公开(公告)号：US09853229B2

公开(公告)日：2017-12-26

申请号：US14478838

申请日：2014-09-05

申请人： University of Southern California

发明人： Mark E. Thompson ,  Peter I. Djurovich ,  Valentina Krylova

IPC分类号： H01L51/00 ,  C07F9/50 ,  C07F1/08 ,  H01L51/50

CPC分类号： H01L51/0091 ,  C07F1/08 ,  C07F9/5045 ,  H01L51/0052 ,  H01L51/0054 ,  H01L51/0058 ,  H01L51/0067 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/5016

摘要： A compound having a structure according to formula (I) is disclosed. In formula (I), Cu is a monovalent copper atom; *C is a carbene carbon; X1 and X2 are selected from alkyl, cycloalkyl, alkoxy, amino, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, heteroalkynyl, arylalkyl, aryloxy, aryl, heteroalkyl, heteroaryl, and combinations thereof; X1 and X2 are independently bonded to *C by an atom selected from C, N, O, S, and P; X1 and X2 are optionally joined to form a ring; and Y is selected halide, alkyl, cycloalkyl, alkoxy, amino, phosphine, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, heteroalkynyl, arylalkyl, aryloxy, aryl, heteroalkyl, heteroaryl, and combinations thereof. A formulation containing compound having a structure according to formula (I), and a device with an organic layer comprising disposed between an anode and a cathode, that includes a compound having a structure according to formula (I) are also described.

公开(公告)号：US20150236279A1

公开(公告)日：2015-08-20

申请号：US14616438

申请日：2015-02-06

申请人： Universal Display Corporation ,  University of Southern California

发明人： Geza SZIGETHY ,  Jason Brooks ,  Mark E. Thompson ,  Patrick Saris ,  Peter I. Djurovich

IPC分类号： H01L51/00 ,  C07F17/02

CPC分类号： H01L51/0085 ,  C07F15/0033 ,  C07F15/02 ,  H01L51/5016

摘要： A compound having a structure of Formula M(LA)x(LB)y(LC)z, where ligand LA is ligand LB is and ligand LC is is disclosed. In Formula M(LA)x(LB)y(LC)z, M is a metal having an atomic number greater than 40; x is 1, 2, or 3; y and z are 0, 1, or 2; x+y+z is the oxidation state of metal M; Z1-Z6 are each C or N; ZD is N or a carbene carbon; rings C and D are independently a 5 or 6-membered carbocyclic or heterocyclic ring; R4 is substituted, while each of R1, R2, R3, RC, RD, R11, R12, and R13 are selected from hydrogen and a variety of moieties; and any adjacent substituents of R1, R2, R3, R4, RC, RD, R11, R12, and R13 are optionally joined to form a ring. Formulations and devices, such as an OLEDs, that include the compound of formula M(LA)x(LB)y(LC)z are also described.

摘要翻译： 公开了具有式M（LA）x（LB）y（LC）z的结构的化合物，其中配位体LA是配位体LB，并且配体LC是公开的。 在式M（LA）x（LB）y（LC）z中，M是原子序数大于40的金属; x为1,2或3; y和z分别为0,1或2; x + y + z是金属M的氧化态; Z1-Z6各自为C或N; ZD为N或碳烯碳; 环C和D独立地为5或6元碳环或杂环; R 4是取代的，而R 1，R 2，R 3，RC，RD，R 11，R 12和R 13各自选自氢和各种部分; 并且R 1，R 2，R 3，R 4，RC，RD，R 11，R 12和R 13的任何相邻的取代基任选地连接形成环。 还描述了包括式M（LA）x（LB）y（LC）z的化合物的制剂和装置，例如OLED。

公开(公告)号：US20150008402A1

公开(公告)日：2015-01-08

申请号：US14302042

申请日：2014-06-11

申请人： University of Southern California

发明人： Mark E. Thompson ,  Yifei Liu ,  Peter I. Djurovich

IPC分类号： H01L51/00 ,  H01L51/50

CPC分类号： H01L51/0085 ,  C07F15/0033 ,  C09K11/06 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1088 ,  C09K2211/1096 ,  C09K2211/185 ,  H01L51/5016

摘要： A compound comprising a ligand LA selected from: as well as, devices and formulations containing the compound are disclosed. In the compounds, X1-X6, are CH or N; Y1-Y12 are independently selected from CH, N, and C-APR1′R1″; when present, exactly one of Y1 through Y12 is C-APR1′R1″ in LA8; A is selected from a single bond, —CRARB—, —NRA—, —O—, —S— and —SiRARB—; and R, R1′, R1″, R2, R3, RA, and RB are each independently a substitutent selected from hydrogen, deuterium, alkyl, cycloalkyl, aryl, and weight of at least 40.

