides in particular, is purified by the direct heat exchange treatment insofar as the metallic oxides are scrubbed out and become enmeshed in the sulfate precipitate.
摘要翻译:在从含硫酸铁(II)和约10-40重量%H 2 SO 4的稀硫酸水流中生产含二氧化硫的气体的方法中, 酸洗液或废H2SO4,包括在蒸发阶段浓缩酸,并将浓缩酸在850-1100℃的温度下,在含有SO 2和金属氧化物的热裂解气中进行还原性裂化, 包括将10-40%强酸性硫酸蒸发至具有热裂解气体的直接热交换的55-70%强酸性硫酸的改进; 同时形成含硫酸铁(II)的预硫化物; 并将所得蒸发的硫酸通入裂化阶段。 所形成的含金属氧化物,特别是铝和镁的氧化物的裂化气体,通过直接热交换处理进行纯化,只要金属氧化物被洗去并变成含硫酸盐沉淀物。
摘要:
Method and apparatus for recovering sulfuric acid and ferrous sulfate crystals from a spent aqueous sulfuric acid pickling solution. The apparatus includes a treating tank, settling tank, and crystal strainer. The tanks utilize sloped bottoms to aid in crystal collection, and the settling tank includes baffle plates to promote settling of crystals. The crystal strainer is of a continuously operable type, and the system is automatically controlled.
摘要:
METHOD FOR RECOVERING METAL VALUES FROM OCEAN FLOOR MODULES OF THE TYPE CONTAINING IRON, MAGANESE, COPPER COBALT AND NICKEL COMPRISING GRINDING THE NODULES INTO PARTICLES, SUBJECTING THE GROUND NODULES TO A FIRST LEACHING STEP WHICH DISSOLVES COPPER AND NICKEL, AFTER WHICH THE SOLIDS ARE SEPARATED, THEN SUBJECTING THE LEACH LIQUOR TO LIQUID ION EXCHANFGE AND ELECTROLYZING SO AS TO OBTAIN COPPER AND NICKEL VALUES. SUBJECTING THE SOLIDS TO A SECOND LEACH, USING FERROUS SULFATE OR FERROUS CHLORIDE, REMOVING THE IRON OXIDE AND SUBJECTING THE SOLIDS TO A LIQUID IION EXCHANGE FOR SEPARATING COBALT AND MANGANESE AND THEN ELECTROLYZING TO RECOVER INDEPENDENTLY THE COBALT AND MANGANESE VALUES.
摘要:
Pigment-grade ferric oxide is precipitated from a solution of a ferrous salt by aerating at ambient temperature while introducing substantially two equivalents of base at such rate as to maintain the pH between 5 and 6.
摘要:
Dilute acid wastes, such as mine drainage waters, are neutralized by reaction with an extremely finely divided limestone slurry after which the neutralized effluent is aerated to strip carbon dioxide and oxidize ferrous iron. After clarification, the product stream is suitable for disposal in surface waters.
摘要:
Acid waste waters containing ferrous iron are neutralized using limestone in a finely divided state. Substantial amounts of a mixed valence, hydrous iron oxide sludge are recycled back to the neutralization and aeration steps of the process to produce a dense, easily dewatered sludge having improved handling characteristics.