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公开(公告)号：US4539158A
公开(公告)日：1985-09-03
申请号：US681747
申请日：1984-12-14
IPC分类号： C07C265/12 , C08G18/80 , C07C119/048
CPC分类号： C08G18/8019 , C07C263/18
摘要： The present invention is directed to a process for the preparation of a stable, liquid adduct comprising reacting a mixture of 1,3-butane diol and neopentyl glycol with diphenylmethane diisocyanate at a temperature of from about 25.degree. C. to about 120.degree. C. in an amount such that said adduct has an isocyanate group content of from about 20 to about 30 percent by weight, and wherein the ratio of mole equivalents of 1,3-butane diol to mole equivalents of neopentyl glycol is from 0.05:0.95 to 0.95:0.05, with the further proviso that(i) if the 4,4'-isomer content of the diphenylmethane diisocyanate is equal to or greater than 98 percent by weight, then said ratio is from 0.30:0.70 to 0.65:0.35,(ii) if the 4,4'-isomer content of the diphenylmethane diisocyanate is less than 98 percent by weight but not less than 90 percent by weight, then said ratio is from 0.30:0.70 to 0.75:0.25,(iii) if the 4,4'-isomer content of the diphenylmethane diisocyanate is less than 90 percent by weight but not less than 80 percent by weight, then said ratio is from 0.30:0.70 to 0.85:0.15 and(iv) if the 4,4'-isomer content of the diphenylmethane diisocyanate is less than 80 percent by weight but not less than 65 percent by weight, then said ratio is from 0.30:0.70 to 0.95:0.05.The invention is also directed to a product produced from such process.
摘要翻译： 本发明涉及制备稳定的液体加合物的方法，其包括在约25℃至约120℃的温度下使1,3-丁二醇和新戊二醇的混合物与二苯基甲烷二异氰酸酯反应。 其量使得所述加合物的异氰酸酯基含量为约20至约30重量％，并且其中1,3-丁二醇的摩尔当量与新戊二醇的摩尔当量的比为0.05:0.95至0.95 ：0.05，另外条件是（ⅰ）如二苯基甲烷二异氰酸酯的4,4'-异构体含量等于或大于98重量％，则所述比例为0.30:0.70-0.65:0.35，（ii ）如果二苯基甲烷二异氰酸酯的4,4'-异构体含量小于98重量％但不小于90重量％，则所述比例为0.30:0.70-0.75:0.25，（iii）如果4， 二苯基甲烷二异氰酸酯的4'-异构体含量小于90重量％，但n = 小于80重量％，则所述比例为0.30:0.70至0.85:0.15，和（iv）如果二苯基甲烷二异氰酸酯的4,4'-异构体含量小于80重量％但不小于65重量％ ，则所述比例为0.30:0.70至0.95:0.05。 本发明还涉及由这种方法生产的产品。
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公开(公告)号：US4519965A
公开(公告)日：1985-05-28
申请号：US643612
申请日：1984-08-23
IPC分类号： C08G18/00 , B29C39/00 , B29C45/00 , B29K75/00 , C08G18/08 , C08G18/48 , C08G18/50 , C08G18/65 , C08J9/02 , C08K5/098 , C08L51/00 , C08L51/02 , C08L67/00 , C08L75/00 , C08L75/04 , C08L77/00 , C08G18/14
CPC分类号： C08G18/6529 , C08G18/5024 , C08K5/098 , C08G2120/00 , C08G2125/00
摘要： The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer molding by reacting a reaction mixture containing(I) a polyisocyanate,(II) an isocyanate-reactive polymer having a molecular weight of about 1800 to 12,000,(III) about 5 to 50% by weight, based on the weight of component (II) of a chain extender comprising a sterically hindered aromatic diamine and(IV) an internal mold release agent mixture comprising(a) about 0.5 to 10% by weight, based on the weight of components (II) and (III) of a zinc carboxylate containing 8 to 24 carbon atoms per carboxylate group and(b) a compatibilizer comprising a member selected from the group consisting of nitrogen-containing, isocyanate-reactive, acyclic compounds and nitrogen-containing, isocyanate-reactive polymers in an amount sufficient to solubilize the zinc carboxylate so that when the internal mold release agent mixture is in admixture with components (II) and (III), the zinc carboxylate possesses improved resistance to precipitation,the reaction mixture being processed as a one-shot system by the RIM process at an isocyanate index of about 70 to 130.