摘要翻译： 公开了包含选自以下的配体LA的化合物：以及含有该化合物的装置和制剂。 在化合物中，X 1 -X 6是CH或N; Y1-Y12独立地选自CH，N和C-APR1'R1“; 当存在时，Y1至Y12中只有一个是LA8中的C-APR1'R1“ A选自单键，-CRARB-，-NRA-，-O - ， - S-和-SiRARB-; R 1，R 1，R 1“，R 2，R 3，R A和R B各自独立地为选自氢，氘，烷基，环烷基，芳基和至少40的重量的取代基。

公开(公告)号：US20140076403A1

公开(公告)日：2014-03-20

申请号：US13894590

申请日：2013-05-15

申请人： University of Southern California ,  The Regents of the University of Michigan

发明人： Stephen R. Forrest ,  Mark E. Thompson ,  John J. Chen ,  Jonathan R. Sommer ,  Peter I. Djurovich ,  Kathryn R. Allen

IPC分类号： H01L51/00

CPC分类号： H01L51/0067 ,  B82Y10/00 ,  C07F5/02 ,  H01L51/0046 ,  H01L51/0072 ,  H01L51/008 ,  H01L51/4253 ,  Y02E10/549

摘要： The present disclosure generally relates to organic photosensitive optoelectronic devices comprising at least one boron dipyrrin compound. In addition, the present disclosure relates to methods of making organic photosensitive optoelectronic devices comprising at least one boron dipyrrin compound. The present disclosure also generally relates to chromophoric compounds that combine strong absorption of light at visible wavelengths with the ability to undergo symmetry-breaking intramolecular charge transfer (ICT), and their use for the generation of free carriers in organic photovoltaic cells (OPVs) and electric-field-stabilized geminate polaron pairs. The present disclosure also relates to the synthesis of such compounds, methods of manufacture, and applications in photovoltaic systems and organic lasers.

摘要翻译： 本发明一般涉及包含至少一种硼二吡啶化合物的有机光敏光电器件。 此外，本公开涉及制备包含至少一种硼二吡啶化合物的有机光敏光电器件的方法。 本公开还通常涉及将可见波长的光的强烈吸收与经历对称断裂的分子内电荷转移（ICT）的能力结合的发色化合物及其在有机光伏电池（OPV）中产生游离载体的用途和 电场稳定的双峰极化子对。 本公开还涉及这种化合物的合成，制造方法以及在光伏系统和有机激光器中的应用。

公开(公告)号：US20240352043A1

公开(公告)日：2024-10-24

申请号：US18624260

申请日：2024-04-02

申请人： UNIVERSAL DISPLAY CORPORATION ,  University of Southern California

发明人： Rasha HAMZE ,  Noah HORWITZ ,  James Fortwengler ,  Jason Brooks ,  Peter I. Djurovich ,  Mark E. Thompson

IPC分类号： C07F1/12 ,  C07F1/08 ,  H10K85/30

CPC分类号： C07F1/12 ,  C07F1/08 ,  H10K85/371

摘要： Provided are organometallic compounds comprising as metal at least one of the coin metals Au, Ag, and Cu and further a ligand comprising a 5-membered heterocyclic ring which is fused to a 6-membered aromatic ring and also fused to a 5- or 6-membered carbocyclic or heterocyclic ring or fused ring system. Also provided are formulations comprising these organometallic compounds. Further provided are organic light emitting devices (OLEDs) and related consumer products that utilize these organometallic compounds.

