POLYURETHANE BASED HOT MELT ADHESIVE

    公开(公告)号:US20240376355A1

    公开(公告)日:2024-11-14

    申请号:US18290053

    申请日:2022-05-11

    Abstract: Hot melt adhesive including a randomly hydroxyl functionalized branched olefin copolymer has: number average molecular weight between 10 to 50 kg/mol, crystallinity content below 30%, enthalpy between 5 to 65 J/g, polydispersity index from 2 to 6, melting temperature between 40 and 120° C., optionally, more than two hydroxyl functionalities per polymer chain and consisting of at least 80 mol % of a unit of formula (1), optionally a unit of formula (2), and between 0.1 to 1 mol %, of a unit of formula (3): wherein: R1 is H or CH3; R2 is a C0-10 hydrocarbyl group; R3 is a C2-10 hydrocarbyl group, and the hydroxyl functionalized olefin copolymer has undergone an addition reaction with a di-, tri-or polyisocyanates of formula (4): O═C═N—R4N═C═O)n Wherein, R4 is a C1-10 hydrocarbyl group.

    POLYACRYLATE-BASED GRAFT COPOLYMER
    18.
    发明申请

    公开(公告)号:US20230026134A1

    公开(公告)日:2023-01-26

    申请号:US17785602

    申请日:2020-11-12

    Abstract: The invention relates to a polyacrylate-based graft copolymer comprising a polyacrylate backbone and polyolefin side chains grafted thereon, wherein the graft copolymer is prepared by reacting a first polymer and a second polymer, wherein the first polymer comprises recurring units having the structure (I) and optionally further recurring units having the structures (II): Formulae (I), (II) wherein R1, R3 is H or CH3 and R2 is a hydrocarbon moiety comprising 1 to 6 carbon atoms, one of R4 and R5 is H and the other one of R5 and R4 is COOR2, C═N, Cl, or an aliphatic or aromatic hydrocarbon moiety optionally containing one or multiple hetero atom functionalities, wherein R2 in (I) is different from R2 in (II) and the second polymer is a functionalized polyolefin having one or multiple hydroxyl functional groups, wherein the graft copolymer is formed by transesterification of the COOR2 group of (1) or (II) with the hydroxyl functional group of the functionalized polyolefin.

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