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13.发明授权Fatty imidazoline crosslinkers for polyurethane, polyurethaneurea and polyurea applications 失效用于聚氨酯，聚氨酯脲和聚脲应用的脂肪咪唑啉交联剂
公开(公告)号：US5541338A
公开(公告)日：1996-07-30
申请号：US408456
申请日：1995-03-22
IPC分类号： C07D233/54 , C08G18/32 , C08G18/65
CPC分类号： C07D233/56 , C08G18/3293 , C08G18/6535 , C08G2101/0008 , C08G2101/0025 , C08G2120/00 , C08G2125/00 , C08G2410/00
摘要： In an active hydrogen-containing B-side composition for reaction with a polyisocyanate-containing A-side composition to make a polyurethane, polyurethane/urea or polyurea elastomer by reaction injected molding, the improvement which comprises a crosslinking polyol composition which is the reaction product of a C.sub.12 -C.sub.36 fatty acid with a polyalkylene polyamine to yield an intermediate imidazoline-containing polyamine reaction product having at least one C.sub.11 -C.sub.35 alkyl substituent and further reacting the intermediate reaction product with a C.sub.2 -C.sub.21 reactive epoxide.
摘要翻译： 在与含多异氰酸酯的A侧组合物反应以制备聚氨酯，通过反应注射成型的聚氨酯/脲或聚脲弹性体的活性含氢B侧组合物中，包括作为反应产物的交联多元醇组合物的改进 的C 12 -C 36脂肪酸与聚亚烷基多胺反应以产生具有至少一个C 11 -C 35烷基取代基的中间体咪唑啉多胺反应产物，并进一步使中间反应产物与C2-C21活性环氧化物反应。
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14.发明授权RIM polyol blends containing acidic siloxane internal mold release agents and quaternary ammonium phenoxides 失效含有酸性硅氧烷内脱模剂和季铵苯氧化物的RIM多元醇共混物
公开(公告)号：US5324759A
公开(公告)日：1994-06-28
申请号：US9507
申请日：1993-01-26
申请人： John E. Dewhurst
发明人： John E. Dewhurst
CPC分类号： C08G18/0833 , B29C33/62 , B29C33/64 , C08G18/615 , C08G2120/00
摘要： In an active hydrogen-containing B-side composition for reaction with a polyisocyanate-containing A-side composition to make a polyurethane, polyurethaneurea or polyurea elastomer by reaction injection molding, the improvement which comprises a mold release composition consisting essentially of (1) the reaction product of a mixture of a phenol compound, a tertiary amine, and a reactive epoxide and (2) a carboxy functional siloxane.
摘要翻译： 在含有多异氰酸酯的A侧组合物与通过反应注射成型制备聚氨酯，聚氨酯脲或聚脲弹性体的活性含氢B侧组合物中，其改进包括脱模组合物，其基本上由（1） 酚化合物，叔胺和活性环氧化物的混合物的反应产物和（2）羧基官能的硅氧烷。
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公开(公告)号：US5322914A
公开(公告)日：1994-06-21
申请号：US120618
申请日：1993-09-13
CPC分类号： C08G18/10
摘要： The invention consists of a composition containing a chemically blocked trimerization catalyst and a polyurethane prepolymer resin or resins with reactive isocyanate groups. In the absence of heat, the catalyst is not active and the solution of catalyst in the resin undergoes no appreciable reaction for periods ranging from hours to weeks depending upon the composition and concentration of the catalysts and the structure and concentration of the isocyanate groups. When heat is applied to the mixture a trimerization reaction occurs which produces a crosslinked polyurethane network with utility as an elastomer or as an adhesive.