公开(公告)号：US20240254385A1

公开(公告)日：2024-08-01

申请号：US18434001

申请日：2024-02-06

申请人： The University of Southern California

发明人： Peter I. Djurovich ,  Mark E. Thompson ,  Narcisse Ukwitegetse ,  Tian-Yi Li ,  Rasha Hamze

IPC分类号： C09K11/06 ,  C07D233/06 ,  C07D239/10 ,  H10K50/11 ,  H10K85/30 ,  H10K101/10

CPC分类号： C09K11/06 ,  C07D233/06 ,  C07D239/10 ,  H10K85/361 ,  H10K85/371 ,  C09K2211/188 ,  H10K50/11 ,  H10K2101/10

摘要： The co-linear or near co-linear structure of bimetallic Janus-type two-coordinated metal complexes may allow for a large transition dipole moment that can enhance the radiative lifetime. The symmetric nature of the bimetallic Janus complexes diminishes or eliminates the polar nature of the monometallic carbene-metal-amide/arene complexes.

公开(公告)号：US10818853B2

公开(公告)日：2020-10-27

申请号：US15174409

申请日：2016-06-06

申请人： University of Southern California

发明人： Mark E. Thompson ,  Matthew J. Jurow ,  Peter I. Djurovich ,  Tobias D. Schmidt

IPC分类号： H01L51/00 ,  C09K11/06 ,  C09K11/02 ,  H01L51/50

摘要： Organic light emitting devices incorporating a film of metal complex emitters that are oriented with their transition dipole moment vectors oriented parallel to the device substrate enhances the outcoupling and eliminate the need for micro-lens arrays, gratings, or other physical extraneous outcoupling methods.

公开(公告)号：US09932359B2

公开(公告)日：2018-04-03

申请号：US14322964

申请日：2014-07-03

申请人： University of Southern California

发明人： Mark E. Thompson ,  Rasha Hamze ,  Peter I. Djurovich

IPC分类号： C07F1/08 ,  H01L51/00 ,  H01L51/50

CPC分类号： C07F1/08 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/008 ,  H01L51/0091 ,  H01L51/5012

摘要： A compound having a structure according to wherein Y is a carbene moeity coordinated to a trivalent copper atom Cu is disclosed. In Formula I, L1, L2, and L3 are three monodentate ligands. In Formula II, L1, L2, and L3 represent a single tridentate ligand chelated by X, wherein X is B—H, C—H, N, P, or P═O.

公开(公告)号：US12058929B2

公开(公告)日：2024-08-06

申请号：US17012997

申请日：2020-09-04

申请人： University of Southern California

发明人： Mark E. Thompson ,  Matthew J. Jurow ,  Peter I. Djurovich ,  Tobias D. Schmidt

IPC分类号： H10K85/30 ,  C09K11/02 ,  C09K11/06 ,  H10K50/11 ,  H10K101/10 ,  H10K101/30

CPC分类号： H10K85/342 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1044 ,  C09K2211/185 ,  H10K50/11 ,  H10K2101/10 ,  H10K2101/30

摘要： Organic light emitting devices incorporating a film of metal complex emitters that are oriented with their transition dipole moment vectors oriented parallel to the device substrate enhances the outcoupling and eliminate the need for micro-lens arrays, gratings, or other physical extraneous outcoupling methods.

公开(公告)号：US10367157B2

公开(公告)日：2019-07-30

申请号：US14433046

申请日：2013-10-07

申请人： University of Southern California

发明人： Mark E. Thompson ,  Cong Trinh ,  Peter I. Djurovich ,  Sarah M. Conron

IPC分类号： B82Y10/00 ,  C09B47/00 ,  C09B57/10 ,  H01L51/00 ,  H01L51/42 ,  H01L51/44 ,  H01L51/50

摘要： Disclosed herein are organic photosensitive optoelectronic devices comprising acceptor and/or donor sensitizers to increase absorption and photoresponse of the photoactive layers of the devices. In particular, devices herein include at least one acceptor layer and at least one donor layer, wherein the acceptor layer may comprise a mixture of an acceptor material and at least one sensitizer, and the donor layer may comprise a mixture of a donor material and at least one sensitizer. Methods of fabricating the organic photosensitive optoelectronic devices are also disclosed.