摘要翻译： 本发明包含含有化学封闭三聚催化剂和聚氨酯预聚物树脂或具有活性异氰酸酯基团的树脂的组合物。 在不存在热的情况下，根据催化剂的组成和浓度以及异氰酸酯基团的结构和浓度，催化剂不活泼，催化剂在树脂中的溶液几小时至几周不会发生明显的反应。 当对混合物施加热量时，发生三聚反应，其产生用作弹性体或粘合剂的交联聚氨酯网络。
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16.发明授权Rim polyol blends containing acidic siloxane internal mold release agents and tin catalysts 失效含有酸性硅氧烷内脱模剂和锡催化剂的环状多元醇共混物
公开(公告)号：US5312845A
公开(公告)日：1994-05-17
申请号：US992404
申请日：1992-12-16
申请人： John E. Dewhurst
发明人： John E. Dewhurst
CPC分类号： C08G18/6529 , C08G18/1875 , C08G18/3825 , C08G18/615 , C08L75/00 , C08G2120/00 , C08G2125/00
摘要： In an active hydrogen-containing B-side composition for reaction with a polyisocyanate-containing A-side composition to make a polyurethane or polyurethaneurea elastomer by reaction injection molding, the improvement which comprises a mold release composition consisting essentially of (1) the reaction product of a mixture of a carboxylic acid, a tertiary amine, and a reactive epoxide and (2) a carboxy functional siloxane.
摘要翻译： 在与含多异氰酸酯的A侧组合物反应以通过反应注射成型制备聚氨酯或聚氨酯脲弹性体的活性含氢B侧组合物中的改进包括脱模组合物，其基本上由（1）反应产物 的羧酸，叔胺和反应性环氧化物的混合物，和（2）羧基官能的硅氧烷。
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公开(公告)号：US5002999A
公开(公告)日：1991-03-26
申请号：US241529
申请日：1988-09-07
CPC分类号： C08K5/098 , C08G18/40 , C08G18/409 , C08L75/00 , C08G2120/00
摘要： The preent invention is directed to an internal mold release composition comprising:(a) a zinc carboxylate selected from the group consisting of zinc stearate, zinc laurate and zinc oleate, and(b) a compatibilizer comprising a dispersion of polyurea and/or a polyhydrazodicarbonamide in an organic compound containing at least one hydroxyl group, in an amount sufficient to solubilize the zinc carboxylate.The invention also relates to the use of such composition.
摘要翻译： 本发明涉及一种内部脱模组合物，其包含：（a）选自硬脂酸锌，月桂酸锌和油酸锌的羧酸锌，和（b）包含聚脲和/或聚二酰氨基脲的分散体的增容剂 在含有至少一个羟基的有机化合物中，其量足以溶解羧酸锌。 本发明还涉及这种组合物的用途。
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18.发明授权
公开(公告)号：US4897428A
公开(公告)日：1990-01-30
申请号：US239366
申请日：1988-08-31
CPC分类号： C08K5/17 , C08G18/3275 , C08G18/3281 , C08K5/098 , C08G2120/00 , C08G2125/00
摘要： The present invention is directed to an internal mold release agent, a composition containing the mold release agent, and a method of using such agent. The mold release broadly comprises zinc oleate or zinc laurate and a specific fatty amine derivative.
摘要翻译： 本发明涉及一种内部脱模剂，含有脱模剂的组合物以及使用该脱模剂的方法。 脱模剂广泛地包括油酸锌或月桂酸锌和特定的脂肪胺衍生物。
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公开(公告)号：US4789688A
公开(公告)日：1988-12-06
申请号：US146075
申请日：1988-01-20
CPC分类号： C08K5/29 , B29C33/60 , C08G18/3825 , C08G18/6535 , C08L75/00 , B29C67/246 , B29K2075/00 , C08G2120/00 , C08G2125/00
摘要： The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer moldings or optionally cellular, rigid structural polyurethanes by reacting a reaction mixture containing(i) a polyisocyanate,(ii) a high molecular weight polymer having at least two hydroxy groups and having a molecular weight of 400 to about 10,000,(iii) about 5 to 50% by weight, based on the weight of component (ii) of a chain-extender having at least two hydroxy groups and(iv) about 0.05 to 10 weight percent, based on the weight of components (ii) and (iii) of a salt based on a carboxy functional siloxane and an amidine group-containing compound of the formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are straight or branched, saturated or unsaturated hydrocarbon chains having up to 30 carbon atoms which may optionally be substituted by ether groups, ester groups, amide groups or amidine groups and may also optionally be terminated by isocyanate-reactive groups such as hydroxyl or amino groups,R.sub.4 corresponds to the definition of R.sub.1, R.sub.2 and R.sub.3, but may additionally represent an aromatic substituent having 6 to 15 carbon atoms or may represent the group --NR.sub.2 R.sub.3 andR.sub.1, R.sub.2, R.sub.3 and R.sub.4 may, with one or both of the amidine nitrogens, also form a heterocyclic ring.The present invention is also directed to the amidine group-containing salt (iv) and to a polyol composition based on components (ii), (iii) and (iv).
摘要翻译： 本发明涉及通过使包含（i）多异氰酸酯的反应混合物，（ii）具有至少两个羟基的高分子量聚合物的反应混合物来生产任选细胞的聚氨酯弹性体模制品或任选的细胞刚性结构聚氨酯的方法 基团，其分子量为400至约10,000，（iii）约5-50重量％，基于具有至少两个羟基的增链剂组分（ⅱ）的重量，和（iv）约0.05至 基于羧基官能硅氧烷和含有脒基的化合物（I）的盐的组分（ii）和（iii）的重量，10重量％，其中R 1，R 2和R 3是直的 或具有至多30个碳原子的支链，饱和或不饱和烃链，其可以任选被醚基，酯基，酰胺基或脒基取代，并且还可以任选地被异氰酸酯反应性基团例如氢 X或氨基，R 4对应于R 1，R 2和R 3的定义，但可以另外表示具有6至15个碳原子的芳族取代基或可以表示基团-NR 2 R 3，并且R 1，R 2，R 3和R 4可以与一个或多个 两个脒氮都形成杂环。 本发明还涉及含脒基盐（iv）和基于组分（ii），（iii）和（iv）的多元醇组合物。
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公开(公告)号：US4581386A
公开(公告)日：1986-04-08
申请号：US737369
申请日：1985-05-23
CPC分类号： C08G18/6529 , B29C33/60 , C08G18/5021 , C08K5/098 , B29K2075/00 , C08G2120/00 , C08G2125/00 , Y10S264/83
摘要： The present invention is directed to a process for the production of optionally cellular, polyurethane elastomer molding by reacting a reaction mixture containing(I) a polyisocyanate,(II) an isocyanate-reactive polymer having a molecular weight of about 1800 to 12,000,(III) about 5 to 50% by weight, based on the weight of component (II) of a chain extender comprising a sterically hindered aromatic diamine and(IV) an internal mold release agent mixture comprising(a) about 0.5 to 10% by weight, based on the weight of components (II) and (III) of a zinc carboxylate containing 8 to 24 carbon atoms per carboxylate group and(b) a compatibilizer comprising a member selected from the group consisting of nitrogen-containing, isocyanate-reactive, acyclic compounds and nitrogen-containing, isocyanate-reactive polymers in an amount sufficient to solubilize the zinc carboxylate so that when the internal mold release agent mixture is in admixture with components (II) and (III), the zinc carboxylate possesses improved resistance to precipitation,the reaction mixture being processed as a one-shot system by the RIM process at an isocyanate index of about 70 to 130.
摘要翻译： 本发明涉及通过使包含（I）多异氰酸酯，（II）分子量为约1800至12,000的异氰酸酯反应性聚合物的反应混合物，（III） ）约5至50重量％，基于包含空间位阻芳族二胺的增链剂组分（II）的重量，和（IV）内部脱模剂混合物，其包含（a）约0.5至10重量％ 基于每个羧酸酯基团含有8至24个碳原子的羧酸锌的组分（II）和（III）的重量，和（b）增容剂，其包含选自含氮，异氰酸酯反应性，非环状 化合物和含氮异氰酸酯反应性聚合物，其量足以溶解羧酸锌，使得当内部脱模剂混合物与组分（II）和（III）混合时，锌羧酸 甲酸酯具有改善的抗沉淀性能，反应混合物通过RIM方法以约70至130的异氰酸酯指数作为单次注射系统加工。
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